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1.
在二级轻气炮上,用高速电子相机扫描照相技术和改进的Mallory实验装置,对z切LiF,Al2O3(蓝宝石)和LiTaO3单晶材料的冲击透光性进行了对比测量,并用黑密度计提取出动态图像定量化的光强对比度变化曲线.结果表明,LiF单晶在102 GPa压强下能够保持长时间的初始透光性不变,与公认的LiF具有优良的高压下透明性的认识一致.LiTaO3单晶在实验压力(139GPa)下变成基本不透明.而Al关键词:
2O3')" href="#">Al2O3
LiF
3')" href="#">LiTaO3
光学透明性 相似文献
2.
基于晶格振动模受激电磁耦子散射过程的基本原理,对由LiTaO3(LT)晶体组成的太赫兹波参量振荡器(TPO)的输出调谐特性、增益和吸收损耗特性,以及基于硅棱镜阵列耦合装置的THz波输出特性等方面进行了详细的理论研究和分析.研究结果表明,基于LiTaO3晶体A1对称性晶格振动的特点以及自身优异的非线性光学特性,通过利用短波长抽运光、适当提高抽运能量以及缩短TPO谐振腔腔长等方法,完全可以实现LT-TPO的高性能运转,证明了LiTaO3晶体是一种性能优良的TPO工作介质.理论计算结果及方法为以后的LT-TPO实验工作提供了详实的理论依据和实验指导.
关键词:
非线性光学
THz辐射
3晶体')" href="#">LiTaO3晶体
电磁耦子 相似文献
3.
Zhang Wendong Tan Qiulin Liu Jun Xue Chenyang Xiong Jijun Chou Xiujian 《Optics & Laser Technology》2010,42(8):1223-1228
An infrared (IR) single-element detector based on a lithium tantalate (LiTaO3) single-crystal wafer has been successfully fabricated. The preparation and design of the device are discussed and analyzed in detail. The processing of a thin LiTaO3 wafer, the characterization of an IR filter window, and the assembly of the wafer and filter are explained. A LiTaO3 sensor element, a CMOS amplifier, a narrow-band filter (which can be selected to operate within the appropriate spectral region), and the read-out circuits are set into a TO-18 vessel. Each TO-18-type detector offers a single channel (a single detection wavelength). Two TO-18 detectors with different filters, one acting as a detection channel and the other as a reference, a broadband light source, a circuit board and a flake of wire gauze are assembled and integrated into a gilded gas cell for the purpose of detecting ethene gas. 相似文献
4.
The EPR g factors g// and g⊥ for Ti3+ ions at the trigonal octahedral Li+ sites of LiNbO3 and LiTaO3 crystals are calculated from the third-order perturbation formulas of g factors for 3d1 ion in trigonal symmetry. In the calculations, the crystal-field parameters are obtained from the structural data by using the superposition model. The calculated values are in reasonable agreement with the observed values. The results are discussed. 相似文献
5.
Ti, Fe Co-doped LiTaO3 (LT) crystals have been grown by the Czochralski method from the congruent melts. The absorption spectra of crystal were measured before and after ultraviolet illumination. Holograms have been recorded in doubly doped crystals with continuous-wave laser light by use of two-color method. The maximum value of refractive-index changes 7×10−5 is achieved. 相似文献
6.
A promising approach to apply the Love wave concept to commercially available low-loss surface acoustic wave (SAW) devices of the type Murata SAF 380 is presented. Thin wave-guiding layers of variable thickness are coated on the piezoelectric substrate of the devices. Two different layer materials were used: sputtered SiO2 and a new polymer in this field, parylene C (poly-[2-chloro-p-xylylene]). Insertion loss, resonance frequency, frequency changes during protein precipitation and noise of the devices are discussed as a function of the thickness of the wave-guiding layer. It is demonstrated that the application of an optimized wave-guiding layer increases the sensitivity. When using SiO2 as wave-guiding layer, an optimum layer thickness of 4 μm leads to a detection limit of 1.7 pg/mm2. Therefore, the detection limit is improved by factor 7.7 as compared to uncoated SAW devices. Parylene-coated devices reach a detection limit of 2.9 pg/mm2 at an optimum layer thickness of 0.5 μm. This corresponds to an improvement by factor 4.3. As the SAW devices used in this study are commercially available at low costs, applying appropriate wave-guiding layers permits an application as chemical or biochemical sensors with excellent sensitivities. Moreover, parylene-coated devices combine the sensitivity increase by excitation of Love waves with an excellent protective effect against corrosive attacks by the surrounding medium. Therefore, these sensors are most suitable for biosensing in conducting buffer solutions. 相似文献
7.
Shuangquan Fang 《Optik》2006,117(2):72-76
Mg, Fe double-doped LiTaO3 and LiNbO3 crystals have been grown by Czochralski method. The optical properties were measured by two-beam coupling experiments and transmitted facula distortion method. The results showed that the photorefractive response speed of Mg:Fe:LiTaO3 was about three times faster than that of Fe:LiTaO3, whereas the photo-damage resistance was two orders of magnitude higher than that of Fe:LiTaO3. In this paper, site occupation mechanism of impurities was also discussed to explain the high photo-damage resistance and fast response speed in Mg:Fe:LiTaO3 crystal. 相似文献
8.
We report on the development of a laser source in the mid-infrared spectral region based on difference-frequency generation (DFG) in a periodically poled LiNbO3 (PPLN) crystal. Continuously tunable coherent radiation from 2.75 to 4.78 μm was produced by optical parametric interaction between a diode-pumped monolithic continuous-wave (CW) Nd:YAG laser operating at 1.064 μm and a CW Ti:Sapphire laser tunable from 767 to 871 nm. Temperature-dependent quasi-phase-matched DFG wavelength acceptance bandwidth was studied and characterized. An empiric formula is given to estimate the phase-matched wavelength acceptance bandwidth as a function of the crystal temperature at Λ = 22.5 μm. A large frequency scan of 128 cm−1 (about 78 cm−1 above 1 μW) near 4.2 μm was achieved. The whole absorption spectrum of the P and R branches of the ν3 band of atmospheric carbon dioxide has been recorded with a single phase-matched frequency scan. 相似文献
9.
In this study we present the effects of iron oxide (Fe2O3) on titanium dioxide (TiO2) in synthesising visible-light reactive photocatalysts. A Fe2O3-TiO2 composite photocatalyst was synthesized from Fe2(SO4)3 and Ti(SO4)2 by a ethanol-assisted hydrothermal method. The preparation conditions were optimized through the investigation of the effects of hydrothermal temperature and time as well as molar ratio of Ti to Fe on the photocatalytic activity. The visual, physical and chemical properties of the Fe2O3-TiO2 composites were investigated. The results showed that α-Fe2O3 and anatase TiO2 were present in the composites. The Fe2O3-TiO2 synthesized under optimum condition consisted of mesoporous structure with an average pore size of 4 nm and a surface area of 43 m2/g. Under visible and solar light irradiation, the photocatalytic activity of optimized sample was significantly higher than that of pure TiO2. This sample led to a photodegradation efficiency of 90% and 40% of auramine under visible light and solar light, respectively. 相似文献
10.
S. D. Pan X. Q. Yu Z. Yan Y. Shen X. J. Lv S. N. Zhu 《Applied physics. B, Lasers and optics》2008,93(4):749-752
We present an approach to generating a tunable orange laser from 0.601 to 0.604 μm based on a quasi-periodically poled superlattice
in LiTaO3 and a Q-switched 1.064 μm Nd:YVO4 laser as pump. The orange laser was generated in a cavity by a parametric process cascaded by a frequency mixing with a maximum
output of 310 mW using 15 W pump power. 相似文献
11.
Tanmay K. Ghorai Susmita Pramanik Panchanan Pramanik 《Applied Surface Science》2009,255(22):9026-9031
Mn2O3/TiO2 solid solution was prepared from two different oxides, manganese oxide (from KMnO4 and ethanol) and TiO2, these samples were characterized by BET, XRD, EDAX, SEM, FT-IR, ESR, XPS and UV–vis absorption spectroscopy. Photocatalytic activities of Mn2O3/TiO2 powder was investigated by photooxidation of different dyes like Rhodamine B, thymol blue, methyl orange and Bromocresol green under visible light (300-W Xe lamp; λ > 420 nm). The results show that the alloy of TiO2 with 1 mol% of Mn2O3 (MNT1) exhibit photocatalytic activity 3–5 times higher than that of P25 TiO2 for oxidation of various dyes (RB, TB, MO and BG). The average particle size and crystallite size of MNT1 were found to be 100 nm and 12 nm measured from SEM and XRD, respectively. The EPR spectra of the Mn2O3/TiO2 samples is a sharp five-line Mn(III) component centered on geff = 1.99. 相似文献
12.
A visible light-driven photocatalyst, C-doped Zn3(OH)2V2O7, prepared by a hydrothermal method was studied. The as-prepared catalyst was characterized by SEM, XRD, DRS, and XPS, and exhibited efficient photocatalytic activity in the degradation of methylene blue (MB) under visible-light irradiation. Besides decoloring, the decomposition of MB was also observed, further demonstrating the performance of the photocatalyst. The carbon existing on the surface of Zn3(OH)2V2O7 nanorods was free and in carbide form. Dye degradation followed first-order kinetics, and was explained on the basis of the Langmuir-Hinshelwood mechanism. 相似文献
13.
K.D OskamK.A Kaspers A Meijerink H Müller-BunzTh Schleid 《Journal of luminescence》2002,99(2):101-105
The luminescence properties of Ce3+ in La3F3[Si3O9] are reported. Excitation and emission bands corresponding to 4f1→5d1 transitions of Ce3+ were identified. The center of gravity of the 5d states lies at remarkable high energy (43.2×103 cm−1) for Ce3+ in a silicate compound. This high value is attributed to the combined oxygen/fluoride coordination of the Ce3+ ion. Emission from the lowest 4f5d level to the 2F5/2 and 2F7/2 levels was found at 32.4×103 and 30.4×103 cm−1. These results are compared with literature data on silicates and fluorides. From the values found for Ce3+, predictions are made for the positions of the 4f5d bands of Pr3+ and Er3+ in La3F3[Si3O9]. For both ions, it is concluded that in this host lattice emission is expected from high lying 4fn energy levels. 相似文献
14.
Preparation of NaYF4:,Er3+/TiO2 composite and up-conversion luminescence properties under visible light excitation
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The up-conversion luminescence composite NaYF 4:Er 3+ /TiO 2 is prepared using the sol-gel method.The specimen has good crystallinity and two shapes,i.e.,viereck and round,while the sizes of viereck and round particles are both micron-sized.The TiO 2 has an anatase structure,while the NaYF 4 has a hexagonal phase,which can be hardly obtained through the common sol-gel method.Due to the big particle size and the high crystallinity of pure NaYF 4:Er 3+,the composite has a small specific surface area that is less than Degussa P25 TiO 2.The NaYF 4:Er 3+ /TiO 2 composite shows several emission peaks at 211,237,and 251 nm under the excitation of 388 nm,at 395 nm and 411 nm under the excitation of 500 nm,and at 467,481,492,and 508 nm under the excitation of 570 nm. 相似文献
15.
The magnetic properties of trigonal Nd0.9Dy0.1Fe3(BO3)4 substituted compound with the competitive Nd-Fe and Dy-Fe exchange interactions have been investigated. It has been shown that in Nd0.9Dy0.1Fe3(BO3)4 a spontaneous spin-reorientation transition from an ease-axis state to an easy-plane occurs near 8 K. Anomalies of the magnetization curves are observed in a spin-flop transition induced by the magnetic field B‖c. The calculations were performed using a molecular-field approximation and a crystal-field model for the rare-earth subsystem. Extensive experimental data on the magnetic properties of Nd0.9Dy0.1Fe3(BO3)4 have been interpreted and good agreement between theory and experiment has been achieved using the obtained theoretical dependences. 相似文献
16.
In this paper, low temperature sintering of the Bi2(Zn1/3Nb2/3)2O7 (β-BZN) dielectric ceramics was studied with the use of BiFeO3 as a sintering aid. The effects of BiFeO3 contents and the sintering temperature on the phase structure, density and dielectric properties were investigated. The results showed that the sintering temperature could be decreased and the dielectric properties could be retained by the addition of BiFeO3. The structure of BiFeO3 doped β-BZN was still the monoclinic pyrochlore phase. The sintering temperature of BiFeO3 doped β-BZN ceramics was reduced from 1000 °C to 920 °C. In the case of 0.15 wt.% BiFeO3 addition, the β-BZN ceramics sintered at 920 °C exhibited good dielectric properties, which were listed as follows: εr = 79 and tan δ = 0.00086 at a frequency of 1 MHz. The obtained properties make this composition to be a good candidate for the LTCC application. 相似文献
17.
One-dimensional(ID) In2O3(ZnO)m superlattice nanobelts are synthesized by a chemical vapor deposition method.The formation of the In2O3(ZnO)m superlattice is verified by the high-resolution transmission electron microscopy images.The typical zigzag boundaries could be clearly observed.An additional peak at 614 cm-1 is found in the Raman spectrum,which may correspond to the superlattice structure.The study about the electrical transport properties reveals that the In2O3(ZnO)m nanobelts exhibit peculiar nonlinear I-V characteristics even under the Ohmic contact measurement condition,which are different from the Ohmic behaviors of the In-doped ZnO nanobelts.The photoelectrical measurements show the differences in the photocurrent property between them,and their transport mechanisms are also discussed. 相似文献
18.
C. Li 《Applied Surface Science》2010,256(22):6801-6804
Fe2O3/Al2O3 catalysts were prepared by solid state reaction method using α-Fe2O3 and γ-Al2O3 nano powders. The microstructure and surface properties of the catalyst were studied using positron lifetime and coincidence Doppler broadening annihilation radiation measurements. The positron lifetime spectrum shows four components. The two long lifetimes τ3 and τ4 are attributed to positronium annihilation in two types of pores distributed inside Al2O3 grain and between the grains, respectively. With increasing Fe2O3 content from 3 wt% to 40 wt%, the lifetime τ3 keeps nearly unchanged, while the longest lifetime τ4 shows decrease from 96 ns to 64 ns. Its intensity decreases drastically from 24% to less than 8%. The Doppler broadening S parameter shows also a continuous decrease. Further analysis of the Doppler broadening spectra reveals a decrease in the p-Ps intensity with increasing Fe2O3 content, which rules out the possibility of spin-conversion of positronium. Therefore the decrease of τ4 is most probably due to the chemical quenching reaction of positronium with Fe ions on the surface of the large pores. 相似文献
19.
Mid-infrared generation based on a periodically poled LiNbO3 optical parametric oscillator
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We report a nanosecond Nd:YVO_4-pumped optical parametric oscillator (OPO) based on periodically poled LiNbO_3 (PPLN). Tuning is achieved in this experiment by varying the temperature and period of the PPLN. The design of double-pass singly resonant oscillator (DSRO) and confocal cavity enables the OPO threshold to be lowered considerably, resulting in a simple, compact, all-solid-state configuration with the mid-infrared idler powers of up to 466mW at 3.41μm. 相似文献
20.
采用传统的固相反应法,在1400–1500 ℃下烧结,制备得到Al2O3-Y2O3-ZrO2三相复合陶瓷.样品的结构、形貌和电性能分别用X射线衍射(XRD)、扫描电子显微镜(SEM)及介电谱表征.XRD表明此三相复合体系无其他杂相,加入Y2O3及ZrO2后使得Al2O3成瓷温度降低;SEM表明此体系晶粒直径为200–500 nm,并且样品随烧结温度的升高而变得更加致密,晶界更加清晰;介电损耗谱中出现峰值弛豫现象,根据Cole-Cole复阻抗谱得出其为非德拜弛豫.
关键词:
2O3-Y2O3-ZrO2三相陶瓷')" href="#">Al2O3-Y2O3-ZrO2三相陶瓷
介电弛豫
阻抗谱
热导率 相似文献