共查询到20条相似文献,搜索用时 15 毫秒
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Komarov A. V. Yakovlev I. P. Novikov D. V. Zakhs V. E. 《Russian Journal of General Chemistry》2003,73(12):1936-1941
4-Hydroxy-5-methyl(phenyl)-2-styryl-6H-1,3-oxazin-6-ones react with hydrazine and phenylhydrazine to give the corresponding 3,5-substituted triazoles. Treatment of the title compounds with ethanol and methanol leads to formation of N-cinnamoylmalonamates. The structure of the products was confirmed by the IR and 1H and 13C NMR spectra. 相似文献
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A variety of 2,2-dimethyl-6-(2-oxoalkyl)-1,3-dioxin-4-ones 5a-l and the corresponding 6-substituted 4-hydroxy-2-pyrones 3a-l were prepared in high yields under mild reaction conditions by the reaction of 2,2,6-trimethyl-1,3-dioxin-4-one 4 with 1-acylbenzotriazoles 9 in the presence of LDA followed by thermal cyclization of 5a-l to 3a-l. Synthesis of novel 6-(1-benzoylalkyl)-2,2-dimethyl-1,3-dioxin-4-ones 12a-c was achieved by alkylation of dioxinone 5a and their subsequent cyclization gave 5-alkyl-4-hydroxy-2-pyrones 13a-c. 相似文献
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Alkyl carbamates and S-alkyl thiocarbamates react with substituted malonyl dichlorides in boiling benzene to give the corresponding 2,5-substituted 4-hydroxy-6H-1,3-oxazin-6-ones. The reaction of S-methyl thiocarbamate with unsubstituted malonyl dichloride in boiling diethyl ether or benzene leads to formation of S-methyl (3-methylsulfanylaminocarbonyl-3-oxopropionyl)thiocarbamate and is not accompanied by cyclization, whereas in boiling toluene 4-hydroxy-2-methylsulfanyl-6H-1,3-oxazin-6-one is obtained.__________Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 3, 2005, pp. 468–472.Original Russian Text Copyright © 2005 by Lalaev, Yakovlev, Zakhs. 相似文献
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4H-3,1-Benzoxazin-4-ones methoxy-substituted 2-(2-arenesulfonylaminophenyl)-4H-3,1-benzoxazin-4-ones
M. V. Loseva B. M. Bolotin B. M. Krasovitskii 《Chemistry of Heterocyclic Compounds》1971,7(8):964-967
Methoxy-substituted 2-(2-tosylaminophenyl)-4H-3,1-benzoxazin-4-one and 2-phenyl-4H-3,1-benzoxazin-4-one were synthesized. Their UV, IR, and luminescence spectra were studied. The position of the methoxy group affects the strength of the intramolecular hydrogen bond (IHB). The luminescence properties of methoxy-substituted 2-(2-tosylaminophenyl)-4H-3,1-benzoxazin-4-ones are associated with the strength of the IHB. The luminescence maximum is shifted to the short-wave region with strengthening of the IHB, and the luminescence intensity increase simultaneously.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1028–1032, August, 1971.The authors thank Yu. S. Ryabokobylko and A. O. Zisman for measuring the absorption spectra in the IR and UV regions. 相似文献
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D. D. Nekrasov 《Chemistry of Heterocyclic Compounds》2001,37(8):925-938
Methods for the production of 6-aryl-2,2-dimethyl-1,3-dioxin-4-ones and their thermolysis in the presence of nucleophiles and dienophiles are discussed 相似文献
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The asymmetric transfer hydrogenation of a series of 2,2-dimethyl-6-(2-oxoalkyl)-1,3-dioxin-4-ones and 2,2-dimethyl-6-(2-oxoaryl)-1,3-dioxin-4-ones was achieved in high enantiomeric excess using a Ru(II) catalyst. The aryl substrates were most compatible with the methodology and this process facilitated a total synthesis of enantiomerically pure (+)-yashabushitriol. 相似文献
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tert-Butyl and 2,6-di(tert-butyl)-4-methylphenyl (BHT) cyclopropanecarboxylates ( 4 , 6 , 24 , 25 ) are lithiated with LiN(i-Pr)2 and t-BuLi, respectively. Reactions with alkyl halides, aldehydes, acyl chlorides, and heteroelectrophiles give α-substituted BHT esters which can be cleaved (t-BuOK/H2O/THF) to the corresponding carboxylic acids or reduced (LiAlH4/THF) to the cyclopropanemethanols. 相似文献
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Gornostaev L. M. Rudenko D. S. Rukovets T. A. Fominykh O. I. Romashkova Yu. G. Gatilov Yu. V. Sil’nikov V. N. 《Russian Journal of Organic Chemistry》2021,57(2):165-169
Russian Journal of Organic Chemistry - The reactions of 3-arylamino-1,4-naphthoquinone-4-oximes with 2,2-dihydroxyindane-1,3-dione proceed without involving the oxime group and lead to... 相似文献
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Reduction of chiral 2-(2-furyl)-3,4-dimethyl-5-phenyloxazo-lidines-1,3 by H2/Raney nickel proceeds simultaneously as hydrogenation of the furan ring and opening of the oxazolidine ring on C2-O bond. Diastere-oselectivity in the first reaction was established as ca 40% and 80% depending on the configuration of the oxazolidine 1 and 2. 相似文献
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The reaction of 6-(tert-butyl)-3-hydrazino-1,2,4-triazin-5(2H)-one with acetone and benzaldehyde yields the corresponding hydrazones. In the presence of thionyl chloride the benzaldehyde hydrazone is converted to 3-(tert-butyl)-6-phenyl-1,2,4-triazolo[4,3-b]-1,2,4-triazin-2(1H)-one and this can also be formed via the acylation of the starting hydrazinotriazinone using benzoyl chloride. 相似文献
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V. Bavetsias 《合成通讯》2013,43(24):4547-4559
Treatment of 2-methoxyacetamidobenzonitriles or 2-chloroacetamidobenzonitrile with UHP and K2CO3 provides a convenient route to 2-methoxymethyl-or 2-chloromethylquinazolin-4(3H)-ones. In addition, demethylation of 2-methoxymethylquinazolin-4(3H)-ones with 48% HBr gives 2-hydroxymethylquinazolin-4(3H)-ones. 相似文献
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M. V. Loseva B. M. Krasovitskii B. M. Bolotin 《Chemistry of Heterocyclic Compounds》1970,6(12):1491-1494
Chloro- and bromo-substituted 2-(2-tosylaminophenyl)-4H-1,3-benzoxaz-4-ones and 2-(2-tosylaminophenyl)-4H-naphtho[2,3-d]-1,3-oxaz-4-ones, their absorption spectra at room temperature, and their luminescence spectra at 77 deg K are described.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1597–1601, December, 1970. 相似文献
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