Weyl’s Gauge Argument

The standard $\mathbb{U}(1)$ “gauge principle” or “gauge argument” produces an exact potential A=dλ and a vanishing field F=d ² λ=0. Weyl (in Z. Phys. 56:330–352, 1929; Rice Inst. Pam. 16:280–295, 1929) has his own gauge argument, which is sketchy, archaic and hard to follow; but at least it produces an inexact potential A and a nonvanishing field F=dA≠0. I attempt a reconstruction.     

Spatial and Temporal Characterization of Distilled Water Plasma Using Laser-Induced Breakdown Spectroscopy: Effect of Self-Absorption on Plasma Parameters

The spatiotemporal evolution of the plasma induced by interaction of an Nd-YAG laser pulse with the surface of distilled water is described. The temporal evolution from 200 ns after the plasma creation to 2200 ns of the H _α and H _β lines is reported. Supposing the local thermodynamic equilibrium, the two plasma parameters, electron density and temperature, are determined, including the influence of the self-absorption on its measurements. The spatial evolution of the H _β intensity and of the electron density is given.     

Inverse Scattering at Fixed Energy on Surfaces with Euclidean Ends

On a fixed Riemann surface (M ₀, g ₀) with N Euclidean ends and genus g, we show that, under a topological condition, the scattering matrix S _V (λ) at frequency λ > 0 for the operator Δ+V determines the potential V if \({V\in C^{1,\alpha}(M_0)\cap e^{-\gamma d(\cdot,z_0)^j}L^\infty(M_0)}\) for all γ > 0 and for some \({j\in\{1,2\}}\) , where d(z, z ₀) denotes the distance from z to a fixed point \({z_0\in M_0}\) . The topological condition is given by \({N\geq \max(2g+1,2)}\) for j = 1 and by N ≥ g + 1 if j = 2. In \({\mathbb {R}^2}\) this implies that the operator S _V (λ) determines any C ^{1, α} potential V such that \({V(z)=O(e^{-\gamma|z|^2})}\) for all γ > 0.     

Diffusion Effects on the Breakdown of a Linear Amplifier Model Driven by the Square of a Gaussian Field

We investigate solutions to the equation ? _t ?? $\mathcal{D}$ Δ?=λS ²?, where S(x, t) is a Gaussian stochastic field with covariance C(x?x′, t, t′), and x∈ $\mathbb{R}$ ^d . It is shown that the coupling λ _cN (t) at which the N-th moment <? ^N (x, t)> diverges at time t, is always less or equal for $\mathcal{D}$ >0 than for $\mathcal{D}$ =0. Equality holds under some reasonable assumptions on C and, in this case, λ _cN (t)=Nλ _c (t) where λ _c (t) is the value of λ at which <exp[λ ∫ ^t ₀ S ²(0, s) ds]> diverges. The $\mathcal{D}$ =0 case is solved for a class of S. The dependence of λ _cN (t) on d is analyzed. Similar behavior is conjectured when diffusion is replaced by diffraction, $\mathcal{D}$ →i $\mathcal{D}$ , the case of interest for backscattering instabilities in laser-plasma interaction.     

Extremely large bandwidth and ultralow-dispersion slow light in photonic crystal waveguides with magnetically controllability

A line-defect waveguide within a two-dimensional magnetic-fluid-based photonic crystal with 45^o-rotated square lattice is presented to have excellent slow light properties. The bandwidth centered at $ \lambda_{0} $  = 1,550 nm of our designed W1 waveguide is around 66 nm, which is very large than that of the conventional W1 waveguide as well as the corresponding optimized structures based on photonic crystal with triangular lattice. The obtained group velocity dispersion $ \beta_{2} $ within the bandwidth is ultralow and varies from ?1,191 $ a/(2\pi c^{2} ) $ to 855 $ a/(2\pi c^{2} ) $ (a and c are the period of the lattice and the light speed in vacuum, respectively). Simultaneously, the normalized delay-bandwidth product is relatively large and almost invariant with magnetic field strength. It is indicated that using magnetic fluid as one of the constitutive materials of the photonic crystal structures can enable the magnetically fine tunability of the slow light in online mode. The concept and results of this work may give a guideline for studying and realizing tunable slow light based on the external-stimulus-responsive materials.     

Structural study,intermolecular interactions in view of X-ray and Hirshfeld surface analysis,DSC characterization,and electrical properties of <Emphasis Type="Italic">bis</Emphasis>-(4-benzylpyridinium) tetrabromozincate

The synthesis and crystal structure of the bis-(4-benzylpyridinium) tetrabromozincate(II) “(4-BP)₂[ZnBr₄]” salt are reported in the present paper. After an X-ray investigation, it has been shown that the title compound belongs to the centrosymmetric monoclinic system at 296 K, in the space group P2₁/n with the following lattice parameters a = 15.0764(8) Å, b = 22.5575(12) Å, c = 16.0739(9) Å, and β = 93.887(3)°. The FT-IR and Raman spectra confirm the presence of both cationic and anionic parts. The crystal packing is governed by an extensive network: N–H…Br, (N: pyridinium), C–H…Br hydrogen bonds, π…π, and C–H…π stacking between identical 4-BP (aromatic–aromatic), in which they may be effective in the stabilization of the crystal structure. Moreover, Hirshfeld surface analysis was used for visually analyzing intermolecular interactions in crystal structures. The phase transitions at T = 323 K have been confirmed by the differential scanning calorimetry. The electrical technique was measured in the 209 Hz–5-MHz frequency range and 298–393-K temperature intervals. The evolution of the dielectric constant as a function of frequency and temperature proved the presence of a first-order phase transition at 323 K.

Open image in new window

Graphical abstract ?

     

Evaluation of spectral dispersion of optical constants of a-Se films from their normal-incidence transmittance spectra using Swanepoel algebraic envelope approach

Spectral dispersions of index of refraction \({n(\lambda )}\) and extinction coefficient \({\kappa (\lambda )}\) of undoped amorphous selenium (a-Se) films of three thicknesses (d?≈?0.5, 0.75, and 1.0 µm) were evaluated by analyzing experimental room-temperature normal-incidence transmittance-wavelength (\({{T_{{\text{exp}}}}(\lambda )} - \lambda\)) data (λ =?400–1100 µm) of their air-supported {a-Se film/thick glass slide}-stacks using Swanepoel’s transmission envelope theory of uniform films. Above a wavelength \({{\lambda _c}\,\, \approx \,\,640\;{\text{nm}}}\), as-measured \({{T_{{\text{exp}}}}(\lambda )}\,\, - \,\lambda\) spectra display well-resolved maxima and minima, with minor shrinkage in transparent and weak absorption regions (750–1100 nm). Below \({\lambda _{\text{c}}}\), a smeared sharp decline of \({{T_{{\text{exp}}}}(\lambda )}\) with decreasing λ, signifying strong absorption in a-Se films and existence of band-tail localized states. For λ > λ _c, the \({n\,(\lambda )}\, - \,\lambda\) data retrieved from algebraic envelope procedures followed a Sellmeier-like dispersion relation, with the best-fit values of high-frequency dielectric constant \({{\varepsilon _\infty }\, \approx \,\,{\text{4.9}}}\), static index of refraction \({{n_{\text{0}}} = n\left( {E\, \to \,{\text{0}}} \right)\,\, \approx \,\,{\text{2.43}}}\), and resonance wavelength \({{\lambda _0}\, \approx \,490\,\,{\text{nm}}}\), which may be assigned to onset of photogeneration in a-Se. Urbach-like dependency of absorption coefficient \({\alpha (h{{\nu }})}\) of a-Se films on photon energy \({h{{\nu }}}\) was realized with an Urbach-tail breadth of 85 meV. All achieved optical parameters were found to be slightly dependent on film thickness. Findings of present algebraic analysis are consistent with reported literature results obtained on the basis of other optical analytical approaches.     

Investigation of conductivity of adhesive layer including indium tin oxide particles for multi-junction solar cells

We report connection conductivity ( \(C_{\rm c}\) ) of adhesive which including \(\hbox {In}_2\hbox {O}_3\) – \(\hbox {SnO}_2\) (ITO) particles developed for fabrication of stacked-type-multi-junction solar cells. The commercial 20- \(\upmu \) m sized ITO particles were heated in vacuum at temperature ranging from 800 to 1,300  \(^{\circ }{\rm C}\) for 10 min to increase \(C_{\rm c}\) . 6.2 wt% ITO particles were dispersed in commercial Cemedine adhesive gel to form 100 samples structured with n-type Si/adhesive/n-type Si (n-Si sample) and p-type Si/adhesive/p-type Si (p-Si sample). Current density as a function of voltage (J–V) characteristics gave \(C_{\rm c}\) . It ranged from 4.3 to 1.0 S/cm \(^2\) for the n-Si sample with 800 \(^{\circ }{\rm C}\) heat-treated ITO particles. Its standard deviation was 0.59 S/cm \(^2\) . On the other hand, it ranged from 2.0 to 0.6 S/cm \(^2\) for the p-Si sample with 800  \(^{\circ }{\rm C}\) heat-treated ITO particles. Its standard deviation was 0.22 S/cm \(^2\) . The distribution of \(C_{\rm c}\) mainly resulted from contact efficiency of ITO particles to substrate. We theoretically estimated that present \(C_{\rm c}\) achieved a low loss of the power conversion efficiency ( \(E_{\rm ff}\) ) lower than 0.3 % in the application of fabrication of multi-junction solar cell with an intrinsic \(E_{\rm ff}\) of 30 % and an open circuit voltage above 1.9 V.     

Numerical analysis of quantum ring intersubband photodetector for far infrared detection

A quantum ring based intersubband photodetector is designed and its optical performance is studied based on a developed theoretical model. Intersubband absorption of quantum rings is numerically calculated for two transitions, from ground state to first excited state and to continuum energy and the effects of broadening mechanisms are studied. Device show responsivity about 0.2 A/W at T = 80 K and V = 2 V. Dark current of structure with and without the resonant tunneling barriers is calculated. Specific detectivity \((D^*)\) is studied at different temperatures and peak values about \(3\times 10^{12}\,\hbox {cm Hz}^{1/2}/\hbox {W}\) is obtained at T = 50 K. Results show that inclusion of resonant tunneling barriers leads to improvement in \(D^*\) about one order of magnitude.     

Efimov Spectrum in Bosonic Systems with Increasing Number of Particles

It is well-known that three-boson systems show the Efimov effect when the two-body scattering length a is large with respect to the range of the two-body interaction. This effect is a manifestation of a discrete scaling invariance (DSI). In this work we study DSI in the N-body system by analysing the spectrum of N identical bosons obtained with a pairwise gaussian interaction close to the unitary limit. We consider different universal ratios such as \({E_N^0/E_3^0}\) and \({E_N^1/E_N^0}\) , with \({E_N^i}\) being the energy of the ground (i = 0) and first-excited (i = 1) state of the system, for \({N \leq16}\) . We discuss the extension of the Efimov radial law, derived by Efimov for N = 3, to general N.     

The Lie–Rinehart Universal Poisson Algebra of Classical and Quantum Mechanics

The Lie–Rinehart algebra of a (connected) manifold ${\mathcal {M}}$ , defined by the Lie structure of the vector fields, their action and their module structure over ${C^\infty({\mathcal {M}})}$ , is a common, diffeomorphism invariant, algebra for both classical and quantum mechanics. Its (noncommutative) Poisson universal enveloping algebra ${\Lambda_{R}({\mathcal {M}})}$ , with the Lie–Rinehart product identified with the symmetric product, contains a central variable (a central sequence for non-compact ${{\mathcal {M}}}$ ) ${Z}$ which relates the commutators to the Lie products. Classical and quantum mechanics are its only factorial realizations, corresponding to Z  =  i z, z  =  0 and ${z = \hbar}$ , respectively; canonical quantization uniquely follows from such a general geometrical structure. For ${z =\hbar \neq 0}$ , the regular factorial Hilbert space representations of ${\Lambda_{R}({\mathcal{M}})}$ describe quantum mechanics on ${{\mathcal {M}}}$ . For z  =  0, if Diff( ${{\mathcal {M}}}$ ) is unitarily implemented, they are unitarily equivalent, up to multiplicity, to the representation defined by classical mechanics on ${{\mathcal {M}}}$ .     

Analytic Binding Energies for Two-Baryon Bound States in 2 + 1 Strongly Coupled Lattice QCD With Two-Flavors

We consider a lattice SU(3) QCD model in 2 + 1 dimensions, with two flavors and 2 × 2 spin matrices. An imaginary time functional integral formulation with Wilson’s action is used in the strong coupling regime, i.e. small hopping parameter ${0 < \kappa \ll 1}$ , and much smaller plaquette coupling ${\beta, 0 < \beta \ll \kappa}$ . In this regime, it is known that the low-lying energy-momentum spectrum contains isolated dispersion curves identified with baryons and mesons with asymptotic masses ${m\approx-3\ln\kappa}$ and ${m_m\approx-2\ln\kappa}$ , respectively. We prove the existence of two (labelled by ±) two-baryon bound states for each of the total isospin sectors I = 0,1 and we obtain, in each case, the exact binding energies ${\epsilon_{I\,\pm} }$ (of order ${\kappa^2}$ ) which extend to jointly analytic function in ${\kappa}$ and β. We also prove that these points are the only mass spectrum up to slightly above the bound state masses. Precisely, we show, for ${\alpha_0=\frac 14, \alpha_1=\frac 1{12}, \alpha_2=\frac12, \alpha_3=\frac 34}$ and small ${\delta >0 }$ , that the bound state masses ${2m-\epsilon_{I\,\pm}}$ are the only points in the mass spectrum in ${(0,2m-\epsilon_{I\,\pm}+\delta \alpha_I\kappa^2)}$ , for I = 0,1, and in ${(0,2m-(1+\delta)\alpha_I\kappa^2)}$ , for I = 2,3. These results are exact and validate our previous results obtained in a ladder approximation. The method employs suitable two- and four-point correlations with spectral representations and a lattice Bethe-Salpeter equation. For I = 0,1, a quark, antiquark space-range one potential of order ${\kappa^2}$ is found to be the dominant contribution to the two-baryon interaction and the interaction of the individual quark isospins of one baryon with those of the other is described by permanents. A novel spectral free decomposition (but spectral representation motivated, for real κ and β) of the two-point correlation, after performing a complex extension, is a key ingredient in showing the joint analyticity of the binding energy.     

Axial strain and temperature sensing characteristics of the single–coreless–single mode fiber structure-based fiber ring laser

This paper experimentally demonstrated a singlemode–coreless–singlemode (SCS) fiber structure-based fiber ring cavity laser for strain and temperature measurement. The basis of the sensing system is the multimodal interference occurs in coreless fiber, and the transmission spectrum is sensitive to the ambient perturbation. In this sensing system, the SCS fiber structure not only acts as the sensing head of the sensor but also the band-pass filter of the ring laser. Blue shift with strain sensitivity of \(\sim\) ?2 pm/με ranging from 0 to 730 με and red shift with temperature sensitivity of \(\sim\) 11 pm/°C ranging from 5 to 75 °C have been achieved. Experimental results also show the proposal has great potential in using long-distance operation. The fiber ring laser sensing system has a optical signal to noise ratio (OSNR) more than 50 and 3 dB bandwidth less than 0.05 nm. The result shows that the coreless fiber has no improvement of the temperature and axial strain sensitivity. However, compared to the common singlemode–multimode–singlemode fiber structure sensors, the laser sensing system has the additional advantages of high OSNR, high intensity and narrow 3 dB bandwidth, and thus improves the accuracy.     

Discovering Echinococcus granulosus thioredoxin glutathione reductase inhibitors through site-specific dynamic combinatorial chemistry

In this study, we report a strategy using dynamic combinatorial chemistry for targeting the thioredoxin (Trx)-reductase catalytic site on Trx glutathione reductase (TGR), a pyridine nucleotide thiol-disulfide oxido-reductase. We chose Echinococcus granulosus TGR since it is a bottleneck enzyme of platyhelminth parasites and a validated pharmacological target. A dynamic combinatorial library (DCL) was constructed based on thiol-disulfide reversible exchange. We demonstrate the use of 5-thio-2-nitrobenzoic acid (TNB) as a non-covalent anchor fragment in a DCL templated by E. granulosus TGR. The heterodimer of TNB and bisthiazolidine (2af) was identified, upon library analysis by HPLC (IC $_{50}$  = 24  $\upmu $ M). Furthermore, 14 analogs were synthetically prepared and evaluated against TGR. This allowed the study of a structure–activity relationship and the identification of a disulfide TNB-tricyclic bisthiazolidine (2aj) as the best enzyme inhibitor in these series, with an IC $_{50}$  = 14  $\upmu $ M. Thus, our results validate the use of DCL for targeting thiol-disulfide oxido-reductases.     

Variable Temperature Single Crystal EPR Studies of Cu(II) in Dipotassium Diaquabis(Malonato-<Emphasis Type="Italic">κ</Emphasis><Superscript>2</Superscript><Emphasis Type="Italic">O,O</Emphasis>′) Nickelate Dihydrate: An Example of Contaminated Ground State

Single crystal X-band electron paramagnetic resonance (EPR) studies on divalent copper ions embedded in dipotassium diaquabis(malonato-κ ² O,O′) nickelate dihydrate have been performed at 300, 123 and 77 K to understand the nature of Jahn–Teller distortion in the paramagnetic host lattice. The angular variation of the EPR spectra reveals the presence of two sites, with one site not showing hyperfine resolution even at 77 K. The spin-Hamiltonian parameters of this six-coordinated Cu(II) ion, evaluated from EPR spectra at various temperatures, are:

• 300 K: g ₁₁ = 2.125, g ₂₂ = 2.118, g ₃₃ = 2.290, no copper hyperfine resolution
• 123 K: g ₁₁ = 2.229, g ₂₂ = 2.113, g ₃₃ = 2.319 and A ₁₁ = 5.02, A ₂₂ = 3.82, A ₃₃ = 6.87 mT
• 77 K: g ₁₁ = 2.224, g ₂₂ = 2.114, g ₃₃ = 2.324 and A ₁₁ = 5.32, A ₂₂ = 3.90, A ₃₃ = 7.06 mT

respectively. The low value observed for A ₃₃ at 123 and 77 K has been explained by assuming a ground state \({\text{d}}_{{x^{2} - y^{2} }}\) wave function for Cu(II) ions, contaminated with the excited state \({\text{d}}_{{z^{2} }}\). From the temperature dependence of the EPR spectra, the Cu(II) ions can be considered as a static Jahn–Teller system, with contaminated ground state. The admixture coefficients and bonding parameters have also been calculated by combining EPR and optical data. The EPR spectrum of powder sample confirms single crystal data.

     

Time Scale Separation and Dynamic Heterogeneity in the Low Temperature East Model

We consider the non-equilibrium dynamics of the East model, a linear chain of 0–1 spins evolving under a simple Glauber dynamics in the presence of a kinetic constraint which forbids flips of those spins whose left neighbor is 1. We focus on the glassy effects caused by the kinetic constraint as ${q\downarrow 0}$ , where q is the equilibrium density of the 0s. In the physical literature this limit is equivalent to the zero temperature limit. We first prove that, for any given L = O(1/q), the divergence as ${q\downarrow 0}$ of three basic characteristic time scales of the East process of length L is the same. Then we examine the problem of dynamic heterogeneity, i.e., non-trivial spatio-temporal fluctuations of the local relaxation to equilibrium, one of the central aspects of glassy dynamics. For any mesoscopic length scale L = O(q ^?γ ), γ < 1, we show that the characteristic time scale of two East processes of length L and λ L respectively are indeed separated by a factor q ^?α , α = α(γ) > 0, provided that λ ≥ 2 is large enough (independent of q, λ = 2 for γ < 1/2). In particular, the evolution of mesoscopic domains, i.e., maximal blocks of the form 111..10, occurs on a time scale which depends sharply on the size of the domain, a clear signature of dynamic heterogeneity. A key result for this part is a very precise computation of the relaxation time of the chain as a function of (q, L), well beyond the current knowledge, which uses induction on length scales on one hand and a novel algorithmic lower bound on the other. Finally we show that no form of time scale separation occurs for γ = 1, i.e., at the equilibrium scale L = 1/q, contrary to what was assumed in the physical literature based on numerical simulations.     

A DFG-based cavity ring-down spectrometer for trace gas sensing in the mid-infrared

Continuing studies into an all-diode laser-based 3.3 μm difference frequency generation cavity ring-down spectroscopy system are presented. Light from a 1,560 nm diode laser, amplified by an erbium-doped fibre amplifier, was mixed with 1,064 nm diode laser radiation in a bulk periodically poled lithium niobate crystal to generate 16 μW of mid-IR light at 3,346 nm with a conversion efficiency of $0.05\,\%\,{\text{W}}^{-1}\,{\text{cm}}^{-1}$ . This radiation was coupled into a 77 cm long linear cavity with average mirror reflectivities of 0.9996, and a measured baseline ring-down time of $6.07\pm 0.03\,\upmu{\rm s}$ . The potential of such a spectrometer was illustrated by investigating the $P(3)$ transition in the fundamental $\nu_{3}(F_{2})$ band of ${\text{CH}}_4$ both in a 7.5 ppmv calibrated mixture of ${\text{CH}}_4$ in air and in breath samples from methane and non-methane producers under conditions where the minimum detectable absorption coefficient ( $\alpha_{\rm min}$ ) was $2.8 \times 10^{-8}\,{\rm cm}^{-1}$ over 6 s using a ring-down time acquisition rate of 20 Hz. Allan variance measurements indicated an optimum $\alpha_{\rm min}$ of $2.9\times 10^{-9}\,{\rm cm}^{-1}$ over 44 s.