以间质隔离法研究CH3O分子在p-H2间质中的红外吸收光谱

本研究利用低温间质隔离技术搭配红外光谱仪研究CH3ONO在p-H2间质中的光解产生CH3O。实验观察到位于689.3/694.6cm-1、945.9/951.7cm-1、1041.8cm-1、1224.7cm-1、1235.5cm-1、1347.7cm-1、1365.4cm-1、1427.5cm-1、1519.5cm-1、1522.3cm-1等处的CH3O红外吸收谱线,并分析得出各振动模式分别为电子态E1/2a1对称性的ν6、电子态E1/2a2对称性的ν6、电子态E3/2对称性的ν2、电子态E3/2e对称性的ν6、电子态E1/2e对称性的ν6、电子态E1/2a1对称性的ν5、电子态E3/2对称性的ν2、电子态E1/2对称性的ν2、电子态E3/2e对称性的ν5及电子态E1/2e对称性的ν5。     

以间质隔离法研究CH3O分子在p-H2间质中的红外吸收光谱

本研究利用低温间质隔离技术搭配红外光谱仪研究CH3ONO在p-H2间质中的光解产生CH3O。实验观察到位于689.3/694.6cm-1、945.9/951.7cm-1、1041.8cm-1、1224.7cm-1、1235.5cm-1、1347.7cm-1、1365.4cm-1、1427.5cm-1、1519.5cm-1、1522.3cm-1等处的CH3O红外吸收谱线,并分析得出各振动模式分别为电子态E1/2a1对称性的ν6、电子态E1/2a2对称性的ν6、电子态E3/2对称性的ν2、电子态E3/2e对称性的ν6、电子态E1/2e对称性的ν6、电子态E1/2a1对称性的ν5、电子态E3/2对称性的ν2、电子态E1/2对称性的ν2、电子态E3/2e对称性的ν5及电子态E1/2e对称性的ν5。     

氟化类金刚石薄膜的拉曼和红外光谱结构研究

关键词：     

Far infrared heterodyne detectors

The characteristics of far infrared detectors are reviewed. Three detectors, the InSb hot electron bolometer, the GaAs Schottky diode and the Josephson point contact junction, have been incorporated as mixers into sensitive heterodyne systems. The performances of existing heterodyne receivers/radiometers are described and compared. Other applications of submillimeter heterodyne techniques are discussed.Supported in part by the U. S. Army Research Office and the Department of the Air Force.     

Far infrared and phase transitions in ferroelectric materials

Abstract

A number of far infrared absorption bands are found in molecular and hydrogen-bonded crystals when there are several formula units in the primitive cell. They are very sensitive to the crystal structure and constitute a convenient probe for looking at small changes in the structure, especially at low temperatures where there is a lack of X-Ray data. As well known examples, the case of LTT (Lithium Thallium Tartrate) where the absorption band observed at 21 cm^?1 at room temperature softens down to 8 cm^?1 at the Curie temperature (T_c = 12 K), and LiNH₄SO₄ which has a phase transition at 26 K, will be considered.

It is less known that some ferroelectric crystals can be studied as very thick single crystal plates (thickness t up to 10 mm) at 4 K, and they show in some cases a far IR transmission that is much higher than expected from the study of thin plates (i.e. t = 20 μm). In fact the transmission does not decrease very much when thickness is higher than some specific value t ₀/2. The crystal is not homogeneous at 4 K. A model with a far IR absorbing surface layer (thickness t ₀/2) and a transparent bulk is a good first approximation.

At some temperature T ₀ located between liquid helium and liquid nitrogen temperatures, the center of the bulk undergoes a phase transition from the absorbing phase into the transparent one. When temperature is still lowered, the transparent phase is extended towards the surface with an incommensurate phase between the surface and the bulk.     

单壁碳纳米管晶格振动模及红外吸收光谱的研究

碳纳米管晶格动力学的研究可以提供碳纳米管结构和螺旋性等方面的相关信息。在室温下测量了单壁碳纳米管的红外吸收光谱,首次在透射法模式下观察到了其晶格振动模的红外吸收峰,通过与晶格动力学理论计算值对照,做出了振动模的初步归属。讨论了单壁碳纳米管高频振动模与管径的关系,并与高取向热解石墨振动模进行了对比。结果表明,红外吸收光谱包含有碳纳米管的许多信息,是研究其晶格动力学的有效方法。     

Far infrared study of optical phonons in K1?xRbxI mixed crystals

The farinfrared properties of mixed alkalai halide crystals, K_1–xRb_xI, x=0.25 and 0.50, have been studied at room temperature. Dispersive Fourier transform spectroscopy (DFTS) has been used to obtain the complex dielectric function of these samples. Infrared-active phonon modes are observed at frequencies close to those of KI and RbI. This two-mode behavior is in agreement with theoretical predictions.     

离子束合成钇硅化物的结构及红外谱特征

将稀土金属钇离子注入到n型单晶Si(111)中制备出钇硅化物埋层.利用x射线衍射、卢瑟福背散射和傅里叶红外吸收谱测量分析了样品的结构、原子的埋层分布和振动模式.结果表明，Y离子在注入过程中已与基底中的Si原子形成了YSi2结构相.真空下的红外光辐照处理促使YSi2择优取向生长，埋层中Si与Y的平均原子浓度比由24下降为20，与六方YSi2的化学计量比一致.还给出了钇硅化物的特征红外吸收谱.     

Infrared absorption spectra of 2,3- and 3,5-dichloroaniline

The infrared absorption spectra of 2,3- and 3,5-dichloroanilines have been recorded in the region 250–4000 cm⁻¹. The spectra of the latter are recorded in solid phase (KBr and Nujol mull) and in CS₂/CCl₄ and CHCl₃ solutions while that of the former in thin film only. The spectra have been analysed assuming C ₃ and C_2v point group symmetry respectively and a tentative assignment of the observed bands to different fundamental modes has been made.     

Far infrared absorption of a-GeSe

Far infrared absorption measurements have been made on a series of a-Ge_xSe_1?x films with near equiatomic compositions. The only sharp feature is an absorption line at 260cm^-1, and the compositional dependance of this feature is correctly described by a model in which the Ge(Se) atoms are 4(2) fold co-ordinated. There is no evidence in our amorphous samples of any absorption band in the frequency range (160?190cm^?1) of the major IR active modes of 3:3 fold co-ordinated crystalline GeSe.     

Far infrared absorption by acceptor states in tellurium

Transmission spectra of slightly antimony-doped tellurium were measured at 2K. Absorptions due to transitions of holes from the acceptor ground state to the excited state and to the valence band were observed. Reflecting the double-maximum structure of the valence band, the ground state splits into two levels, the binding energies of which are found to be 1.31 and 1.47 meV, respectively.     

射频远红外波导自由电子激光器的新特性

 提出了用波导本征模展开的方法计算射频调制的短脉冲电子束在矩形波导中的自发辐射。模展开系数决定了辐射进入TE_0n模的功率。将短脉冲理想化为时间上的d函数,可以发现当辐射频率正好等于用来调制电子束的射频的整数倍时,辐射模式表现为“纯”的波导本征模,此时辐射功率最强。用此方法估算了设计中的上海远红外波导自由电子激光器的辐射功率。     

射频远红外波导自由电子激光器的新特性

提出了用波导本征模展开的方法计算射频调制的短脉冲电子束在矩形波导中的自发辐射。模展开系数决定了辐射进入TE0n模的功率。将短脉冲理想化为时间上的d函数,可以发现当辐射频率正好等于用来调制电子束的射频的整数倍时,辐射模式表现为“纯”的波导本征模,此时辐射功率最强。用此方法估算了设计中的上海远红外波导自由电子激光器的辐射功率。     

反常吸收与高质量的远红外光谱

在水汽含量恒定但相对湿度较大的情况下,远红外光谱仪得不到理想的100%线。这表明过高的水汽含量将会导致反常吸收现象。反常吸收的出现将严重影响远红外光谱的质量。研究了光谱仪内部空气相对湿度和光谱分辨率对反常吸收的影响,发现降低水汽含量和采用适当光谱分辨率可以有效抑制反常吸收现象,对获得高质量的远红外光谱很有益处。在无反常吸收现象发生的实验条件下,采用"湿度中和法"在空气湿度波动的情况下也可以得到理想的100%线,这为快速获得高质量的远红外光谱提供了新测量方法。     

钛酸锶钡纳米管的制备及其红外吸收性能研究

首次采用溶胶凝胶法结合通孔阳极氧化铝模板, 成功制备出了钛酸锶钡纳米管. 该制备工艺简单、易实现而且成本低. 首先制备通孔阳极氧化铝模板和钛酸锶钡溶胶, 然后通过浸渍加上匀胶的方法将钛酸锶钡溶胶引入到通孔阳极氧化铝模板的纳米孔洞中, 最后在650℃下煅烧1 h形成钛酸锶钡纳米管. X射线衍射(XRD)证明, 制得的钛酸锶钡纳米管为立方钙钛矿相, 主要沿(110)晶向生长. 扫描电子显微镜(SEM)显示, 钛酸锶钡纳米管外径、内径和管长分别为75 nm, 50 nm, 16 μm. 傅里叶变换显微红外光谱仪(FTIR)测试结果表明在波数为1350-1650 cm^-1红外波段, 阳极氧化铝/钛酸锶钡纳米管复合结构较钛酸锶钡薄膜有两处明显的吸收峰, 吸收峰位于1470和1550 cm^-1处, 与通孔阳极氧化铝模板相比其吸收峰强度高出一倍, 最后分析了出现这一现象的可能原因.     

Far infrared absorption by pure and hydrogenated amorphous silicon

Measurements of the far infrared absorption coefficient of pure and hydrogenated a-Si are reported. The results are similar to earlier data on pure a-Si though we find different relative strengths of the three absorption bands. The present data are sufficiently accurate at low frequencies to observe structure on the lowest frequency peak, and the behaviour of this upon hydrogenation is consistent with the charged void model proposed earlier.     

Detection of minor constitutents of the stratosphere by far infrared emission spectroscopy

The far infrared (30–110 cm^–1) emission spectrum of the lower stratosphere has been measured from balloon altitudes with a high resolution (0.06 cm^–1) rapid-scanning Michelson interferometer on two flights in 1976. The quality and resolution of the spectra obtained from two altitudes have permitted a careful search for emission lines from environmentally important molecules such as HCl, NO₂, OH, H₂O₂, and CO, among the more prominent and well-known features due to H₂O, O₃ and O₂. Column densities have been determined for H₂O and O₃ and upper limit estimates have been made from tentative identifications of several other constituents. However, the large angular field of view observed by the instrument prevented the determination of concentration profiles from atmospheric limb scans to the horizon. The possible future directions of this technique are outlined on the basis of operating experience over a 6 year programme. The viability of this method of monitoring the concentrations of minor constituents in the stratosphere is discussed with respect to other equivalent techniques.     

直接键合InP-GaAs结构界面的特性研究

通过对直接键合InP-GaAs结构的红外吸收光谱分析以及断面扫描电子显微镜观察发现，样品制备过程中不均匀的外加压强导致InP-GaAs交界面局部出现了不连续过渡的空间层，实验上将熔融石蜡渗透并被填充到该空间层，利用其对3.509μm波长光的强烈吸收特性可表征 这种局部的键合不连续区域，二维扫描测试样品不同区域的吸收谱得到3.509μm波长吸收强 度等值线图，从而描绘出外加压强的不均匀分布.实验上通过改进键合装置的施压均匀性， 得到了连续过渡界面且均匀键合的InP-GaAs结构，利用这种均匀键合技术有望制备大尺寸器 件例如光学微腔等. 关键词： 晶片直接键合 界面 红外吸收光谱     

Infrared absorption spectra studies in (NaNO3–NaNO2) system

A complete infrared study of the mixed crystal system of NaNO₃ and NaNO₂ is carried out in the region 600—3000 cm^—1 at room temperature. The study includes fundamental internal normal vibrations of the NO^—₂ and NO^—₃ ions. The IR spectra, spectral band shape intensities, combination modes, and frequencies of the internal modes were studied as a function of NO^—₃ ion concentration. Special attention is paid to the bending mode, the combination mode, and a symmetric stretching mode.     

纯铌酸锂晶体红外光谱的低温研究

测量了同成分纯铌酸锂的低温红外光谱,发现低温下铌酸锂晶体将会出现位于3200 cm^-1左右的新红外吸收峰.研究发现该峰与晶体中的氢离子无关,并且其峰强和峰形都随温度的升高发生复杂的变化.基于上述实验结果,认为该峰应该起源于电子在相邻的小极化子（Nb⁴⁺_Li）和自由极化子（Nb⁴⁺_Nb）之间的跃迁.另外,通过拟合发现新红外吸收峰可分解成三个高斯峰,这三峰应归因于能量有细微差别的三种跃迁. 关键词： 铌酸锂 红外吸收光谱 杂质缺陷