Diagnostics of laser-ablated carbon plumes by photoionization using a tunable laser

Tunable laser pulses at wavelengths from 250 to 880 nm were fired at plumes produced by laser ablation of a carbon target in He atmosphere. We observed an electrical current due to photoionization, which roughly reflected the behavior of carbon clusters in the plume. The photoionization current had dynamic temporal variations, comprising a rapid increase at the beginning (T_D<0.2 ms, where T_D is the time after a YAG laser pulse for laser ablation irradiates the target), a gradual increase for 0.2D<3 ms, and a slow decrease for T_D>7 ms. The increasing phase of the photoionization current was synchronized with the decreasing phase of C₂ radical density. For He gas pressures lower than 0.8 Torr no photoionization current was detected. The growth rate of the photoionization current was higher for a higher He gas pressure.     

工作在可见和紫外波段的自由电子激光器

Madey指出用直线加速器,限制了电子束束流密度,使得自由电子激光器可能达到的短波长极限为1μm左右。本文提出利用自由电子激光器的高次谐波运转,用直线加速器可望获得可见和紫外波段的短波长激光。实现自由电子激光器高次谐波运转的关键是建立高K值的Wiggler磁场。     

A novel structure of visible semiconductor lasers

Terraced substrate inner current stripe lasers emitting in the range of 750–780 nm are developed with very simple fabrication processes. The lasers have good performance of cw room temperature, linear light-current output over 30 mW per facet and maintain stable fundamental transverse and longitudinal mode of 2–4 times current threshold. The current threshold of 25 mA under cw room temperature operation has been achieved.     

High-quality and high-efficiency machining of glass materials by laser-induced plasma-assisted ablation using conventional nanosecond UV, visible, and infrared lasers

This paper reports the micromachining of fused quartz and Pyrex glass by laser-induced plasma-assisted ablation (LIPAA) using a conventional nanosecond laser at wavelengths 266 nm, 532 nm, and 1064 nm, respectively. High-quality surface structuring can be achieved at each of these wavelengths. The micrograting formed has periods of 14 7m at 266 nm, 20 7m at 532 nm, and 30 7m at 1064 nm, respectively. The ablation rate using a 266 nm laser is much larger than that at longer wavelengths. The ablation thresholds of laser fluence are 0.7 J/cm² for 266 nm, 1.5 J/cm² for 532 nm and 3.7 J/cm² for 1064 nm, respectively. The 532 nm and 1064 nm lasers enable hole drilling in 0.5 and 2.0-mm thick fused quartz and Pyrex glass substrates of about 0.7-0.8 mm in diameter. However, the less destructive through channel can be only formed in Pyrex glass by using a 532 nm laser.     

A new generation of ultra-violet/visible gas lasers

The field of ultra-violet/visible gas lasers has undergone a rapid expansion in the past three years since the discovery of the first rare gas monohalide excimer laser. There are now many new high power ultra-violet and visible lasers available with demonstrated efficiencies exceeding 1%. This review of the field emphasises the common properties of these laser systems and indicates their potential impact on commercial photochemical processes.     

A study of the early stages of the kinetics of titanium oxidation by Auger electron spectroscopy and mirror electron microscopy

The early stages of titanium oxidation have been followed by Auger Electron Spectroscopy and Mirror Electron Microscopy. The influence of the temperature and the oxygen pressure have been determined m the 100–600°C and 10^?9? 10^?7 Torr ranges. The surface potential variations measured by MEM reveal 4 different stages, while AES measurements indicate only 2 stages. The correlation between the various stages is given, as well as a qualitative interpretation.     

Upconversion of IR radiation into the visible and UV ranges

A review of theoretical and experimental results on the upconversion of IR radiation due to resonant nonlinear phenomena in metal vapors is presented. Various experimental schematics providing high quantum conversion efficiency and the feasibility of converting an arbitrary IR wavelength are discussed.     

Semiconductor disk lasers for the generation of visible and ultraviolet radiation

Recent developments in semiconductor disk lasers (SDLs) generating visible or ultraviolet light are reviewed. After an introduction on potential applications, we discuss how the combination of vertical‐emitting semiconductor GaAs‐based structures and intra‐cavity nonlinear conversion techniques can be successfully exploited to uniquely meet demands for continuous‐wave radiation in the visible and ultraviolet spectral range. To do so, an overview of the device operating principles and performance is presented highlighting the underlying material considerations, semiconductor structural designs, thermal management techniques and suitable cavity configurations. This summary is completed by a presentation of new developments in the field, with a particular focus on the trends towards miniaturization.     

Photoablation by UV and visible laser radiation of native and doped biological tissue

Photoablation studies of biological material (human cornea) with UV and visible laser light show that effective, apparently non-conventional thermal photoablation can be achieved by introducing energy absorbing dopants in the tissue. Previously unknown high ablation rates of 80 Gmm/pulse have been observed. The results allow one to clearly postulate different ablation mechanisms for increasing laser fluence. The results are compared with the photoablation rates observed with 193 nm UV laser light on undoped human cornea. Explosive desorption has been found the dominant process involved.     

Cluster formation in UV laser ablation plumes of ZnSe and ZnO studied by time-of-flight mass spectrometry

The composition of nitrogen laser (wavelength 337 nm, pulse width 3 ns) induced ablation plumes from ZnSe and ZnO targets was studied at different laser fluences using a time-of-flight mass spectrometer. In the case of ZnSe, abundant ion signals corresponding to Se and ZnSe clusters, some of which were Se-rich, were detected with fluence-dependent distributions. At a laser fluence of 1250 J m^-2, clusters with elevated intensity were observed at sizes of 6, 13, 19, 23 and 33 ZnSe molecules (magic numbers), which match quite well with the earlier observation by others of magic numbers of chemically similar ZnS produced by a conventional vaporization and quenching scheme. In the case of ZnO, we detected the presence of atomic Zn and molecular species of ZnO, as well as a series of (ZnO)_n-type clusters with fluence-dependent distributions. Unlike the case of ZnSe, no magic numbers were observed for ZnO. PACS 61.46.+w; 82.80.Rt; 42.62.-b; 81.16.Mk     

On the pumping of plasma lasers by a high-frequency-modulated electron beam

The possibility of effective pumping of plasma lasers by a high-frequency-modulated electron beam, i.e. an electron beam in the form of a periodic train of electron bunches, is discussed. It is shown that if such parameters of the medium as the relaxation times of the electron temperature ρ_Te and the electron density ρ_Ne are in agreement with the pulse width ρ_p and the interval between pulses, 1/?_m, this will facilitate effective laser pumping and amplitude modulation of the laser radiation. Existing microwave tubes, such as a traveling-wave tube and a klystron, provide the required parameters of a periodic train of current pulses (electron bunches) over a wide range of pulse widths ρ_p and pumping current amplitudes.     

A comparison between shake-up and UV charge-transfer transitions

The He(II) spectra of the unsubstituted metallocenes {M(η-C₅H₅)₂}, M  V, Cr, Mn, Fe, Co, Ni and Ru, and of {Mn(η-C₅H₄Me)₂} are reported; both He(I) and He(II) spectra of some decamethylmetallocenes {M(η-C₅Me₅)₂}, where M  Mg, V, Cr, Mn, Fe, Co and Ni, are also given. Intensity changes between the He(I) and He(II) spectra are shown to provide a reliable guide to band assignment. A ligand field treatment of the decamethylmanganocene cation, including limited configuration interaction, gives values for Δ₂, B and C; these values are also in good agreement with the photoelectron spectra of {M(η-C₅Me₅)₂} where M  V, Cr and Fe. Overlap between the ligand and metal “d” band structures prevents complete assignment in the cases of Co and Ni.     

Characterization of laser-ablated and chemically reduced silver colloids in aqueous solution by UV/VIS spectroscopy and STM/SEM microscopy

Silver colloids in aqueous solution were studied by different scanning microscopy techniques and UV/VIS spectroscopy. The silver colloids were produced either by chemical reduction or by nanosecond laser ablation from a solid silver foil in water. Variation of laser power and ablation time leads to solutions of metal clusters of different sizes in water. We characterized the electronic absorption of the clusters by UV/VIS spectroscopy. STM (scanning tunneling microscope) imaging of the metal colloids shows atomic resolution of rod- or tenon-like silver clusters up to 10-nm length formed by laser ablation. Our scanning electron microscope measurements, however, show that much larger silver colloids up to 5-μm length are also formed, which are not visible in the STM due to their roughness. We correlate them with the long-wavelength tail of the multimodal UV/VIS spectrum. The silver colloids obtained by chemical reduction are generally larger and their electronic spectra are red-shifted compared to the laser-ablated clusters. Irradiation of the colloid solution with nanosecond laser pulses of appropriate fluence at 532 nm and 355 nm initially reduced the colloid size. Longer irradiation at 355 nm, however, leads to the formation of larger colloids again. There seems to be a critical lower particle size, where silver clusters in aqueous solution become unstable and start to coagulate. Received: 24 June 2002 / Revised version: 25 July 2002 / Published online: 25 October 2002 RID="*" ID="*"This work is part of the thesis of H. M?ltgen RID="**" ID="**"Corresponding author. Fax: +49-211/811-5195, E-mail: kleinermanns@uni-duesseldorf.de     

Time-resolved spectroscopy measurements of a titanium plasma induced by nanosecond and femtosecond lasers

We have studied the plasma induced at the surface of a titanium target following irradiation with femtosecond and nanosecond laser pulses. Time-resolved imaging and spectroscopic measurements allowed us to evidence some features specific to the femtosecond-laser-induced plasma. In this ultrashort interaction regime, we could discriminate between three different velocity populations in the plasma expansion. Coulomb explosion firstly creates highly energetic Ti⁺ ions, which are followed by atomic neutral titanium and lastly by nanoscale titanium oxide clusters. Received: 28 September 2001 / Accepted: 9 July 2002 / Published online: 25 October 2002 RID="*" ID="*"Corresponding author. Fax: +33-1/6931-9996, E-mail: albert@ensta.fr     

Mechanism of electron violent acceleration by extra-intense lasers in vacuum

The mechanism underlying the electron capture acceleration (Phys. Rev. E 58 (1998) 6575) is studied. It is found that the longitudinal electric field, resulting from the transverse spatial gradient of the laser fields, is responsible for the violent electron acceleration while the transverse fields play the role of confining the electron inside the laser beam.     

Surface modification of pure titanium by pulsed electron beam

The microstructure, hardness and corrosion resistance of commercially pure Ti treated by low energy high current pulsed electron beam (LEHCPEB) have been investigated. The thin near-surface melted layer rapidly solidified into β and subsequently transformed into ultrafine α′ martensite. This has led to a drastic improvement of the corrosion properties and a significant increase (more than 60%) in hardness of the top surface.     

Computer programs for processing of UV and visible absorption spectra

A mathematical method for calculation of the stability constants of complexes by spectrophotometric data is represented. The program algorithm SQCONS is developed based on the method of nonlinear squares. As a test example, a calculation of the constant and the molar coefficients of extinction of the monosulfate complex CuSO ₄ ⁰ is presented. Institute of Mineralogy and Petrography of the Siberian Division of the Russian Academy of Sciences, 3, Universitetskii Ave., Novosibirsk, 630090, Russia. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 65, No. 4, pp. 581–586, July–August, 1998.     

Dynamic mechanical properties of interpenetrating polymer networks formed by UV curing processes

Two-component interpenetrating polymer networks (IPN) were made by stepwise synthesis by UV-irradiated polymerization and heat curing. The mechanical properties of normal IPN, inverse IPN and SIN (simultaneous interpenetrating networks) prepared with acrylate and epoxy were studied. Unique mechanical properties were found in each case. All of these iPN systems were composed of the individual preswollen networks. A homogeneous system is produced in the inverse IPN and SIN, while a heterogeneous system is brought about in the normal IPN. Glass transition temperatures for the inverse IPN and the SIN are lower than the normal IPN, and are attributed to molecular packing effects.