Residual stress relaxation in cleaved fibers

The relaxation of intrinsic stress, in particular, the frozen-in stress in the vicinity of the cleaved end of optical fibers is studied. Stress distribution is measured at many cross sections along the fiber using a conventional polariscopic stress measurement technique. Fibers drawn with different tensions are used to study the dependence of stress release on the draw tension. From the measured frozen-in stress, the frozen-in viscoelastic stress is studied through the calculation of mean axial stress. The dependence of the release of viscoelastic stress on the draw tension is established. Though the presence of residual stress shows a sudden decline as a consequence of cleaving, it is not completely released at the cleaved end and is explained by the frozen-in viscoelastic stress in the optical fiber. The study shows that the relaxation of frozen-in viscoelastic stress near the cleaved fiber end is only a fraction of the amount of total residual stress in the optical fiber.     

Effect of asymmetric stress relaxation on the polarization-dependent transmission characteristics of a CO2 laser-written long-period fiber grating

The effect of stress-induced birefringence on polarization-dependent transmission characteristics was thoroughly investigated for a long-period fiber grating (LPFG) that was fabricated by use of a stress relaxation method with a CO2 laser. A series of two-dimensional axial stress profiles for one complete period of a LPFG was measured with an optical tomographic measurement technique. We found that the asymmetry in the stress distribution of the cladding was much larger than in the core of the LPFG. The splitting of polarization-dependent loss peaks in the optical transmission spectrum was calculated based on the measured asymmetric stress profiles and was compared with an experimental result.     

CO(2) laser writing of long-period fiber gratings in optical fibers under tension

We demonstrate experimentally that the efficiency of writing a long-period fiber grating in a single-mode fiber by CO(2) laser pulses increases significantly with the axial stress applied along the fiber. We attribute the enhancement in writing efficiency to the generation of nonuniform inelastic frozen-in strains across the fiber under tension by CO(2) laser heating. Controlling the axial stress distribution along a fiber during the CO(2) laser writing process thus provides an additional degree of freedom for control of the grating characteristics.     

Residual stress relaxation in the core of optical fiber by CO(2) laser irradiation

We observed residual stress relaxation by CO(2) laser irradiation in the cores of optical fibers by direct stress measurement. It was demonstrated that the mechanical stress was fully relaxed by CO(2) laser irradiation and that the remaining stress in the core was thermal stress that was due to a mismatch of the thermal expansion coefficients of the fiber core and cladding. The net core stresses after relaxation were 17, 68, and 203 MPa in Ge-B-codoped fibers drawn at 0.53, 1.38, and 3.48 N, respectively. Changes in the refractive indices of the cores as a result of residual stress relaxation were also estimated.     

Design of double-coated optical fibers to minimize long-term axial-strain-induced microbending losses

The design of double-coated optical fibers to minimize long-term axial-strain-induced microbending losses is investigated. The microbending loss is dominated by the compressive radial stress at the interface between the glass fiber and primary coating. To know the long-term axial-strain-induced microbending losses in double-coated optical fibers, the stresses in fibers are analyzed by the viscoelastic theory. To minimize these long-term microbending losses, the thickness and Young's modulus of the secondary coating should be decreased if the strength of coating is satisfied. Meanwhile, the Poisson's ratio of the primary coating should be increased, but the Young's modulus of the primary coating and relaxation time of the secondary coating should be decreased. Alternatively, the radius and relaxation time of the primary coating exist their optimum values. The long-term axial-strain-induced microbending losses in single-coated optical fibers are also discussed.     

Transient binding and dissipation in cross-linked actin networks

In contrast with entangled actin solutions, transiently cross-linked actin networks can provide highly elastic properties while still allowing for local rearrangements in the microstructure-on biological relevant time scales. Here, we show that thermal unbinding of transient cross-links entails local stress relaxation and energy dissipation in an intermediate elasticity dominated frequency regime. We quantify the viscoelastic response of an isotropically cross-linked actin network by experimentally tuning the off rate of the transiently cross-linking molecules, their density, and the solvent viscosity. We reproduce the measured frequency response by a semiphenomenological model that is predicated on microscopic unbinding events.     

Nonlinear viscoelastic dynamics of nanoconfined wetting liquids

The viscoelastic dynamics of nanoconfined wetting liquids is studied by means of atomic force microscopy. We observe a nonlinear viscoelastic behavior remarkably similar to that widely observed in metastable complex fluids. We show that the origin of the measured nonlinear viscoelasticity in nanoconfined water and silicon oil is a strain rate dependent relaxation time and slow dynamics. By measuring the viscoelastic modulus at different frequencies and strains, we find that the intrinsic relaxation time of nanoconfined water is in the range 0.1-0.0001 s, orders of magnitude longer than that of bulk water, and comparable to the dielectric relaxation time measured in supercooled water at 170-210 K.     

Rheology of active filament solutions

We study the viscoelasticity of an active solution of polar biofilaments and motor proteins. Using a molecular model, we derive the constitutive equations for the stress tensor in the isotropic phase and in phases with liquid crystalline order. The stress relaxation in the various phases is discussed. Contractile activity is responsible for a spectacular difference in the viscoelastic properties on opposite sides of the order-disorder transition.     

Metachronal propulsion of non-Newtonian viscoelastic mucus in an axisymmetric tube with ciliated walls

Cilia-induced flow of viscoelastic mucus through an idealized two-dimensional model of the human trachea is presented.The cilia motion is simulated by a metachronal wave pattern which enables the mobilization of highly viscous mucus even at nonzero Reynolds numbers.The viscoelastic mucus is analyzed with the upper convected Maxwell viscoelastic formulation which features a relaxation time and accurately captures normal stress generation in shear flows.The governing equations are transformed from fixed to wave(laboratory)frame with appropriate variables and resulting differential equations are perturbed about wave number.The trachea is treated as an axisymmetric ciliated tube.Radial and axial distributions in axial velocity are calculated via the regular perturbation method and pressure rise is computed with numerical integration using symbolic software MATHEMATICA^‘TM’.The influence of selected parameters which is cilia length,and Maxwell viscoelastic material parameter i.e.relaxation time for prescribed values of wave number are visualized graphically.Pressure rise is observed to increase considerably with elevation in both cilia length and relaxation time whereas the axial velocity is markedly decelerated.The simulations provide some insight into viscous-dominated cilia propulsion of rheological mucus and also serve as a benchmark for more advanced modeling.     

Effect of annealing on the structural, optical and electrical properties of ZnO thin films by spray pyrolysis

Zinc oxide thin films have been deposited on glass substrates at a substrate temperature of 673 K by spray pyrolysis. The samples are annealed in ambient atmosphere at various temperatures. The effect of annealing on structural, electrical, and optical properties of ZnO films has been investigated. X-ray diffraction patterns show that crystallinity of the ZnO films has been improved after annealing. The morphology of ZnO thin films is studied by atomic force microscopy. The tensile strain (compressive stress) is found to decrease with increase in annealing temperature which indicates the relaxation of tensile strain in ZnO thin films. A decrease in energy band gap is observed with increase of annealing temperature. The mechanism of blue-green luminescence of ZnO thin film has been analyzed. The resistivity is found to decrease with annealing temperature.     

光纤涂料对光纤衰减的影响

分析光纤涂料的厚度、应力松驰、热处理及辐射等对光纤衰减的影响。提出应根据光纤技术要求选择既符合工艺条件又与光纤材料相匹配的涂料,并严格控制涂料厚度和同心度,以保证光纤质量。     

Determination of stress-induced intrinsic birefringence in a single-mode fiber by measurement of the two-dimensional stress profile

The two-dimensional (2-D) axial stress profile of a single-mode fiber is obtained with an optical tomographic measurement technique. All stress components of the fiber are calculated from a measured axial stress profile. We demonstrate that the differential group delay induced by intrinsic nonsymmetric stress as well as the induced linear birefringence between two orthogonal polarization modes can be determined with an analytic technique based on a vector perturbation method from a measured asymmetric 2-D stress distribution.     

Optical measurement of the viscoelastic and biochemical responses of living cells to mechanical perturbation

We have developed an optical method for real-time monitoring of cellular motion in a natural environment with nanometer resolution. From the motion driven by small optical forces, we measured dynamic viscoelastic responses of living cells in the linear reversible region. Cytoplasmic gel-to-sol transition that was due to the disruption of the actin-filament framework was detected, and a linear release of Ca(2+) from intracellular storage that was related to submicrometer cell deformation was observed. The method was shown to be a powerful tool for studying the natural response of cells to mechanical perturbation.     

Correlation of electron spin resonance and optical absorption of K atoms in solid Ar

Electron spin resonance (ESR) and optical absorption spectra of K atoms embedded in Ar matrices have been measured simultaneously. ESR and optical spectra could be correlated comparing the effects of annealing and light induced site modifications. Electron spin relaxation times were estimated by saturation measurements. A large variety of ESR spectra was found which could be arranged into four groups according to their A and g factor matrix shifts. Two of these groups could be correlated with optical absorptions namely with the so-called red and blue triplet bands. The other two groups belong to K-(H₂O)_n complexes. Part of the absorption disappeared irreversibly upon annealing at about 12 K. There is considerable experimental evidence that this annealing process indicates the transition from an amorphous to a microcrystalline structure at about 12 K.     

Viscoelastic modeling of canine vocalis muscle in relaxation

Analysis of vocal fold vibration requires information on the viscoelastic properties of the vocalis muscle. The force response of two canine vocalis muscles was measured in one-dimensional, stepwise elongation of the tissue as a function of time with a computer-controlled ergometer. The viscoelastic behavior of the muscle in its passive state was demonstrated through the relaxation test. A quasilinear viscoelastic model was used to parametrize the relaxation function, and results are reported for various levels of strain. Furthermore, a model was used to obtain theoretical time-dependent stress-strain curves to compare with experimental data.     

Lactone polymers. V. Viscoelastic properties of poly-ε-caprolactone and poly-ε-thiocaprolactone

The viscoelastic properties of crystalline poly-ε-caprolactone and poly-ε-thiocaprolactone have been characterized and compared by stress relaxation and dynamic mechanical studies. The glass transition temperature of poly-ε-thiocaprolactone was shown to be -40°C at 1 Hz and appeared to be independent of the degree of crystallinity. The rate of viscoelastic relaxation for each polymer was independent of linear strain rate of a decade range. The density of each polymer over a wide temperature range was used to reduce the individual time-dependent modulus values to an arbitrary reference temperature. This reduction of stress relaxation data to a standard mechanical state obviated the requirement of vertical shift factors for construction of the respective master curves. The distribution of relaxation times was correlated with the glass transition and the crystalline melt temperature range for each polymer.     

Laser nonlinear-optical probing of silicon/SiO2 interfaces: Surface stress formation and relaxation

A nonlinear optical technique based on optical second harmonic generation in reflection is shown to provide information on the surface layer structure of semiconductor crystals, thin films and layered systems. The second harmonic intensity is sensitive to inhomogeneous stress in centrosymmetric materials via spatial selection rules and the appearance of an electric dipole contribution to the second order nonlinear optical susceptibility. The technique is used to monitor mechanical stress relaxation in the SiO₂/Si interface during several annealing procedures.     

Complex dynamics in gelling systems

We study the viscoelastic properties and the relaxation process in a gelling system by means of a minimal statistical-mechanics model. The model is based on percolation and bond fluctuation dynamics. The values for the critical exponents of the viscosity and elasticity agree with a part of the experimental observations and of the theoretical predictions. The obtained relaxation patterns well reproduce the behaviour observed in different gelling systems. Received 10 March 2002 and Received in final form 30 April 2002     

Characteristics of photoluminescence and Raman spectra of InP doped silica fiber

We fabricated a silica optical fiber doped with InP sandwiched in the core and the inner cladding layers by using the conventional modified chemical vapor deposition process. We presented the experimental X-ray analysis on the optical properties and found that compound InP was contained in the fiber core after annealing process. Broadband photoluminescence observed in InP doped fiber was well coincided with those coming from the recombination of deep levels in InP. The occurrence of temperature-dependent photoluminescence both at the lower and room temperature would be related with the localized defects and their confinement in the micro-network structure of Si-O-Si. The Raman spectra reveal that Si-O-In vibration would disorder the silica ring structures and enervate their vibrations.