Nuclear quadrupole interaction of199mHg-ferrocenethiol complexes

We determined the^199mHg nuclear quadrupole interaction (NQI) by time differential perturbed angular correlation in the following ferrocenethiol complexes with mercury: ferrocenethiol (v _Q =1253(4) MHz, =0); 1,1-ferrocenedithiol (47%v _Q =1555(8) MHz, =0.13(2); 25%v _Q =726(19) MHz, =0.81(2); rest unspecific); 2-ferrocenyl-ethanethiol (v _Q =1306(6) MHz, =0.17(1)); and a 1, 1-bis (2-mercapto-propylthio)ferrocene oligomer (v _Q =1411(5), =0). All NQIs are rather large with small asymmetry parameters, indicating essentially linear S-Hg-S bonds. The only exception is the minority fraction in 1,2-ferrocenedithiol which suggests the formation of a 1,3-dithia-2-mercura[3]ferrocenophane.     

Analytic study of power spectra of the tent maps near band-splitting transitions

Successive band-splitting transitions occur in the one-dimensional map x_i+1=g(x_i),i=0, 1, 2,... withg(x)=x, (0 x 1/2) –x +, (1/2 <x 1) as the parameter is changed from 2 to 1. The transition point fromN (=2ⁿ) bands to 2Nbands is given by=(2)^1/N (n=0, 1,2,...). The time-correlation function _i=x_ix₀/(x₀)²,x_i x_i–x_i is studied in terms of the eigenvalues and eigenfunctions of the Frobenius-Perron operator of the map. It is shown that, near the transition point=2, _i–[(10–42)/17] _i,0-[(102-8)/51]_i,1 + [(7 + 42)/17](–1)ⁱe^–yi, where2(–2) is the damping constant and vanishes at=2, representing the critical slowing-down. This critical phenomenon is in strong contrast to the topologically invariant quantities, such as the Lyapunov exponent, which do not exhibit any anomaly at=2. The asymptotic expression for _i has been obtained by deriving an analytic form of _i for a sequence of which accumulates to 2 from the above. Near the transition point=(2)^1/N, the damping constant of _i fori N is given by _N=2(^N-2)/N. Numerical calculation is also carried out for arbitrary a and is shown to be consistent with the analytic results.     

Conditional stability of multiple-charged solitons

The stability of the three-dimensional multiple-charged soliton solutions to the nonlinear field equations is studied by Lyapunov's method. It is proved that an absolutely stable soliton solution can not exist in any field model. By imposing the subsidiary condition ^pQ_i=0 (fixation of charges) we find a sufficient condition for stability of the stationary soliton which includes the inequality ^{k i} (Q ⁱ / ^k <0. An illustrative example is considered.     

Solution of coupled differential equations of soliton theory

We present the complete set of solutions of the coupled differential equations of the form ()²=(), ² =(). Equations of this form appear in several physical situations.     

Long-time tails in lattice Lorentz gases

We consider a Lorentz gas on a square lattice with a fraction c of scattering sites. The collision laws are deterministic (fixed mirror model) or stochastic (with transmission, reflection, and deflection probabilities ,, and respectively). If all mirrors are parallel, the mirror model is exactly solvable. For the general case a self-consistent ring kinetic equation is used to calculate the longtime tails of the velocity correlation function (0) (t) and the tensor correlation Q(0)Q(t) withQ= _{x y} . Both functions showt ^–2 tails, as opposed to the continuous Lorentz gas, where the tails are respectivelyt ^–2 andt ^–3. Inclusion of the self-consistent ring collisions increases the low-density coefficient of the tail in (0)(t) by 30–100% as compared to the simple ring collisions, depending on the model parameters.     

Thes-f model with Coulomb repulsion: Thermodynamics of two atomic cluster. Spin 1/2

A cluster of two atoms described by thes-f model with Coulomb repulsion has been considered. The interaction between localized 4f electrons (S=1/2) is taken in the molecular field approximation. The thermodynamic quantities like magnetization, specific heat and correlation functions n , n , S ^z n , S ^z n , S ^z (n –n ), n n and S ⁺ a ⁺ a as functions of temperature are presented for different band fillingN=0, 0.5, 1, 1.5, 2. The dependence of Curie temperature onN is calculated. The phase diagram forN=1 (T=0K) shows the possibility of existence of two phases: paramagnetic and ferromagnetic.The Curie temperature and the specific heat as functions ofN exhibit similar trends as found in experiments on doped magnetic semiconductors.     

Logically independent von Neumann lattices

Three definitions of logical independence of two von Neumann latticesP₁,P₂ of two sub-von Neumann algebras ₁, ₂ of a von Neumann algebra are given and the relations of the definitions clarified. It is shown that under weak assumptions the following notion, called logical independence is the strongest:A B 0 for any 0 A P₁, 0 B P₂. Propositions relating logical independence ofP₁,P₂ toC ^*-independence,W ^* independence, and strict locality of ₁, ₂ are presented.     

On the determination of the position of the energy level of surface recombination centres

A detailed analysis of the dependence of the surface recombination velocitys on the surface potential _s leads to the conclusion that the position of the surface recombination level with respect to the centre of the energy gapE _t -E _i does not coincide with the valueq _s *, while the surface recombination velocitys decreases to half its maximum value. The difference between the two quantities is negligible only when the width of the curves( _s ) between the points corresponding to the valuess=1/2s _max is greater than 8kT.

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s _s , E _t -E _{i s} , s . , s( _s ) , s=1/2s _max, 8kT.

     

Photon scattering on quasi-free neutrons in the reaction γd→γ′np and neutron polarizabilities

The possibility to obtain information on n scattering at intermediate energies from the reaction dnp is analyzed. To this aim, the differential cross sectiond ³ /d ,d _n dE _n and the scattering asymmetry with linearly polarized photons are calculated at photon energies 100 to 400 MeV in the diagrammatic approach. The pole diagrams of the impulse approximation are evaluated with realistic n and p scattering amplitudes. One-loop diagrams withnp rescattering in the final state and with meson-exchange and isobar currents are taken into account as well. The main contribution to the differential cross sectiond ³ /d ,d _n dE _n in the kinematics of quasi-free n scattering arises from the neutron pole diagram. The correction due to other diagrams is typically –30% to –10% and decreases with increasing photon energy and momentum transfer. The sensitivity of the cross sections to the magnitude of the neutron electric polarizability and to the sign of the ⁰2 decay constant is demonstrated.     

Entropy,the central limit theorem and the algebra of the canonical commutation relation

The central limit theorem of Cushen and Hudson is reformulated on the algebra of the CCR. Namely, for a gauge invariant state , the weighted convolutions _n of the central limit tend to the quasi-free reduction _Q of pointwise. It is proved that if the initial relative entropy S(, _Q ) is finite, then S( _n , _Q ) goes to 0 and so _n – _Q 0. No restriction on the dimension of the test function space is made.     

Some properties of topological geons

We investigate the Finkelstein-Misner geons for a non-simply-connected space-time manifold (M, g ₀). We use relations between different Lorentzian structures unequivalent tog ₀ and topological properties ofM given by the Morse theory. It implies that to some pieces of geons we have to associate Wheeler's worm-holes. Geons that correspond to time-orientable Lorentz structures are related tog ₀ by Morse functions that describe the attaching of a handle of index one. In the case of geons associated to time-nonorientable Lorentzian structures, appropriate handles are related to loops along which the notion of time reverses. If we assume electromagnetic properties of geons, then only four species, v, e, p, m, of different geons can exist and geon m has to decay according to mv+p+e.     

Diffusion in a one-dimensional gas of hard point particles

We simulate the classical diffusion of a particle of massM in an infinite one-dimensional system of hard point particles of massm in equilibrium. Each computer run corresponds to about 10⁸ collisions of the diffusive particle. We find that (t) 1/t fort large enough, and a crossover from an M m regime where=2 to=3 forM=m. The diffusion constant has a sharp maximum atM=m. We study moments x(t)² and x(t)⁴, and examine the behavior ofq ² (t)=x(t)⁴/3x(t)²². We find thatq(t)1 (consistent with a normal distribution) in theM limit (for all timest) and in the t limit for allM. On sabbatical leave from IVIC-Instituto Venezolano de Investigaciones Cientificas.     

Surviving extrema for the action on the twisted SU(∞) one point lattice

We give a simplified construction of twist eating configurations, based on a theorem due to Frobenius. These configurations are defined through the equation:U U U ⁺ U ⁺ =exp(2in /N) withU SU(N), =1 tod andn an antisymmetric matrix with integer entries. In the (Twisted)-Eguchi-Kawai model they yield extrema some of which survive forN. Comparison is made with the Monte Carlo data of the internal energy in the small coupling region.     

A complete proof of the Feigenbaum conjectures

The Feigenbaum phenomenon is studied by analyzing an extended renormalization group map . This map acts on functions that are jointly analytic in a position variable (t) and in the parameter () that controls the period doubling phenomenon. A fixed point ^* for this map is found. The usual renormalization group doubling operatorN acts on this function ^* simply by multiplication of with the universal Feigenbaum ratio ^*= 4.669201..., i.e., (N ^*(,t)= ^*( ^* ,t). Therefore, the one-parameter family of functions, ^* , ^* (t)=( ^*(,t), is invariant underN. In particular, the function ₀ ^* is the Feigenbaum fixed point ofN, while ^* represents the unstable manifold ofN. It is proven that this unstable manifold crosses the manifold of functions with superstable period two transversally.     

Time-energy uncertainty and relativistic canonical commutation relations in quantum spacetime

It is shown that the time operatorQ ⁰ appearing in the realization of the RCCR's [Q,P^v]=–jhg^v, on Minkowski quantum spacetime is a self adjoint operator on Hilbert space of square integrable functions over _m =×v _m , where is a timelike hyperplane. This result leads to time-energy uncertainty relations that match their space-momentum counterparts. The operators Q appearing in Born's metric operator in quantum spacetime emerge as internal spacetime operators for exciton states, and the condition that the metric operator should possess a ground exciton state assumes the significance of achieving minimal spacetime4-momentum uncertainty in fundamental standards for spacetime measurements.Supported in part by NSERC research grant No. A5206.     

KL,S → l+l− decays in the quark model of superconductivity type

The probabilities of K_L,S l⁺l^– decays are calculated by considering only the dominant two-lepton channel K_L,S ^{* *} l⁺l^–. The transitions K⁰ X, where X=⁰,, or (700) dominating in the K_L,S ^{* *}decay amplitudes, are described by the effective weak Lagrangian. The matrix elements of four-quark operators are calculated within the framework of the quark model of superconductivity type. It is shown that the leading contribution to matrix elements of K⁰ X transitions comes from the penguin operator matrix elements.     

Statistical mechanics of nonlinear wave equations. 3. Metric transitivity for hyperbolic sine-gordon

McKean and Vaninsky proved that the canonical measuree ^–H d Q d P based upon the Hamiltonian of the wave equation ² Q/t ² - ² Q/x ² +f(Q) = 0 with restoring forcef(Q)=F'(Q) is preserved by the associated flow ofQ andP =Q , and they conjectured that metric transitivity prevails,always on the whole line, and likewise on the circleunless f(Q)=Q orf(Q)=shQ. Here, the metric transitivity is proved for the whole line in the second case. The proof employs the beautiful d'Alembert formula of Krichever.     

The computer as a physical system: A microscopic quantum mechanical Hamiltonian model of computers as represented by Turing machines

In this paper a microscopic quantum mechanical model of computers as represented by Turing machines is constructed. It is shown that for each numberN and Turing machineQ there exists a HamiltonianH _N ^Q and a class of appropriate initial states such that if c is such an initial state, then _Q ^N (t)=exp(–1H _N ^Q t) _Q ^N (0) correctly describes at timest ₃,t ₆,,t _3N model states that correspond to the completion of the first, second, , Nth computation step ofQ. The model parameters can be adjusted so that for an arbitrary time interval aroundt ₃,t ₆,,t _3N, the machine part of _Q ^N (t) is stationary.     

Primes in Short Intervals

Contrary to what would be predicted on the basis of Cramérs model concerning the distribution of prime numbers, we develop evidence that the distribution of (x+H)–(x), for 0xN, is approximately normal with mean H and variance HlogN/H, when NHN^1–.Dedicated to Freeman Dyson, with best wishes on the occasion of his eightieth birthdayResearch supported by NSF grants DMS–0070720 and DMS–0244660.Research supported by the American Institute of Mathematics and NSF grants.     

Clusters,metastability, and nucleation: Kinetics of first-order phase transitions

We describe and interpret computer simulations of the time evolution of a binary alloy on a cubic lattice, with nearest neighbor interactions favoring like pairs of atoms. Initially the atoms are arranged at random; the time evolution proceeds by random interchanges of nearest neighbor pairs, using probabilities compatible with the equilibrium Gibbs distribution at temperatureT. For temperatures 0.59T_c, 0.81 T_c, and 0.89T _c, with density of A atoms equal to that in the B-rich phase at coexistence, the density C₁ of clusters ofl A atoms approximately satisfies the following empirical formulas: C₁ w(1 –)³ andC ₁, (1 –)⁴Q₁w¹ (2 l 10). Herew is a parameter and we defineQ _l = _K e ^–E(K) , where the sum goes over all translationally nonequivalentl-particle clusters andE(K) is the energy of formation of the clusterK. Forl > 10,Q ₁ is not known exactly; so we use an extrapolation formulaQ _l Aw _s ^–l l ^– exp(–bl ), wherew _s is the value ofw at coexistence. The same formula (withw > w _s) also fits the observed values of C, (for small values ofl) at densities greater than the coexistence density (forT=0.59T_c): When the supersaturation is small, the simulations show apparently metastable states, a theoretical estimate of whose lifetime is compatible with the observations. For higher supersaturation the system is observed to undergo a slow process of segregation into two coexisting phases (andw therefore changes slowly with time). These results may be interpreted as a more quantitative formulation (and confirmation) of ideas used in standard nucleation theory. No evidence for a spinodal transition is found.Supported by AFOSR Grant No. 73-2430D and by ERDA Contract No. EY-76-C-02-3077*000.