A comprehensive experimental study of the rheological behaviour of HDPE.

Extensional properties of four high density polyethylenes with different molecular weights and molecular weight distributions are presented. The samples have already been well characterized in shear and non-isothermal extensional flow. The data were collected at 180 °C for elongational rates between 3 · 10^–1 and 10^–4s^–1. Some qualitative and quantitative generalizations of the results are given.     

Experimental study of heat and mass transfer from a horizontal cylinder in downward air-water mist flow with blockage effect

An experimental study was made on convective heat and mass transfer from a horizontal heated cylinder in a downward flow of air-water mist at a blockage ratio of 0.4. The measured local heat transfer coefficients agree fairly well with the authors' numerical solutions obtained previously for the front surface of a cylinder over the ranges mass flow ratio 0–4.5×10⁻², a temperature difference between the cylinder and air 10–43 K, gas Reynolds number (7.9–23)×10³, Rosin-Rammler size parameter 105–168 μm, and dispersion parameter 3.4–3.7. Heat transfer augmentation, two-pahse to single-phase of greater than 19 was attained at the forward stagnation point. For heat transfer in the rear part of the cylinder, an empirical formula is derived by taking into account the dimensionless governing variables, that is, coolant-feed and evaporation parameters.     

Ruheschermodul und erste Normalspannungsdifferenz von Polyäthylenoxidlösungen

Zusammenfassung Lösungen von 1, 2 und 3% Polyäthylenoxid (M = 4,6 10⁶) in Wasser, welche durch einen Zusatz von Isopropanol stabilisiert sind, werden mit rheologischen Methoden untersucht. Fließkurven mit Deformationsgeschwindigkeiten von 10^–3 bis 10⁶ s^–1 zeigen den scherentzähenden Bereich. Er wird von einer Zunahme des Schermoduls und des Speichermoduls begleitet, die in einer Kegel-Platte-Strömung und in einer exzentrischen Torsions-Strömung bestimmt wurden. Der Ruheschermodul wird aus Anlaufmessungen erhalten und läßt auf ein gut ausgebildetes Verhängungsnetzwerk schließen; eine weitgehend freie Durchdringbarkeit der Polyäthylenoxid-Knäuel wird diskutiert.

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Rheological measurements are reported on aqueous solutions containing 1, 2 and 3% of polyethylenoxid (M = 4.6 10⁶) with propanol-2 as stabilizing agent. Flow curves with rates of shear ranging from 10^–3 to 10⁶ s^–1 cover the full shear thinning region. This region coincides with the increase of shear modulus and storage modulus, which had been determined with a cone-and-plate and with an excentric rotating disks-rheometer, respectively. Start-up measurements show a considerable rigidity at rest. The experimental data are discussed in terms of the entangled network model of fairly good penetrable chains.

Vortrag, gehalten auf der Jahrestagung der Deutschen Rheologischen Gesellschaft in Ulm vom 7.–10. März 1983.     

Peculiar features in the rheological behavior of electrorheological suspensions

Studies have been made of concentrated (up to 60%) diatomite suspensions in transformer oil, the structure and theological properties of which depend on an applied electric field. Studies have been conducted of steady-state and transient regimes of straining involving continuous and periodic shear. The structure in such suspensions is formed in the presence of an electric field of 10^–3 –10² duration. The suspensions under continuous stationary strain behave as non-Newtonian fluids with a yield stress dependent on electric intensity. Under periodic deformation conditions the test suspensions exhibit elasticity which abruptly diminishes with increasing deformation amplitude.     

Effects of microchannel geometry on pulsed flow mixing

Although the mixing of reagents is often crucial in many microfluidic devices, good mixing in these laminar, low Reynolds number, flows remains a challenge. It was shown in Refs. [Glasgow, I., Aubry, N., 2003. Lab on a Chip 3, p. 114; Glasgow, I., Batton, J., Aubry, N., 2004. Lab on a Chip 4, p. 558] that pulsing can induce mixing at the confluence of two inlet microchannels in an efficient manner. In this paper, we show that this mixing is affected by both the geometry of the confluence and the inclusion of features in the channels, which induce secondary flow. More specifically, we study mixing in 200 μm wide by 120 μm deep channels, at flow rates from 48 nl s⁻¹ to 4.8 μl s⁻¹, corresponding to Reynolds numbers of 0.3–30. For the parameter values studied, the pulsed flow technique is more effective at mixing than the secondary flow induced by the channel geometry features, and combining both methods leads to even better mixing. In addition, pulsing the reagents such that they pass multiple times through the spatial features, which induce secondary flow leads to mixing over shorter distances.     

Mixed convection flow over a vertical plate with localized heating (cooling), magnetic field and suction (injection)

An analysis is carried out to study the effects of localized heating (cooling), suction (injection), buoyancy forces and magnetic field for the mixed convection flow on a heated vertical plate. The localized heating or cooling introduces a finite discontinuity in the mathematical formulation of the problem and increases its complexity. In order to overcome this difficulty, a non-uniform distribution of wall temperature is taken at finite sections of the plate. The nonlinear coupled parabolic partial differential equations governing the flow have been solved by using an implicit finite-difference scheme. The effect of the localized heating or cooling is found to be very significant on the heat transfer, but its effect on the skin friction is comparatively small. The buoyancy, magnetic and suction parameters increase the skin friction and heat transfer. The positive buoyancy force (beyond a certain value) causes an overshoot in the velocity profiles.A mass transfer constant - B magnetic field - C_fx skin friction coefficient in the x-direction - C_p specific heat at constant pressure, kJ.kg^–1.K - C_v specific heat at constant volume, kJ.kg^–1.K^–1 - E electric field - g acceleration due to gravity, 9.81 m.s^–2 - Gr Grashof number - h heat transfer coefficient, W.m².K^–1 - Ha Hartmann number - k thermal conductivity, W.m^–1.K - L characteristic length, m - M magnetic parameter - Nu_x local Nusselt number - p pressure, Pa, N.m^–2 - Pr Prandtl number - q heat flux, W.m^–2 - Re Reynolds number - Re_m magnetic Reynolds number - T temperature, K - T_o constant plate temperature, K - u,v velocity components, m.s^–1 - V characteristic velocity, m.s^–1 - x,y Cartesian coordinates - thermal diffusivity, m².s^–1 - coefficient of thermal expansion, K^–1 - , transformed similarity variables - dynamic viscosity, kg.m^–1.s^–1 - ₀ magnetic permeability - kinematic viscosity, m².s^–1 - density, kg.m^–3 - buoyancy parameter - electrical conductivity - stream function, m².s^–1 - dimensionless constant - dimensionless temperature, K - w, conditions at the wall and at infinity     

Nonequilibrium ionization accompanying hypersonic flow of carbon dioxide gas over blunt bodies

A study is made of the nonequilibrium ionization in the shock layer when carbon dioxide gas flows over cones with spherical noses at velocity 4–7 km/sec, the density of the oncoming flow being 10^–8-10^–5 g/cm³. The influence of admixtures of nitrogen and sodium on the electron concentration is investigated.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 1, pp. 183–186, January–February, 1981.     

A small scale capillary viscometer for polymer melts

Summary A small scale capillary viscometer that is capable of measuring the flow curves of 2–3 gms of molten polymer over the shear rate range 0.4 sec^–1 to 20,000 sec^–1 is described. A piezo electric crystal pressure transducer is used to measure the pressure directly above the capillary. Flow curves are given for anionic polystyrenes and polyethylene fractions, and it is shown that the viscosities measured agree with determinations in a cone and plate viscometer.

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Zusammenfassung Es wird ein maßstäblich kleines Kapillarviskosimeter für 2–3 g geschmolzener Polymere beschrieben, das die Durchfiußkurve in Abhängigkeit vom Scherkoeffizienten im Bereich von 0,4 sec^–1 bis 20000 sec^–1 bestimmt. Verwendet wird ein piezoelektrischer Kristall-Druckaufnehmer, der den Druck genau über der Kapillare mißt. Angeführt werden Durchflußkurven für anionische Polystyrole und Polyäthylenanteile. Es wird gezeigt, daß die gemessenen Zähigkeiten mit denen von Kegel- und Plattendichtemessern übereinstimmen.

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Paper presented at the Conference on Experimental Rheology, University of Bradford, April 17–19, 1968.     

Limiting analytical solutions for complex saturated and unsaturated transport problems

Non-linear diffusion and velocity-dependent dispersion problems are under consideration. The necessary and sufficient conditions allowing the comparison of solutions to the two dimensional convection-dispersion equations with different coefficients are obtained. These conditions provide a framework within which solutions to the complex non-linear problems mentioned above can be estimated by solutions to the problems possessing analytical solvability.Nomenclature c(x, y, t) concentration of solute in solution,ML ^–3 - C(h)=d/dh moisture capacity function - D,D _ij hydrodynamic dispersion coefficient, a second order tensor,L ² T ^–1 - D _L longitudinal hydrodynamic dispersion coefficient,L ² T ^–1 - D _m molecular diffusion coefficient,L ² T ^–1 - D _T transverse hydrodynamic coefficient,L ² T ^–1 - G flow domain for the unsaturated flow problem - G _z , G _w flow domain and complex potential domain, respectively, for the hydrodynamic dispersion problem - h piezometric head,L - I _n given mass flux normal to the boundary,MLT ^–1 - k hydraulic conductivity,LT ^–1 - K(h) unsaturated hydraulic conductivity,LT ^–1 - L continuously differentiable function with respect to all arguments - m porosity - n(x,t) outer normal vector to the boundary - t time,T - V(x, y, t) seepage velocity vector withV=V,LT ^–1 - x Cartesian coordinate system - x horizontal coordinate,L - y vertical coordinate (elevation),L - (x),(x,t) given functions in initial and boundary conditions (3), (4) - ₁(,) angle between vectors ₁c andV - boundary of the flow domain - _L , _T longitudinal and transverse dispersivities, respectively,L - water mass density,ML ^–3 - v _i components of a unit vector in the direction of the outward normal to the boundary - =–kh velocity potential - =/m - stream function defined such thatw=+i is the complex potential - =/m     

Some plane adiabatic ideal gas flows containing shocks

We obtain the solution describing adiabatic flows of an ideal gas characterized by the two parameters a and b such that [a]=L ^m+1 T ^–1, [b]=ML ^–2–2m where m is arbitrary (m > 0).h This solution permits the construction of flows containing shocks.Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnicheskoi Fiziki, Vol. 10, No. 3, pp. 71–73, May–June, 1969.     

Obtaining the load-extension curves of samples subjected to an explosion load

The energy of explosives has been increasingly used in recent times for the mechanical testing of construction materials subjected to high rates of deformation [1–8]. We describe in the present paper a small apparatus for the uniaxial expansion testing of samples with the aid of explosives at deformation rates of about 10³ sec^–1; we report on some results of testing steel and aluminum alloy samples.Translated from Zhurnal Prikladnoi Mekhanika i Tekhnicheskoi Fizika, No. 1, pp. 184–186, January–February. 1975.     

Electrical Conductivity of Rocks under Shock Compression

The electrical conductivity of silicate rocks (quartzite, granite, and dry and wet tuffs) under single shock–wave loading is measured. It is shown that even at a shock–wave pressure of 20 GPa, the conductivity of rocks changes by several orders of magnitude compared to the initial value (10^–9 — 10^{–12 –1} · m^–1 for dry rocks) and reaches 0.01 ^–1 · m^–1 for quartzite and granite and 0.1 — 1.0 ^–1 · m^–1 for tuff. As the shock–wave amplitude increases from 20 to 60 GPa, the electrical conductivity increases by further one or two orders of magnitude. The experiments with rocks did not reveal a drastic change in electrical conductivity similar to the that observed for silicon dioxide (fused quartz) at a pressure of about 40 GPa.     

Heat transfer to non-Newtonian flows over a cylinder in cross flow

Over a range of 102<Re^*<5800, 6.5<Pr^*<79, and 0.6<n<1, circumferential wall temperatures for water and aqueous polymer (purely viscous) solution flows over a smooth cylinder were measured experimentally. The cylinder was heated by passing direct electric current through it. Aqueous solutions of Carbopol 934 and EZ1 were used as power-law non-Newtonian fluids. The peripherally averaged heat transfer coefficient for purely viscous non-Newtonian fluids, at any fixed flow rate, decreases with increasing polymer concentration. A new correlation is proposed for predicting the peripherally averaged Nusselt number for power-law fluid flows over a heated cylinder in cross flow.     

Smooth Linearization for a Saddle on Banach Spaces

As a continuation of a previous work on linearization of class C¹ of diffeomorphisms and flows in infinite dimensions near a fixed point, in this work we deal with the case of a saddle point with some non-resonance restrictions for the linear part. Our result can be seen as an extension of results by Hartman [Boletin de la Sociedad Matematica Mexicana 5(2), 220–241 (1960)] and Aronson, Belitskii and Zhuzhoma [Introduction to the Qualitative Theory of Dynamical systems on surfaces, AMS Transl. Math. Monog. vol.153, pp. 268–277 (1996)] in dimension two. We also present an application to a system of nonlinear wave equations.AMS Subject Classifications: Primary: 35B05, 34G20. Secondary: 35B40, 34D05.Dedicated to Professor Shui-Nee Chow on the occasion of his 60th birthday     

Experimental investigation of the separation of flow around a sphere

The results of an experimental investigation of the flow around a sphere over a broad range of Mach numbers M=0.3–3 and Reynolds numbers Re=3·10⁴–3·10⁷ are presented. The experiments were carried out on a ballistic test stand and in a wind tunnel. Flow patterns and pressure distributions were obtained. In particular, the effect of the Mach and Reynolds numbers on the position of the separation point and the edge shock was studied; the pressure distribution on the sphere was measured; and a nonmonotonic displacement of the flow separation point upon passage through the speed of sound was established.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 1, pp. 152–156, January–February, 1991.     

Linear and branched poly(butyleneterephthalate): Activation energy for melt flow

Poly(butyleneterephthalate) (PBTP) samples of different molecular weights, both linear and branched, were synthetized by mass polymerization and studied in the molten state with a melt-flow-index apparatus at different temperatures in the range 245–270 °C. In our experimental conditions ( 20 s^–1) the behaviour of PBTP samples was Newtonian, as reported previously. The flow activation energyE _a,0 was found to increase with degree of branching: typicallyE _a,0 was about 47 and 63–79 kJ/mol for linear and branched polymers respectively.Presented in part at the IX. International Congress on Rheology, Acapulco, Mexico, October 8–13, 1984     

Diffusion of moisture in deformable porous media. Anisotropic fibrous materials

This paper presents a study on the deformation of anisotropic fibrous porous media subjected to moistening by water in the liquid phase. The deformation of the medium is studied by applying the concept of effective stress. Given the structure of the medium, the displacement of the solid matrix is not taken into account with respect to the displacement of the liquid phase. The transport equations are derived from the model proposed by Narasimhan. The transport coefficients and the relation between the variation in apparent density and effective stress are obtained by test measurements. A numerical model has been established and applied for studying drip moistening of mineral wool samples capable or incapable of deformation.Nomenclature D mass diffusion coefficient [L²t^–1] - e void fraction - g gravity acceleration [Lt^–2] - J mass transfer density [ML^–2t^–1] - K hydraulic conductivity [Lt^–1] - K _s hydraulic conductivity of the solid phase [Lt^–1] - K ^* hydraulic conductivity of the deformable porous medium [Lt^–1] - P pressure of moistening liquid [ML^–1 t^–2] - S degree of saturation - t time [t] - V speed [Lt^–1] - X horizontal coordinate [L] - Z vertical coordinate measured from the bottom of porous medium [L] - z z-coordinate [L] Greek Letters porosity - ₁ total hydric potential [L] - _g gas density [ML^–3] - ₁ liquid density [ML^–3] - ₀ apparent density [ML^–3] - _s density of the solid phase [ML^–3] - density of the moist porous medium [ML^–3] - external load [ML^–1t^–2] - effective stress [ML^–1t^–2] - bishop's parameter - matrix potential or capillary suction [L] Indices g gas - 1 moistening liquid - p direction perpendicular to fiber planes - s solid matrix - t direction parallel to fiber planes - v pore Exponent * movement of solid particles taken into account     

Extensional flow of polystyrene melt

Summary The extensional flow of molten polystyrene was studied in the strain rate range of 7.8×10^–4 sec^–1 to 2.2×10^–2 sec^–1 at a test temperature of 300F (149 C) Extensional viscosity was compared to shear viscosity measured at the same degree of stress and temperature and found to be from 3 to 350 times greater in magnitude but much less stress dependent.     

An application of Ungar's differential transform to elastodynamics

In recent years, a lot of writers have used Cagniard-de Hoop’s method^[1][2] to solve some problems of elastic wave. But it is a difficult and complicated task to change the path of integration when we use this method. A differential transform by A.Ungar^[3,6] can obviate this difficulty. In this paper, weuse Ungar’s differential transform to solve a case of Lamb’s problem^[1][2].     

Dynamic instabilities of boiling two-phase flow in a single horizontal channel

Dynamic instabilities of two-phase flow associated with refrigerant R-11 in a uniformly heated horizontal in-tube boiling system were experimentally investigated. An experimental setup was designed and built to work in a wide range of mass fluxes G [75–1050 kg/(m² s)], heat fluxes q (0–100 kW/m²), and fluid inlet temperatures T_inlet (2–24°C). Dynamic instability data were obtained under various working conditions. The dependence of oscillation amplitude and period on system parameters is discussed, and the boundaries of various oscillations are located on the steady-state characteristic curves.