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1.
Tm:YVO4晶体的光谱参数计算   总被引:10,自引:0,他引:10  
由测量的Tm :YVO4晶体的吸收光谱 ,考虑到单轴晶体在各个方向上的吸收不同和折射率随波长的变化 ,根据Judd Ofelt理论计算了Tm3 +在YVO4中的强度参数、各个能级的振子强度、自发辐射几率、荧光分支比、积分发射截面等参数。强度参数为Ω2 =1 9416× 10 - 2 0 (cm2 ) ,Ω4=0 15 6 8× 10 - 2 0 (cm2 ) ,Ω6=0 396 3× 10 - 2 0 (cm2 )。计算结果表明 ,1 D2 → 3 F4的跃迁几率远大于1 D2 向其他各个能级的跃迁几率  相似文献   

2.
钨酸钇钠晶体中Tm3+的光谱特性   总被引:4,自引:2,他引:2       下载免费PDF全文
测量了Tm3 :NaY(WO4 ) 2 晶体的吸收光谱、发射光谱和激发光谱 ,利用J_O理论计算了钨酸钇钠晶体的强度参数 :Ω2 =7 2 130 4× 10 - 2 0 cm2 ,Ω4 =0 5 0 4 76 6× 10 - 2 0 cm2 ,Ω6 =0 977784× 10 - 2 0 cm2 ,以及Tm3 的光学参数包括各能级的荧光寿命和荧光分支比、积分发射截面等 ,在计算了Tm3 的自发辐射概率时 ,同时考虑了电偶极跃迁和磁偶极跃迁 .研究了其发光特性和跃迁通道 ,发现存在1 D2 3H6 →1 G4 3F4 的交叉弛豫  相似文献   

3.
采用Czochralski法生长了均匀透明的Tm:YVO4, Tm:Er:YVO4和Tm:Yb:YVO4晶体, 测量了其室温下吸收光谱, 研究了晶体中掺杂稀土离子的光谱性质. 根据Judd-Ofelt理论拟合出晶体场唯象强度参数: Ω2=1.13×10-20 cm2, Ω4=1.63×10-20 cm2, Ω6=0.65×10-20cm 2.  相似文献   

4.
报道了对Tm ,Ho双掺YVO4 晶体光谱性能的测量结果 ,包括用UV 3 65型分光光度计测出单掺Tm∶YVO4 及Ho∶YVO4 吸收谱以及双掺Tm∶Ho∶YVO4 的吸收谱 ;用Ar离子激光器 4 88nm ,LD激光器激发测量样品荧光光谱 ;用J O理论进行光谱参数计算及对能级结构进行分析 ;研究了在λ=80 5nm的激光二极管激发下Tm对Ho的敏化发光过程。发现与YAG ,YLF为基质的Tm ,Ho双掺材料相比 ,该材料中的Tm3 + 离子具有大而均匀的吸收宽度 (~ 2 6nm) ,大的峰位吸收截面和积分吸收截面 (~ 1 4× 1 0 -2 0 cm2 和 2 74 5× 1 0 -2 0cm) ,能量转换效率高 (可达 87% ) ,且泵浦阈值低 (~ 1 5mW )。表明了YVO4 晶体中Tm能有效地敏化Ho,并产生 2 μm的发射。文中对发射强度与泵浦功率及Tm ,Ho之间掺杂浓度的关系进行了初步的分析与讨论。光谱的观察结果表明∶在实现LD泵浦 ,全固体化 ,小型 ,高效的 ,2 μm激光振荡的探索中 ,Tm∶Ho∶YVO4 晶体将是一种很有实际应用潜力的材料。  相似文献   

5.
摘要:报道了对Tm,Ho双掺YVO4晶体光谱性能的测量结果,包括用UV-365型分光光度计测出单掺Tm:YVO4及Ho:YVO4吸收谱以及双掺Tm:Ho:YVO4的吸收谱;用Ar离子激光器488nm,LD激光器激发测量样品荧光光谱;用J-O理论进行光谱参数计算及对能级结构进行分析;研究了在λ=805nm的激光二极管激发下Tm对Ho的敏化发光过程。发现与YAG,YLF为基质的Tm,Ho双掺材料相比,该材料中的Tm3+离子具有大而均匀的吸收宽度(~26nm),大的峰位吸收截面和积分吸收截面(~1.4×10-20cm2和274.5×10-20 cm),能量转换效率高(可达87%),且泵浦阈值低(~15mW)。表明了YVO4晶体中Tm能有效地敏化Ho,并产生2μm的发射。文中对发射强度与泵浦功率及Tm,Ho之间掺杂浓度的关系进行了初步的分析与讨论。光谱的观察结果表明:在实现LD泵浦,全固体化,小型,高效的,2μm激光振荡的探索中,Tm:Ho:YVO4晶体将是一种很有实际应用潜力的材料。  相似文献   

6.
利用X射线粉末衍射确定了Tm3+掺杂硅酸镓镧(La3Ga5SiO14,LGS)晶体的晶体结构;运用DICVOL91程序计算了该晶体不同部位的晶胞参数;测定了Tm:LGS晶体的室温吸收谱和470 nm光激发下的发射光谱;根据Judd-Ofelt理论拟合了Tm3+的三个晶场调节参数Ωt(t=2,4,6),分别为2.694×10-20 cm2,1.842×10-20 cm2,0.030 × 10-20 cm2;计算了各个能级跃迁的谱线强度、振子强度、吸收截面等,进而计算了3H4和3F4态的自发跃迁概率、辐射寿命、荧光分支比和积分发射截面,并对结果进行了分析.  相似文献   

7.
钒酸钇(YVO4)晶体有高的激光损伤阈值和高的激光输出斜率效率,也有很好的机械性能和化学稳定性.从测量TmYVO4晶体的吸收谱入手,考虑该晶体的各向异性效应,拟合出Tm3+的光学强度参量,进一步得到了振子强度f,辐射跃迁速率A和积分发射截面Σ等光学参量.在350-2500nm范围内,YVO4晶体基质的吸收很小,而Tm3+在YVO4晶体中发光能力很强;特有的是蓝光1D2→3F4(约为454nm)跃迁有极大的振子强度(38×10-6)和积分发射截面(33×10-18cm),有利于实现短波长的激光输出.  相似文献   

8.
测定了Er:YCa4O(BO3 ) 3 晶体室温下的吸收谱。根据Judd Ofelt理论拟合了Er3 离子的晶体场调节参数Ωt=(2 ,4 ,6 ) 分别为 19 2 0 4 9× 10 -2 2 ,5 992 0× 10 -2 2 和 4 3334× 10 -2 2 cm2 ,计算了各能级跃迁的谱线强度、自发辐射跃迁几率、辐射寿命、荧光分支比和积分发射横截面 ,并对结果作了分析。最后讨论了Yb3 的敏化作用。  相似文献   

9.
Tm,Ho双掺杂YVO4晶体中Tm对HO敏化发光现象   总被引:5,自引:0,他引:5  
《发光学报》2001,22(2):175-181
摘要报道了对Tm,Ho双掺YVO4晶体光谱性能的测量结果,包括用UV-365型分光光度计测出单掺TmYVO4及HoYVO4吸收谱以及双掺TmHoYVO4的吸收谱;用Ar离子激光器488nm,LD激光器激发测量样品荧光光谱;用J-O理论进行光谱参数计算及对能级结构进行分析;研究了在λ=805nm的激光二极管激发下Tm对Ho的敏化发光过程。发现与YAG,YLF为基质的Tm,Ho双掺材料相比,该材料中的Tm3+离子具有大而均匀的吸收宽度(~26nm),大的峰位吸收截面和积分吸收截面(~1.4×10-20cm2和274.5×10-20 cm),能量转换效率高(可达87%),且泵浦阈值低(~15mW)。表明了YVO4晶体中Tm能有效地敏化Ho,并产生2μm的发射。文中对发射强度与泵浦功率及Tm,Ho之间掺杂浓度的关系进行了初步的分析与讨论。光谱的观察结果表明在实现LD泵浦,全固体化,小型,高效的,2μm激光振荡的探索中,TmHoYVO4晶体将是一种很有实际应用潜力的材料。  相似文献   

10.
根据Judd-Ofelt理论,测得了Tm3+ 在TmP5O14晶体中的强度参数分别为Q2=:1.50×10-20cm2,Q4=1.51×10-20cm2,Q6=0.916×10-20cm2,计算的振子强度Pcal.与实验值Pexp.符合较好,平均根方误差为2.60×10-7。求得Qλ后,计算了J多重激发态之间的振子强度,自发辐射跃迁速率,辐射寿命和荧光分支出,与YAlO3:Tm3+,YAG:Tm3+、Y2O3:Tm3+等晶体和掺Tm3+玻璃的光谱参数进行了比较,并就3H4→3H6,3F4→3H5,1D2→3H4和1G4→3H4的跃迁进行了对比和讨论。观察到Tm3+在不同介质中的Pexp.与强度参数的总和∑τλ=τ2+τ4+τ6存在Pexp=α∑τλ+b的关系。  相似文献   

11.
Two-dimensional scanning of a 0.6328 mum guided-light beam has been realized using noncolinear acousto-optic (AO) coplanar Bragg diffraction together with colinear AO guided-mode to substrate radiation-mode conversion in a Z-cut Xpropagation LiNbO3 proton-exchanged (PE) waveguide. The two surface acoustic (SAW) waves utilized are at the center frequencies of 500 and 200 MHz, propagating in the Y and X axes, respectively. Two-dimensional scanning of approximately 720 resolvable light beam spots, namely, 18 40 (horizontal vertical) scanning, has been demonstrated using a light beam of 1.0 mm aperture. The total number of resolvable beam spots can be greatly increased from 720 by simply utilizing SAW transducers of larger bandwidth and a light beam of greater aperture. It should also be possible to significantly increase the diffraction efficiency from 3 % by optimizing the parameters of the PE waveguide and the SAWs.  相似文献   

12.
A simple technique of pulse compression, based on the linear chirp compensation of self-phase modulation (SPM) spectra in dispersion shifted fibers, is demonstrated. The optimization procedure is carried out, for a short span of a single-mode fiber, using a parabolic law, which describes the behavior of the squared output pulse width versus the pump peak power in the case of Gaussian pulses. The experimental results give a minimum pulse duration of 233 fs, which is in good agreement with the model. Shorter and coherent pulses, down to 90 fs, have been obtained by inserting an interference filter at the optical output.  相似文献   

13.
Results of a study of the effect of γ-radiation on the spectral luminescence properties of cadmium tungstate crystals doped with silver, bismuth, and molybdenum cations are presented. Spectral characteristics of the nondnnnoped crystals are briefly described. Absorption and photo and X-ray luminescence spectra of the crystals taken before and after exposure to γ-radiation (5.5·104 Gy) are compared. It is found that the spectral characteristics of the crystals doped with silver, bismuth, and molybdenum cations do not change markedly after the exposure. The relation between the type of impurity-induced defects, individual characteristics of the impurity cations, and the character of the effect of γ-radiation on the spectral luminescence properties of impure crystals is analyzed (preliminarily). Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 1, pp. 55–60, January–February, 1997.  相似文献   

14.
The Shanghai Synchrotron Radiation Facility(SSRF)booster ring,a full energy injector for the storage ring,is deigned to accelerate the electron beam energy from 150MeV to 3.5GeV that demands high extraction efficiency at the extraction energy with low beam loss rate when electrons are ramping.Closed orbit distortion(COD)caused by bending magnet field uniformity errors which affects the machine performance harmfully could be effectively reduced by bending magnet location sorting.Considering the affections of random errors in measurement,both ideal sorting and realistic sorting are studied based on measured bending magnet field uniformity errors and one reasonable combination of bending magnets which can reduce the horizontal COD by a factor of 5is given as the final installation sequence of the booster bending magnets in this paper.  相似文献   

15.
16.
We measure the waveform and phase curves of short optical pulses before and after transmission over different lengths of fibers by use of the pulse analyzer with the frequency-resolved optical gating (FROG),and numerically simulate pulse evolution under the experimental conditions.The nonlinear coefficient of the fiber is given by comparing the experimental results with the numerical ones.Difference between the experiment and numerical simulation is analyzed.  相似文献   

17.
Resonance scattering of elastic spherical shell and cylindrical shell while the surrounding fluid medium has absorption is studied. The normal mode solution derived using exact elastic theory and the separation of variables is still applicable. However, the scattering form function has to be modified for the absorbing medium, otherwise the unreasonable result would be obtained. The backscattering form function in the absorbing medium is redefined, and the form function of elastic spherical and cylindrical shell with vacuum or solid matter filled is calculated in various absorption conditions. The results show that the absorption of surrounding fluid leads to notable attenuation of the coincidence resonances in the mid-frequency, but it has a little influence on the low-frequency resonance scattering induced by the filler inside the shell.  相似文献   

18.
A versatile and low-cost single-beam self-referenced phase-sensitive surface plasmon resonance(SPR)sensing system with ultra-high resolution performance is presented.The system exhibits a root-mean-square phase fluctuation of ±0.0028.over a period of 45 min.i.e.a resolution of±5.2×10-9 refractive index units.The enhanced performance has been achieved through the incorporation of three design elements:a true single-beam configuration enabling complete self-referencing so that only the phase change associated with SPR gets detected,a differential measurement scheme to eliminate spurious signals not related to the sensor response,and the elimination of retardation drifts by incorporating temperature stabilization in the liquid crystal phase modulato .Our design should bring the detection sensitivity of non-labeling SPR biosensing closer to that achievable by conventional fluorescence-based techniques.  相似文献   

19.
Ta2O5 films are prepared on BK7 substrates with conventional electron beam evaporation deposition.The effects of SiO2 protective layers and annealing on the laser-induced damage threshold (LIDT) of the films are investigated.The results show that SiO2 protective layers exert little influence on the electric field intensity(EFI)distribution,microstructure and microdefect density but increase the absorption slightly.Annealing iS effective on decreasing the microdefect density and the absorption of the films.Both SiO2 protective layers and annealing are beneficial to the damage resistance of the films and the latter is more effective to improve the LIDT.Moreover,the maximal LIDT of Ta2O5 films is achieved by the combination of SiO2 protective layers and annealing.  相似文献   

20.
Gray cross correlation matching technique is adopted to extract candidate matches with gray cross correla- tion coefficients less than some certain range of maximal correlation coefficient called multi-peak candidate matches. Multi-peak candidates are extracted corresponding to three closest feature points at first. The corresponding multi-peak candidate matches are used to construct the model polygon. Correspondence is determined based on the local geometric relations between the three feature points and the multi-peak candidates. The disparity test and the global consistency checkout are applied to eliminate the remaining ambiguous matches that are not removed by the local geometric relational test. Experimental results show that the proposed algorithm is feasible and accurate.  相似文献   

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