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1.
The emission of Ni2+ ions in MgO, KMgF3, KZnF3 and MgF2 crystals has been investigated. The fine structure on the bands at about 20 000 cm-1 and 13 000 cm-1 has been studied in detail and from this and the excitation spectra these bands are assigned to and transitions respectively. 相似文献
2.
A theoretical model used to describe the and B3Πg states of N2 is presented. Using recently acquired high resolution spectra of the (0-0) band, rotational energy levels of the v = 0 vibrational levels of these two states are generated with this model. These levels are in excellent agreement with those obtained using a combination differences technique. The precision of the model generated levels is 0.01 cm?1. The previously unpublished rotational levels of Dieke and Heath for the , B3Πg and C3Πu states are referenced to the (v = 0, J = 0) ground level and tabulated here. Estimates of the precision of their work are made. 相似文献
3.
The absorption and MCD spectra of the , , and spin-allowed transitions of Cr3+ in K2NaGaF6 are reported. It is shown that transitions to the . states are induced by T1u vibratio the other spin-allowed transition, , there are three competing intensity mechanisms: electric dipole induced by T1u vibrations, electric dipole induced by T2u vibrations and magnetic dipole, and an estimate is made of the relative importance of these. The magnetic dipole zero-phonon line is observed to be accompanied by a vibrational sideband for which the coupling is predominantly with T2u vibrations. Other weak transitions are observed in MCD spectra and their origin briefly discussed. 相似文献
4.
Yu.M Efremov A.N Samoilova V.B Kozhukhovsky L.V Gurvich 《Journal of Molecular Spectroscopy》1978,73(3):430-440
Absorption and emission spectra of Mo2 were investigated using flash photolysis of the Mo(CO)6 molecule. Tentative vibrational and rotational analyses of the 98Mo2 spectra were performed. For the ground state, type was proposed with ωe = 477.1 cm?1, , and D0(Mo2) = 95 ± 15 kcal mole?1. The results were compared with theoretical calculations for Mo2 and experimental results for Cr2 obtained previously. It seems reasonable that the transition metal diatomic molecules of this type have a high bond order. 相似文献
5.
The non-selective nature of the (α, nγ) reaction has been used to complement information from charged-particle reactions on the level structure of 88Y and 90Y. The γ-ray spectra were recorded with a 25 cm3 Ge(Li) detector at 90° to the beam using primarily targets of 85Rb2CO3 and 87Rb2CO3 and α-particle energies of 11.8, 12.2 and 13.0 MeV. The resulting transitions were accommodated in level schemes that involved primarily the following shell model configurations: , , , in 88Y and , , in 90Y. 相似文献
6.
Harry Partridge Charles W. Bauschlicher James R. Stallcop 《Journal of Quantitative Spectroscopy & Radiative Transfer》1985,33(6):653-655
Potential energy curves for the , and states of N+2 that dissociate to N () and , have been determined from a complete active space self-consistent field calculation. The state is found to be significantly bound (De = 2.68 eV) with a minimum at 1.72 Å. 相似文献
7.
Metastable He2 molecules are produced by a dc discharge in a flowing He stream. Laser excitation downstream of the discharge produces excitation spectra for a number of He2 states. LIF spectra are observed for the series for n = 4–9, excepting 5 and the series for n = 5–15. 相似文献
8.
Line positions and molecular constants for the 0-0, 1-0, 2-0, 0-1, 2-1, 3-1, 0-2, 1-2, and 4-2 bands of the C2 Phillips system () are reported. Among them, five bands have not been reported previously. Rotational perturbations have been observed in the previously unobserved v = 1 level of the state. This state is perturbed by the state which was discovered by Ballik and Ramsay. These observations provide new information regarding the perturbing state. In particular, the minimum of the potential energy for the state has been found to be at 9227.4 cm?1 instead of 13 310 cm?1, which was the previous Te value for this electronic state. 相似文献
9.
A. Possoz Ph. Deschepper L. Grenacs P. Lebrun J. Lehmann L. Palffy A. De Moura Gonçalves C. Samour V.L. Telegdi 《Physics letters. [Part B]》1977,70(2):265-268
The helicity, h?, of μ? in π-decay has been determined as positive (h??+0.90) from the average polarization, Pav≡〈JB·sμ〉, of 12B produced in the reaction. We obtain also dynamical information on μ-capture: (i) the weak magnetism form factor, μ=4.5±1.1, and (ii) the sum of the induced pseudoscalar (gp) and the 2nd class induced tensor (gT) couplings versus gA, (. The latter result, adopting the “canonical” value of , leads to which is compatible with zero and in strong contradiction with the value ?—6 recently advocated by Kubodera, Delorme and Rho. 相似文献
10.
Robert S. Mulliken 《Journal of Molecular Spectroscopy》1976,61(1):92-99
Predissociations in the y1Πg and Rydberg states of N2 (configurations and , respectively) and their likely causes, are discussed. Peaking of rotational intensity at unusually low J values, without sharp breaking off, is interpreted as due to case c? or case ci predissociation. Λ doubling in the y state, attributed to interactions with the state and with another, 1Σ+, state of the same electron configuration as x, is analyzed. From this analysis the location of the (unobserved) state, here labeled x′, is obtained. It is concluded that the predissociation in the Π+ levels of the y state is an indirect one mediated by the interaction with x′ coupled with predissociation of x′ by a state dissociating to atoms: combined, however, with perturbation of the y state by the k1Πg Rydberg state (configuration ), whose Π+ levels are completely predissociated. 相似文献
11.
The hyperfine spectra of the (17-7)P(57) line of 79Br2 and the (12-4) P(129) line of 81Br2, both of the electronic transition near 633 nm have been measured by the saturated absorption method. An analysis based on nuclear quadrupole and spin-rotation interactions is presented. 相似文献
12.
N.B. Manson J.T. Gourley E.R. Vance D. Sengupta G. Smith 《Journal of Physics and Chemistry of Solids》1976,37(12):1145-1148
At helium temperatures two sharp lines at 9350 and 9510 cm?1 have been observed for the first tune on the low-energy side of the broad double-peaked absorption corresponding to the transition in Fe2+ at the octahedral site in MgO. The lower energy line has a half width of 4 cm?1; Zeeman measurements show that it is of magnetic dipole origin. The Zeeman spectra are consistent with those expected for a pure electronic transition from the (5T2g)T2g ground state to the 5Eg excited state. The second line, with a halfwidth of ~ 35 cm?1, a vibrational sideband. 相似文献
13.
14.
The emission spectrum of the He2 molecule has been rephotographed in the ~4000–~5700 Å region and the , , and transitions analyzed. The 4dδj3Δu, 4dπj3Πu, and states have been characterized through v = 2 and the 4dδJ1Δu, 4dπJ1Πu, , and states for v = 0. The term levels for these perturbed and l-uncoupled states have been confirmed (a) by analyses of bands with common levels from Δv = 0, ±1 sequences and (b) by analyses of the transitions between the above states from 4d and 4s and the and states associated with 3pσ. Molecular constants are reported which have been partially corrected for the effects of l-uncoupling and the homogeneous perturbations between the state pairs J, H and j, h. 相似文献
15.
Zinc and cadmium atoms have been condensed with argon and krypton at 10 K. The most intense absorption is due to the atomic transition, and a weak band is due to the atomic absorption. Structured absorptions at 252 and 254 nm in solid argon and krypton with vibrational spacings of 140-120 cm?1 are due to the transition of Zn2. Similar 273 and 277 nm absorptions with 110-90 cm?1 vibrational spacings are due to Cd2 in solid argon and krypton, respectively. 相似文献
16.
L Nemes 《Journal of Molecular Spectroscopy》1978,72(1):102-123
Medium resolution infrared grating spectra of gaseous ketene, H2CCO were recorded between 1000 and 400 cm?1, both at instrument temperature (40°C) and with cooling (?40°C). Interferometric Fourier spectra were also measured at ?70°C with resolution 0.22 cm?1 between 450 and 330 cm?1. The K structure of the fundamentals ν5, ν6, ν8, and ν9 was assigned. These fundamentals are coupled by a-axis Coriolis interactions. These couplings were analysed on the symmetric top basis for setting up the perturbation matrix and by utilizing the K-dependent Coriolis shifts of levels. A preliminary analysis of the Coriolis intensity anomalies was also undertaken.Band center values from combination differences are and . Synthetic spectra indicate the band origins of ν8 and ν9 to be close to 977.8 and 439.0 cm?1, respectively. Estimates of Coriolis coupling constants obtained from synthetic spectra are , , , and . Approximate ratios of unperturbed vibrational transition moments obtained from spectral simulations are . 相似文献
17.
Accurate SCF computations are reported on the Rydberg states of N2 of electron configurations , , and ---3σg2πg, also on the valence states of the configuration . The Rydberg state calculations supplement those of Lefebvre-Brion and Moser. A comparison is made between the states and the parallel set of states of the configuration. This comparison shows a sharp difference in the 1Σ+ states of the two configurations, the 1Σ+ state being very high in the latter but relatively low in the former configuration. Recknagel coefficients are given for the several states of the two configurations; as expected, these are much smaller for the configuration. Also, the 1Δ state is relatively lower for the latter configuration. 相似文献
18.
Optical absorption spectra of Ni2+ in (NH4)2Mg(SO4)2·6H2O and Co2+ in Na2Zn(SO4)2·4H2O single crystals have been studied at room and liquid nitrogen temperatures. From the nature and position of the observed bands, a successful interpretation could be made assuming octahedral symmetry for both the ions in the crystals. The splitting observed for band in Ni2+ and band in Co2+ at liquid nitrogen temperature have been explained as due to spin-orbit interaction. The extra band observed at 16,325 cm-1 in the case of Ni2+ at low temperature has been interpreted to be the superposition of vibrational mode of SO2-4 radical on band. The observed band positions in both the crystals have been fitted with four parameters B, C, Dq and ζ. 相似文献
19.
The (0,0) band of the emission (Infrared Afterglow) system of molecular nitrogen has been recorded with a resolution of 0.046 cm?1 and a line position accuracy of 0.007 cm?1. Six hundred and seventy-two lines are tabulated into a line list for the 1.53 μm (low-resolution) emission feature. Of these, 482 are assigned as members of the 27 branches of the B′ → B transition, while 150 are identified with the 1PG (3,6) band. Molecular constants for the v = 0 levels of the and B3Πg states have been computed and tabulated. 相似文献
20.
The 2Πu-X2Πg transition in Br2+ was reexamined using dispersed laser-induced fluorescence, and emission spectroscopy in a seeded molecular beam. New constants are derived, confirming the large difference between and , and reconciling the emission spectrum with photoelectron data. 相似文献