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Quantum chemical calculations at the CASSCF level of theory on the O3‐homologous molecules CX22‐, NX2‐, X3, OX2, and FX2+ (X: O, S, Se, Te, Po) indicate that the triatomic inorganic biradicals in the FX2+ series have unusually high biradical character. 相似文献
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ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option. 相似文献
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Peter B. Hitchcock 《Journal of organometallic chemistry》1982,240(2):C51-C52
The paramagnetic compounds [Os2(OCOR)4Cl2] (R = n-C3H7, C2H7, C2H5, CH2Cl) have been synthesized by reaction of [Os(OCOCH3)2Cl]n with the appropriate acids and the binuclear tetracarboxylate bridged structure confirmed by X-ray analysis for R = n-C3H7, (OsOs distance 2.301 Å, cf. the related [Os2(hp)4Cl2](CH3CN)2; OsOs, 2.357 Å) (hp = 2-hydroxypyridine anion). 相似文献
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Dr. Guillermo Moreno-Alcántar 《欧洲无机化学杂志》2023,26(16):e202200788
The use of self-assembly for building complex functional structures is a current topic of interest in supramolecular chemistry. In this context, the use of biomolecule-based building blocks has paved the way for the development of intracellular assemblies. Currently, the potential functionality of such assemblies in biomedical applications is being disclosed. On the other hand, the use of inorganic (metal-based) building blocks is still in its infancy. The construction of inorganic self-assemblies in-bio is particularly challenging and demands great efforts to reach applications. However, the plethora of thinkable advantages related to the use of inorganic self-assembly in living cells must fuel new discoveries in this area. This Concept reviews the current advances, perspectives, and challenges in inorganic self-assembly in living systems. 相似文献
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