共查询到20条相似文献,搜索用时 15 毫秒
1.
A. A. Kamyshova A. Z. Kreindlin P. V. Petrovskii A. S. Peregudov Yu. A. Borisov A. A. Koridze 《Russian Chemical Bulletin》2005,54(12):2805-2812
The reaction of [Cp*2RuBr]+Br− with bromine in CH2Cl2 (CD2Cl2) in an inert atmosphere at room temperature produces the complexes [Cp*Ru(Br)C5Me4CH2Br]+Br3
− (syn conformer), [Cp*Ru(Br)C5Me3(CH2Br)2]+ (syn and anti conformers), and [Ru(Br)(C5Me4CH2Br)2]+ (syn conformer). All complexes were characterized by 1H and 13C NMR spectroscopy; the former complex, by elemental analysis. These complexes were also prepared by the reaction of [Cp*RuC5Me4CH2]+BF4
− with bromine in CH2Cl2.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2712–2718, December, 2005. 相似文献
2.
The effects of La3+ on inward K+ channels at plasma membrane in vicia guard cells are investigated using the whole-cell patch-clamp recording mode. It is
shown that La3+ on both sides of plasma membrane blocks inward K+ currents in a concentration-dependent manner, indicating that La3+ binding sites may exist on both sides of plasma membrane in guard cells in vicia. The dose response is fitted by the Michaelis-Menten
relation characterized by an inhibitor constant K
i
of 2.56±0.25 μmol · L−1 (outside membrane) and (1.18±0.11)×10−15 mol · L−1 (inside membrane). Intracellular La3+ has much stronger inhibitory effect on inward K+ currents than extracellular La3+ does, suggesting there may exist stronger binding sites inside membrane than outside membrane. Since ion channel activities
of guard cells directly affect plant stomatal movement and water status, our results imply that rare earth elements might
have potential practical values in regulating plant water status and strengthening plant drought endurance. 相似文献
3.
The photoluminescence properties of xZnO–(100−x)SiO2 (x = 0, 5, 10, 20) containing 1% Eu2O3 prepared by a sol–gel method were systematically investigated. The results indicated that the relative proportion of f–f transitions to charge transfer (CT) absorption decreased with the increase of ZnO concentration. The intensity of 5D0–7FJ transitions of Eu3+ ions was enhanced with the increase of ZnO content due to local structure changes and decreased quantities of Eu3+ ions clusters. The results of fluorescence line narrow (FLN) spectra indicated that Eu3+ ions occupied one site in SiO2 glass and two sites in ZnO–SiO2 glasses. The second-order crystal field parameters were calculated. B20 and B22 for site 1 increased with excitation energy, while ones hardly changed for site 2. 相似文献
4.
Comparative quantum chemical calculations of structural parameters, chemical shifts of 11B NMR spectra, and atomic charges in 10-vertex boron hydride anions [1-CB9H10]− and [1-B10H9N2]− were performed using the restricted Hartree-Fock method with the 6-31++G(D,P) basis set.
Dedicated to Academician G. A. Abakumov on the occasion of his 70th birthday.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1853–1855, September, 2007. 相似文献
5.
H. López-González M. Jiménez-Reyes M. Solache-Ríos A. Rojas-Hernández 《Journal of Radioanalytical and Nuclear Chemistry》2007,274(1):103-108
Solubility product (Lu(OH)3(s)⇆Lu3++3OH−) and first hydrolysis (Lu3++H2O⇆Lu(OH)2++H+) constants were determined for an initial lutetium concentration range from 3.72·10−5 mol·dm−3 to 2.09·10−3 mol·dm−3. Measurements were made in 2 mol·dm−3 NaClO4 ionic strength, under CO2-free conditions and temperature was controlled at 303 K. Solubility diagrams (pLuaq vs. pC
H) were determined by means of a radiochemical method using 177Lu. The pC
H for the beginning of precipitation and solubility product constant were determined from these diagrams and both the first
hydrolysis and solubility product constants were calculated by fitting the diagrams to the solubility equation. The pC
H values of precipitation increases inversely to [Lu3+]initial and the values for the first hydrolysis and solubility product constants were log10
β*
Lu,H
= −7.92±0.07 and log10
K*sp,Lu(OH)3 = −23.37±0.14. Individual solubility values for pC
H range between the beginning of precipitation and 8.5 were S
Lu3+ = 3.5·10−7 mol·dm−3, S
Lu(OH)2+ = 6.2·10−7 mol·dm−3, and then total solubility was 9.7·10−7 mol·dm−3. 相似文献
6.
Ribeiro Guevara S Zizek S Repinc U Pérez Catán S Jaćimović R Horvat M 《Analytical and bioanalytical chemistry》2007,387(6):2185-2197
Mercury tracers are powerful tools that can be used to study mercury transformations in environmental systems, particularly
mercury methylation, demethylation and reduction in sediments and water. However, mercury transformation studies using tracers
can be subject to error, especially when used to assess methylation potential. The organic mercury extracted can be as low
as 0.01% of the endogenous labeled mercury, and artefacts and contamination present during methylmercury (MeHg) extraction
processes can cause interference. Solvent extraction methods based on the use of either KBr/H2SO4 or HCl were evaluated in freshwater sediments using 197Hg radiotracer. Values obtained for the 197Hg tracer in the organic phase were up to 25-fold higher when HCl was used, which is due to the coextraction of 197Hg2+ into the organic phase during MeHg extraction. Evaluations of the production of MeHg gave similar results with both MeHg
extraction procedures, but due to the higher Hg2+ contamination of the controls, the uncertainty in the determination was higher when HCl was used. The Hg2+ contamination of controls in the HCl extraction method showed a nonlinear correlation with the humic acid content of sediment
pore water. Therefore, use of the KBr/H2SO4 method is recommended, since it is free from these interferences. 197Hg radiotracer (T
1/2 = 2.673 d) has a production rate that is about 50 times higher than that of 203Hg (T
1/2 = 46.595 d), the most frequently used mercury radiotracer. Hence it is possible to obtain a similar level of performance
to 203Hg when it is used it in short-term experiments and produced by the irradiation of 196Hg with thermal neutrons, using mercury targets with the natural isotopic composition. However, if the 0.15% natural abundance
of the 196Hg isotope is increased, the specific activity of the 197Hg tracer can be significantly improved. In the present work, 197Hg tracer was produced from mercury 51.58% enriched in the 196Hg isotope, and a 340-fold increase in specific activity with respect to natural mercury targets was obtained. When this high
specific activity tracer is employed, mercury methylation and reduction experiments with minimum mercury additions are feasible.
Tracer recovery in methylation experiments (associated with Me197Hg production from 197Hg2+ spike, but also with Hg2+ contamination and Me197Hg artefacts) with marine sediments was about 0.005% g−1 WS (WS: wet sediment) after 20 h incubation with mercury additions of 0.05 ng g−1 WS, which is far below natural mercury levels. In this case, the amount of Hg2+ reduced to Hg0 (expressed as the percent 197Hg0 recovered with respect to the 197Hg2+ added) varied from 0.13 to 1.6% g−1 WS. Me197Hg production from 197Hg2+ spike after 20 h of incubation of freshwater sediment ranged from 0.02 to 0.13% g−1 WS with mercury additions of 2.5 ng g−1 WS, which is also far below natural levels. 197Hg0 recoveries were low, 0.0058 ± 0.0013% g−1 WS, but showed good reproducibility in five replicates. Me197Hg production from 197Hg2+ spiked in freshwater samples ranged from 0.1 to 0.3% over a period of three days with mercury additions of 10 ng L−1. A detection limit of 0.05% for Me197Hg production from 197Hg2+ spike was obtained in seawater in a 25 h incubation experiment with mercury additions of 12 ng L−1. 相似文献
7.
The mono- and bisligands complexes formed by rare earth cation (Sc, Y) with pentazolato anion or cyclo-P5− anion, the all-nitrogen counterparts of metallocenes or the all-phosphorus counterparts of metallocenes, have been studied
at hybrid basis sets level with the DFT method. The geometric parameters, binding energy and the charge distributions of these
complexes were characterized. And their stable orders were obtained. Monoligand complexes incline to become bisligands complexes
due to their destabilization. The charge transferring between ligand and metallic cation has affinity with the stability of
complex. The possibility of forming stable [M(η
5-E5)2] (M = Sc, Y, E = N, P) complexes is predicted and they are viable synthetic targets theoretically, especially Sc(η
5-N5)2. 相似文献
8.
Abdolraouf Samadi-Maybodi S. Masoomeh Pourali Mohsen Tafazzoli 《Journal of solution chemistry》2009,38(2):159-169
27Al NMR spectroscopy is a powerful tool for the study of coordination and solvation in both aqueous and nonaqueous solutions.
In this study, the complexes coexisting upon dissolution of AlCl3 in acidic acetone + methanol solutions are shown to consist essentially of mixed hexacoordinated species of the general formula
[Al(CH3OH)6−n
(CH3COCH3)
n
]3+ (n=1,2 and 3), all exhibiting distinctly different 27Al shielding effects. The relative populations of the various mixed species are found to be highly dependent upon the acetone:methanol
mole ratio that in the more acetone-rich mixtures with aluminum become appreciably coordinated by acetone. The results demonstrate
that the key factor for the formation of acetone-containing species in acidic methanolic solutions is having the CH3COCH3:CH3OH mole ratio at 3:1. 相似文献
9.
Rollie J. Myers 《Journal of solution chemistry》2007,36(3):395-403
We have measured the second acid dissociation constant, K
2a
, at several ionic strengths for hydrogen telluride (H2Te) using the Charge Transfer to Solvent (CTTS) uv spectra of its anions HTe− and Te2−. Since it is produced in our solutions, we have also determined the spectra of Te2
2− both in the uv and in the visible regions. At 25 ∘C, K
2a
= (1.28 ± 0.02) × 10−12 by extrapolation to zero ionic strength. Its value at an ionic strength equal to 0.5 mol.dm-3 was estimated to be (8.7 ± 0.2) × 10−12. The solution thermodynamics of these species are also discussed and comparisons are made to related acids. 相似文献
10.
The mechanism of the spin-forbidden reaction Ti+(4F, 3d24s1) + C2H4→TiC2H2
+ (2A2) + H2 on both doublet and quartet potential energy surfaces has been investigated at the B3LYP level of theory. Crossing points
between the potential energy surfaces and the possible spin inversion process are discussed by means of spin-orbit coupling
(SOC) calculations. The strength of the SOC between the low-lying quartet state and the doublet state is 59.3 cm−1 in the intermediate complex IM1-4B2. Thus, the changes of its spin multiplicity may occur from the quartet to the doublet surface to form IM1-2A1, leading to a sig-nificant decrease in the barrier height on the quartet PES. After the insertion intermediate IM2, two distinct
reaction paths on the doublet PES have been found, i.e., a stepwise path and a concerted path. The latter is found to be the
lowest energy path on the doublet PES to exothermic TiC2H2
+(2A2) + H2 products, with the active barrier of 4.52 kcal/mol. In other words, this reaction proceeds in the following way: Ti++C2H4→4IC→IM1-4B2→4,2ISC→IM1-2A1→[2TSins]→IM2→[2TSMCTS]→IM5→TiC2H2
+(2A2)+H2.
Supported by ‘Qinglan’ Talent Engineering Funds by Tianshui Normal University. 相似文献
11.
Lenoble V Garnier C Masion A Ziarelli F Garnier JM 《Analytical and bioanalytical chemistry》2008,390(2):749-757
This work allowed the characterization of the Cd-binding sites of two compounds taken as models for exudates, the main components
of soil organic matter (SOM). The studied compounds were exopolysaccharides (EPS), specifically exudates of roots (polygalacturonic
acid) and of soil bacteria (Phytagel). Potentiometric acid–base titrations were performed and fitting of the obtained results
indicated the presence of two main classes of acidic sites, defined by their pK
a values, for both EPS but of a different nature when comparing the two compounds. The two studied exopolysaccharides presented
different acidic/basic site ratios: 0.15 for Phytagel and 0.76 for polygalacturonic acid. Spectroscopic techniques (13C/113Cd NMR, FTIR) distinguished different Cd surroundings for each of the studied EPS, which is in agreement with the titration
results. Furthermore, these analyses indicated the presence of –COOH and –OH groups in various proportions for each exopolysaccharide,
which should be linked to their reactivity towards cadmium. Cadmium titrations (voltammetric measurements) also differentiated
different binding sites for each compound and allowed the determination of the strength of the Cd-binding site of the EPS.
Fitting of the results of such voltammetric measurements was performed using PROSECE (Programme d’Optimisation et de Speciation Chimique dans l’Environnement), a software coupling chemical speciation calculation and binding parameter optimization. The fitting, taking into account
the Cd2+/H+ competition towards exopolysaccharides, confirmed the acid-base titrations and spectroscopic analyses by revealing two classes
of binding sites: (i) one defined as a strong complexant regarding its Cd2+–EPS association (logK = 9–10.4) and with basic functionality regarding H+–EPS association (pK
a = 11.3–11.7), and (ii) one defined as a weak complexant (logK = 7.1–8.2) and with acidic functionality (pK
a = 3.7–4.0). Therefore the combination of spectroscopic analyses, voltammetry, and fitting allowed the precise characterization
of the binding sites of the studied exopolysaccharides, mimicking the main SOM components. Furthermore, the binding parameters
obtained by fitting can be used in biogeochemical models to better define the role of key SOM compounds like exudates of roots
and of soil bacteria on trace metal transport or assimilation. 相似文献
12.
Effects of La3+ and Eu3+ on outward potassium channels (Kout+) in Vicia guard cells have been studied by patch clamping technique. Extracellular La3+ inhibited Kout+ currents with a half-inhibition concentration (IC50) of 81 μmol·L−1. Interestingly, intracellular La3+ activated Kout+ currents at a free concentration of 1.13 × 10−14 mol·L−1, and inhibited Kout+ currents at a free concentration of 5.86 × 10−14 mol·L−1. Extracellular Eu3+ also activated Kout+ currents at concentrations of 10 μmol·L−1 and 50 μmol·L−1, and inhibited Kout+ currents at concentrations of more than 1 mmol·L−1. The effects of La3+ and Eu3+ on Kout+ currents may contribute to regulation of the plant water status, which may be one of the mechanisms of the biological effect
of rare earth elements. 相似文献
13.
V. Ya. Kavun I. A. Tkachenko N. A. Didenko A. B. Slobodyuk V. I. Sergienko 《Russian Journal of Inorganic Chemistry》2010,55(8):1179-1183
The ionic mobility in heptafluorozirconates (NH4)2.7Rb0.3ZrF7 and (NH4)2.75Cs0.25ZrF7 has been studied by 1H and 19F NMR in the temperature range 150–430 K. The types of ion motion were determined and their activation energies were estimated.
A phase transition results in a modification in which diffusion in the ammonium sublattice and orientational disorder of ZrF73− anions are observed. Owing to diffusion of ammonium ions, the compounds have relatively high ionic conductivity (σ ≥ 5 ×
10−5 S/cm at 420 K). 相似文献
14.
R. Dabbagh H. Ghafourian A. Baghvand G. R. Nabi H. Riahi M. A. Ahmadi Faghih 《Journal of Radioanalytical and Nuclear Chemistry》2007,272(1):53-59
The ability of living filamentous cells of the cyanobacterium Oscillatoria homogenea to separate stable strontium and 90Sr from aqueous solution is demonstrated in this study. On a basis of filamentous cell biovolume, the removal were 43.78 nM·ml·(mm3)−1 and 3129.48 mBq·ml·(mm3)−1 after 240 hour incubation. The optimum pH for strontium uptake is 9±0.3. The increasing biovolume of the blue-green alga
elevates sorption. In the liquid culture containing 21.2 mm3·ml−1 filamentous cells and 1000 nM·ml−1 initial strontium concentration, the maximum strontium removal was 455.34 nM·ml·(mm3)−1. At 1200 Lux illumination, the maximum removal value was 58.62 nM·ml·(mm3)−1, and at the initial strontium concentration of 6590 nM·ml−1, 235.40 nM·ml·(mm3)−1 removal was observed. The experimental data fitted to Langmuir isotherm and the model parameters and correlation coefficient
(R
2) were q
max = 7.143 μg·(mm3)−1, b = 0.003 and 0.99, respectively. 相似文献
15.
T. A. Mastryukova O. I. Artyushin M. P. Pasechnik E. V. Sharova I. L. Odinets V. P. Morgalyuk I. G. Tananaev G. V. Myasoedova B. F. Myasoedov 《Russian Chemical Bulletin》2005,54(11):2540-2544
The composition of complexes formed upon the extraction of UVI and ThIV nitrates with O-n-nonyl(N,N-dibutylcarbamoylmethyl) methyl phosphinate (L) from solutions of nitric acid without additional solvent was determined by 31P NMR spectroscopy. The structures of the complexes formed were studied by IR spectroscopy. Uranium(VI) is extracted from 3 and 5 M solutions of HNO3 as the [UO2(L)2(NO3)2] complex, while thorium(IV) is extracted from 5 M HNO3 as the [Th(L)3(NO3)3]+·NO
3
−
complex. In both cases, ligand L has bidentate coordination. Ligand L contacts with 3 and 5 M nitric acid to form adducts L·HNO3 and L· (HNO3)2, respectively.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2460–2464, November, 2005. 相似文献
16.
The Gibbs free energies of solvation (ΔG
s) and the electronic structures of endohedral metallofullerenes M+@C60 (M+= Li+, K+) were calculated within the framework of the density functional theory and the polarizable continuum model. In water environment,
the equilibrium position of K+ is at the center of the fullerene cavity whereas that of Li+ is shifted by 0.14 nm toward the fullerene cage. The Li+ cation is stabilized by interactions with both the fullerene and solvent. The equilibrium structures of both endohedral metallofullerenes
are characterized by very close ΔG
s values. In particular, the calculated ΔG
s values for K+@C60 are in the range from −124 to −149 kJ mol−1 depending on the basis set and on the type of the density functional. Molecular dynamics simulations (TIP3P H2O, OPLS force field, water sphere of radius 1.9 nm) showed that the radial distribution functions of water density around
C60 and M+@C60 are very similar, whereas orientations of water dipoles around the endohedral metallofullerenes resemble the hydration pattern
of isolated metal ions. 相似文献
17.
Kitamura K Omran AA Takegami S Tanaka R Kitade T 《Analytical and bioanalytical chemistry》2007,387(8):2843-2848
The interaction of a non-steroidal anti-inflammatory drug, niflumic acid (NFA), with human serum albumin (HSA) has been investigated
by 19F nuclear magnetic resonance (NMR) spectroscopy. A 19F NMR spectrum of NFA in a buffered (pH 7.4) solution of NaCl (0.1 mol L−1) contained a single sharp signal of its CF3 group 14.33 ppm from the internal reference 2,2,2-trifluoroethanol. Addition of 0.6 mmol L−1 HSA to the NFA buffer solution caused splitting of the CF3 signal into two broadened signals, shifted to the lower fields of 14.56 and 15.06 ppm, with an approximate intensity ratio
of 1:3. Denaturation of HSA by addition of 3.0 mol L−1 guanidine hydrochloride (GU) restored a single sharp signal of CF3 at 14.38 ppm, indicating complete liberation of NFA from HSA as a result of its denaturation. These results suggest that
the binding is reversible and occurs in at least two HSA regions. Competitive 19F NMR experiments using warfarin, dansyl-l-asparagine, and benzocaine (site I ligands), and l-tryptophan and ibuprofen (site II ligands) revealed that NFA binds to site I at two different regions, Ia and Ib, in the
ratio 1:3. By use of 19F NMR with NFA as an 19F NMR probe the nonfluorinated site I-binding drugs sulfobromophthalein and iophenoxic acid were also found to bind sites
Ia and Ib, respectively. These results illustrate the usefulness and convenience of 19F NMR for investigation of the HSA binding of both fluorinated and nonfluorinated drugs. 相似文献
18.
M. N. Sokolov E. V. Chubarova E. V. Peresypkina A. V. Virovets V. P. Fedin 《Russian Chemical Bulletin》2007,56(2):220-224
The reactions of the tetranuclear hydroxo complexes [M4(μ2-OH)8(H2O)16]8+ (M = Zr or Hf) with the lacunary Keggin-type ([α-PW11O39]7−) and Dawson-type ([α 2-P2W17O61]10−) phosphotungstates in aqueous solutions produce the sandwich polyoxometalate complexes [M(α-PW11O39)2]10− (M = Zr (1) or Hf (2)) and [M(α 2-P2W17O61)2]16− (M = Zr (3) and Hf (4)). The complexes were isolated and structurally characterized as salts with potassium and dimethylammonium cations. The zirconium
and hafnium atoms have a square antiprismatic coordination environment (coordination number is 8). In all complexes, the mutual
arrangement of the ligands corresponds to the syn isomer. Hafnium complexes 2 and 4 are the first structurally characterized polyoxometalate complexes of this metal. The structures of the resulting compounds
were confirmed also by 31P NMR spectroscopy in solution.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 214–218, February, 2007. 相似文献
19.
Soumen K. Maiti Debabrata Bera Parimal Chattopadhyay Lalitagauri Ray 《Applied biochemistry and biotechnology》2009,159(2):488-504
Due to technological advancement, environment suffers from untreated toxic heavy metal bearing effluent coming from different
industries. Chromium (VI) is one of those heavy metals having adverse impact on ecological balance, human, and plant health
because of its carcinogenic properties. Biosorption is presented as an alternative to traditional technologies which are costly
and inefficient for treatment of industrial wastes containing low amount of heavy metals. In this study, bioremediation of
Cr (VI) ions by immobilized Bacillus cereus M1
16 was investigated in a laboratory scale packed bed up-flow column reactor. The effect of important parameters, such as the
inlet flow rate, influent concentration, and effective bed height, has been studied. External mass transfer, surface adsorption,
and intrabead mass transfer were also studied to conclude the rate limiting step for removal of Cr (VI) and to determine the
process parameters which are important for biosorption optimization. The external mass transfer coefficient was calculated
at different flow rates (6.51 × 10−2 to 7.58 × 10−2 cm/min). Using the model, the surface adsorption rate constant (k
ad) and the intrabead mass transfer coefficient (k
i) were predicted as 0.0267 × 10−3 and 0.7465 × 10−3 l/g/min, respectively. Both are much lower than the external mass transfer coefficient (k
e). The surface adsorption phenomenon is acting as the rate-limiting step due to its high resistance for removal of Cr (VI). 相似文献
20.
The results of kinetic and equilibrium experiments with the set of reaction of proton abstraction from 4-nitrophenyl[bis(ethylsulphonyl)]methane
in acetonitrile are reported. Two strong organic bases are used: 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) and 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene
(MTBD).
The rates of proton transfer reaction have been measured by T-jump method in the presence of perchlorate of the appropriate
base as a common cation BH+ and supporting electrolyte-tetrabutylammonium perchlorate (TBAP) in the temperature range between 20–40°C are: k
H
=1.32×107−2.00×107 and 2.82×107−4.84×107 dm 3mol−1s−1 for MTBD and TBD respectively. The enthalpies of activation ΔH
MTBD
≠
=13.5 and ΔH
TBD
≠
=18.1 kJmol−1. The entropies of activation are negative: ΔS
MTBD
≠
=−62.3 and ΔS
TBD
≠
=−40.3 Jmol−1K−1.
The change of the absorbance of the anion of 4-nitrophenyl[bis9ethylsulphonyl)]methane at the temperature 25°C in the presence
of common cation BH+ gives the equilibrium constants K=705 and 906 M−1 for MTBD and TBD respectively.
Kinetic and equilibrium results are discussed. The possible mechanism of proton transfer reaction between 4-nitrophenyl[bis(ethylsulphonyl)]methane
and cyclic organic bases: MTBD and TBD in acetonitrile is proposed. 相似文献