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1.
HF的电子态X^1Σ^+和B^1Σ^+之势能函数和△ν=2泛频跃迁…   总被引:6,自引:3,他引:3  
用Murrell-Sorbie函数表述HF(X^1Σ^+和B^1Σ^+)的势能函数。通过对HF振转能级的计算,得到△ν=2泛频跃迁精细结构,所得结果中,基态之P支与W.Q.Jeffers发表的实验结果进行了比较。  相似文献   

2.
利用Guassian94程序和QCISD/6-311++G方法得到He-HF和He-FH两种线性平衡结构,计算出了这两种弱结合分子的结构参数、离解能和二阶力常数。在此基础上,利用多体项展式方法民出He-HF(X^1Σ^+)体系的分析势能函数,得到的势能面准确地再现了He-HF和He-FH两种线性结构。  相似文献   

3.
本采用H2O的二个^1A1态的双值多体项展式(DMBE)势能函数,用Ehrenfest模型方法研究了反应(1)O(^1D)+H2→OH和(2)O(^1D)+H2→OH(A^2∑^+)+H的非绝热碰撞动力学过程。讨论了电子非绝热跃迁对反应(1)的影响及H2振动能对反应(2)的促进作用。并求得反应(1)的室温速度常数为0.944×10^-^1^0cm^3.molecule^-^1.s^-^1。  相似文献   

4.
低温宽带NaCl(OH^—):(F^+2)H色心激光的实验研究   总被引:2,自引:1,他引:1  
林碧洲  许承晃 《光学学报》1994,14(4):46-350
在NaCl晶体中掺入OH^-离子可以有效地提高F^+2心的稳定性。采用四镜折迭X型像散补偿腔,获得了峰值波长1.57μm、输出功率>250mW的低温宽带NaCl(OH^-):(F^+2)H色心激光。本文着重讨论OH^-对F^+2心的稳定作用和影响色心激光振荡的各种因素。  相似文献   

5.
PuO2体系的分子反应动力学研究   总被引:2,自引:1,他引:1  
基于PuO2分子(X^5Σg^+)的多体展式分析势能函数,用准经典的Monte-Carlo轨迹法研究了O(^3Pg)+PuO(0,0)和Pu(^7Fg)+O2(0,0)的分子反应动力学过程。结果表明:O(^3Pg)+PuO(0,0)碰撞生成少量稳定络合物PuO2(X^5Σg^+),该反应是无阈能反应;而Pu(^7Fg)+O2(0,0)碰撞生成稳定络合物的同时,主要还发生了Pu(^7Fg)+O2(0  相似文献   

6.
林碧洲  许承晃 《光学学报》1996,16(2):62-166
研究了K^+对NaCl(OH^-)中(F^+2)H心的形成及其光谱性质的影响。结果表明,K^+的存在抑制了F^+2型心的形成,发迹了(F^+2)H心的光谱性质,拓宽了发射谱的半功率谱宽。  相似文献   

7.
用Penning型离子阱经碰撞反应H2^++H2→H4^+产生稳定的H4^+,主要的反应产物是H3^+,但十分明显地观测到H4^+信号。H4^+在阱中稳定存在时间长达0.1s量级,远比Kirchner等人测量的10^-6s量级长,最后讨论了生成H4^+的反应过程机制。  相似文献   

8.
氟锆酸盐玻璃中Tm^3+离子的红外光谱性质   总被引:1,自引:1,他引:0  
根据Tm^3+离子有吸收光谱,计算在氟锆酸盐玻璃中的^Tm^3+的Judd-Ofelt参数和工外跃迁^3Fi→^3H4,^3H4→^3H6和3F4→^3H5 发跃迁几率,研究了Tm^3+的红外发射光谱的交叉驰豫过程,讨论了离子浓度对红外发光强度的影响,并讨论了这些跃迁的发射截面。  相似文献   

9.
NaF:OH^—晶体色心及其在氮分子激光照射下的光谱特性   总被引:1,自引:1,他引:0  
冯志萍  王存达 《光学学报》1995,15(8):046-1049
对NaF晶体和NaF:OH^-晶体在电子束辐照前后及在氮分子激光作用下的红外和紫外光谱进行了研究。认为激光强度能否使OH^-分解,决定着F^+2心的再生或退电离。  相似文献   

10.
采用傅里叶变换光谱技术(FTS)记录了CH^35Cl3和它的同位素分子CH^35Cl2^37Cl的V=3的高分辨光谱,由于0.02m^-1分经不足以分辨K结构,我们将所观察到的谱线近似归属为K=0的转动能级,归属了CH^35Cl3岔子4〈J〈73,CH^35Cl^37Cl分子6〈J〈53的转动级。最后采用最小二乘法拟合,得到了关于J的转动常数和振动带心。  相似文献   

11.
Two-dimensional scanning of a 0.6328 mum guided-light beam has been realized using noncolinear acousto-optic (AO) coplanar Bragg diffraction together with colinear AO guided-mode to substrate radiation-mode conversion in a Z-cut Xpropagation LiNbO3 proton-exchanged (PE) waveguide. The two surface acoustic (SAW) waves utilized are at the center frequencies of 500 and 200 MHz, propagating in the Y and X axes, respectively. Two-dimensional scanning of approximately 720 resolvable light beam spots, namely, 18 40 (horizontal vertical) scanning, has been demonstrated using a light beam of 1.0 mm aperture. The total number of resolvable beam spots can be greatly increased from 720 by simply utilizing SAW transducers of larger bandwidth and a light beam of greater aperture. It should also be possible to significantly increase the diffraction efficiency from 3 % by optimizing the parameters of the PE waveguide and the SAWs.  相似文献   

12.
Results of a study of the effect of γ-radiation on the spectral luminescence properties of cadmium tungstate crystals doped with silver, bismuth, and molybdenum cations are presented. Spectral characteristics of the nondnnnoped crystals are briefly described. Absorption and photo and X-ray luminescence spectra of the crystals taken before and after exposure to γ-radiation (5.5·104 Gy) are compared. It is found that the spectral characteristics of the crystals doped with silver, bismuth, and molybdenum cations do not change markedly after the exposure. The relation between the type of impurity-induced defects, individual characteristics of the impurity cations, and the character of the effect of γ-radiation on the spectral luminescence properties of impure crystals is analyzed (preliminarily). Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 1, pp. 55–60, January–February, 1997.  相似文献   

13.
We measure the waveform and phase curves of short optical pulses before and after transmission over different lengths of fibers by use of the pulse analyzer with the frequency-resolved optical gating (FROG),and numerically simulate pulse evolution under the experimental conditions.The nonlinear coefficient of the fiber is given by comparing the experimental results with the numerical ones.Difference between the experiment and numerical simulation is analyzed.  相似文献   

14.
Resonance scattering of elastic spherical shell and cylindrical shell while the surrounding fluid medium has absorption is studied. The normal mode solution derived using exact elastic theory and the separation of variables is still applicable. However, the scattering form function has to be modified for the absorbing medium, otherwise the unreasonable result would be obtained. The backscattering form function in the absorbing medium is redefined, and the form function of elastic spherical and cylindrical shell with vacuum or solid matter filled is calculated in various absorption conditions. The results show that the absorption of surrounding fluid leads to notable attenuation of the coincidence resonances in the mid-frequency, but it has a little influence on the low-frequency resonance scattering induced by the filler inside the shell.  相似文献   

15.
A versatile and low-cost single-beam self-referenced phase-sensitive surface plasmon resonance(SPR)sensing system with ultra-high resolution performance is presented.The system exhibits a root-mean-square phase fluctuation of ±0.0028.over a period of 45 min.i.e.a resolution of±5.2×10-9 refractive index units.The enhanced performance has been achieved through the incorporation of three design elements:a true single-beam configuration enabling complete self-referencing so that only the phase change associated with SPR gets detected,a differential measurement scheme to eliminate spurious signals not related to the sensor response,and the elimination of retardation drifts by incorporating temperature stabilization in the liquid crystal phase modulato .Our design should bring the detection sensitivity of non-labeling SPR biosensing closer to that achievable by conventional fluorescence-based techniques.  相似文献   

16.
Ta2O5 films are prepared on BK7 substrates with conventional electron beam evaporation deposition.The effects of SiO2 protective layers and annealing on the laser-induced damage threshold (LIDT) of the films are investigated.The results show that SiO2 protective layers exert little influence on the electric field intensity(EFI)distribution,microstructure and microdefect density but increase the absorption slightly.Annealing iS effective on decreasing the microdefect density and the absorption of the films.Both SiO2 protective layers and annealing are beneficial to the damage resistance of the films and the latter is more effective to improve the LIDT.Moreover,the maximal LIDT of Ta2O5 films is achieved by the combination of SiO2 protective layers and annealing.  相似文献   

17.
Gray cross correlation matching technique is adopted to extract candidate matches with gray cross correla- tion coefficients less than some certain range of maximal correlation coefficient called multi-peak candidate matches. Multi-peak candidates are extracted corresponding to three closest feature points at first. The corresponding multi-peak candidate matches are used to construct the model polygon. Correspondence is determined based on the local geometric relations between the three feature points and the multi-peak candidates. The disparity test and the global consistency checkout are applied to eliminate the remaining ambiguous matches that are not removed by the local geometric relational test. Experimental results show that the proposed algorithm is feasible and accurate.  相似文献   

18.
A novel method based on fiber gratings for measuring the effective indices of fiber modes is proposed. The effective index difference between the core mode and a cladding mode was obtained by analyzing the interference fringe of a pair of cascaded long-period fiber gratings. In order to extract the core mode index from the measured index difference, an index matching oil immersion method is proposed. By analyzing the interaction between the cladding mode and the oil applied on the cladding surface, the mode order and the effective index of the involved cladding mode might be calculated. Experimental results about the interference fringe shifts induced by the oil index and the oil-applied length are also presented.  相似文献   

19.
Optical Pulse Compression Schemes That Use Nonlinear Bragg Gratings   总被引:2,自引:0,他引:2  
Nonlinear optical pulse compression of picosecond pulses typically requires long lengths of optical fiber and multiple components. Periodic structures, such as fiber Bragg gratings, are highly dispersive at wavelengths outside of the photonic bandgap. This implies that such gratings can be used as very short all-fiber compressors. In this paper a number of such compression schemes are reviewed involving uniform and nonuniform fiber Bragg gratings, relying on both soliton and nonsoliton compression principles. Experimental results supporting the corresponding underlying theory are also presented. Finally, an extension of one of the compression schemes is shown, which allows the generation of adjustable high-repetition rate soliton trains.  相似文献   

20.
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