Temperature analysis of the powder streams in coaxial laser cladding

The powder stream temperature of a newly developed coaxial laser cladding technique have been calculated and measured in this study. A simplified one-dimensional model of the particle heating problem under laser irradiation was solved with various conditions of laser intensity, particle size and flow velocity. The experimental results have been successfully detected by a pin-hole infrared sensor with the temperature calibration for hot particles. The thermal profiles of the coaxial nozzle give an optimum operation range of the stand-off distance for coaxial laser cladding.     

激光点火煤粒周围的温度场

本文采用激光全息摄影技术记录激光加热下的单颗粒煤在某一时刻燃烧的全息图，通过再现系统和数字图象处理过程而获得二维的温度场分布，为研究煤的着火与燃烧的特性提供了一种新方法．同时采用了数学模型对几种煤从着火到燃尽时其周围的温度场进行计算，与实验进行了比较，得到了较为一致的结果．     

The formation of micro/nanoparticles in laser-enhanced electroplating with continuous-wave and pulsed Nd-YAG laser interactions

The copper particles generated by the laser-enhanced electroplating method have been investigated in this study, and the results have been examined at various process conditions. The electrolyte jet of copper sulfate was impinged on a stainless steel electrode and irradiated with a Nd-YAG laser at continuous-wave (CW) and Q-switched output modes, respectively, to generate the particle size distribution from micro- to nano-scale.According to the electrochemical dynamics theory, the mechanism of the proposed technique for the particles formation is mainly due to the thermal effects from the laser interaction in electroplating. In the experiments, the laser energy absorbed by the electrolyte jet and the temperature rise of the electrode during the laser radiation has been measured. In the numerical simulation, the temperature fields of the impinging jet of the laser nozzle were calculated. It shows that the growth of the particle is significantly corresponding to the laser power and pulse mode of the laser interaction.     

A unipolar pulsed plasma generator in combination with a laser as a plasma jet source

A pulsed plasma generator ignited by plasma produced by laser radiation is described. The plasma generator can provide a relatively high-velocity plasma jet of specific chemical composition. The principal parameters of the plasma jet (its velocity, charged particle concentration, and temperature) have been measured and the properties of the plasma jet have been found to be independent of the polarity of the plasma generator ring electrode.The authors are grateful to M. A. El'yashevich for discussing the present paper.     

Time-resolved two-color LII: size distributions of nano-particles from gas-to-particle synthesis

A two-color LII technique for in situ measurements of particle size distributions is described. The technique is based on the simultaneous detection of time-resolved LII signals at two different wavelengths with one-dimensional spatial resolution using a newly developed experimental setup. The ratio of both LII signals yields particle temperatures as a function of time and location. Measured particle temperature decays are numerically simulated based on a detailed cooling model for particle ensembles. Particle size distributions are obtained by fitting simulated particle temperature decays to measured ones using multi-dimensional non-linear regression. The two-color LII technique for particle sizing can be applied to a wide range of materials because it is independent of the optical properties of the particle material. Exemplarily, the measuring technique is applied to investigate the synthesis of nanoscaled metal oxide particle in a laser vaporization reactor.     

Simultaneous measurement of particle size, velocity, andtemperature in thermal plasmas

The in-flight measurement of particle parameters (size, velocity, temperature, and local number density) can prove insight into the plasma processing of solid materials. A measurement technique for simultaneously obtaining the size, velocity, and temperature of particles entrained in high-temperature flow fields is described. Particle size and velocity are obtained from a combination laser-particle-sizing system and laser Doppler velocimeter. The particle temperature is determined by a two-color pyrometry technique and the data rate is a measure of relative particle number density. Typical measured temperatures and velocities for the 5-100 μm particles used in plasma spraying are 1600-3500 K and 100-300 m/s, respectively. Since particle size, velocity, and temperature are measured simultaneously, cold particles (<1600 K) are identified and their relative number density can be quantified. Data from two plasma spray systems, a metal one (Ni-Al) and a metal oxide one (Al₂O₃), are presented and their application to understanding the plasma spray-coating process is illustrated     

Observation of laser light scattering by a turbulent gas without seeding

An experiment of laser light scattering by a turbulent highly subsonic free jet of air is presented. The originality of the method lies in the fact that no particle seeding is needed. The experimental scattering cross section, which can be interpreted from the three-dimensional spectral density of temperature fluctuations, is compared to the theoretical one obtained by turbulent mixing theories. The scattered field time correlations measured in the heterodyne mode are interpreted by considering the Doppler effect on moving turbulent eddies and compared with theory. The intensity time correlations measured in the homodyne mode are interpreted in terms of local properties of the turbulence.     

Collective Scattering of Electromagnetic Waves from a Relativistic Magnetized Plasma

Recently, laser and microwave scatterings have become one of the important diagnostic means for plasma. Laser and microwave correlative scattering spectrum is determined by particle-density fluctuations in a weak turbulent plasma. In a relativistic plasma, on the basis of complete electromagnetic interaction between particles, a general expression for particle density fluctuations and spectra of laser and microwave scattering from a magnetized plasma are derived. The laser and microwave scattering spectra provide information on electron density and temperature, ion temperature, resonance and nonresonance effects.     

Effect of surrounding gas temperature on the morphological evolution of TiO2 nanoparticles generated by laser ablation in tubular furnace

Titanium oxide nanoparticles are synthesized by laser ablation of Ti target in oxygen atmosphere under well-controlled temperature profiles in a tubular furnace. The size and the shape of generated nanoparticles are varied by changing the temperature of furnace. The mobility-based size distributions of generated air-borne nanoparticles are measured using a scanning mobility particle sizer, and the size distributions of primary particles are analyzed by a scanning electron microscope. When the particles are generated by laser ablation at the room temperature, the particles are agglomerates in gas phase with the average mobility diameter of 117 nm and the mean diameter of primary particles of 11 nm. The primary particle diameter increases from 11 to 24 nm by raising the furnace temperature up to 800 °C. Since the mass of Ti vapor ablated from a target is found to be constant regardless of the furnace temperature, this particle growth may be attributed to the reduction in nuclei number as a result of mild quenching at higher temperatures. As the temperature reaches higher than 1,000 °C, the mobility diameter suddenly drops and the primary particle diameter increases due to sintering, and at 1,200 °C the mobility diameter coincides with the primary particle diameter. Since the laser oven method offers an independent control of vapor concentration and the temperature of surrounding atmosphere, it is an effective tool to study the formation process of nanoparticles from primary particles with a given size.     

Laser diagnostics of a low-pressure hollow-cathode arc

We report the use of resonance fluorescence induced by a repetitively pulsed tunable dye laser in measuring electron collisional transfer rates between fine-structure levels, electron density and neutral particle temperature in a low-pressure hollow-cathode arc. Excitation by a narrow bandwidth laser is analyzed to obtain correct interpretation of the results. A power-broadening formula, which is valid for large saturation parameters, has been derived and experimentally verified.     

Constraints of two-colour TiRe-LII at elevated pressures

The main objective of this work is to investigate the influence of high-pressure conditions on the determination of primary particle size distributions of laser-heated soot particles using pyrometrically determined temperature decays. The method is based on time-resolved laser-induced incandescence measurements carried out at two different wavelengths (two-colour TiRe-LII). The LII signals are transferred into a particle ensemble averaged (effective) temperature using Planck’s thermal radiation formula. Assuming that all particles within the size distribution possess a unique temperature at the end of the laser pulse, the size distribution can be determined by numerically simulating the measured temperature decay. From our investigations, for pressures up to a few bars it is obvious that this strategy can be successfully applied if standard laser pulses of nano-second duration are used as an LII-excitation source. At higher pressures the time scales of heat conduction are decreased to such an extent that a unique temperature for all particles within the ensemble cannot be assumed at the end of the nano-second laser pulse. However, further investigations show that the presented two-colour TiRe-LII technique can be successfully adopted under technical high-pressure conditions as well, if the pulse duration of the TiRe-LII-excitation source is reduced into the pico-second range.     

Determination of Particle Mass Density Distribution

A new method for the determination of two characteristics of a sample of particles, the correlation of particle mass density with particle size and the distribution of particle mass density, is presented. The new method to meet these requirements is based on the combination of two optical particle sizing techniques where the measured particle characteristics have a different dependence on particle mass density. Photosedimentation and laser diffraction were chosen as suitable techniques for this goal. The determination of particle mass density by photosedimentation and laser diffraction is based on the fact that for each particle size class of the sample to be analysed the mass density can be calculated by an application of the Lambert-Beer law. The particle size distribution of the sample has to be known for the determination of particle mass density, and it is measured by laser diffraction. From this, two particle characteristics, the relationship of particle mass density and particle size and the distribution of particle mass density, are obtained. The capacity of the algorithm and its limitations are demonstrated by computational simulations including an error propagation analysis. Experimental results are shown for homogeneous and heterogeneous materials.     

Thermal processes of a powder particle in coaxial laser cladding

This paper presents a numerical analysis of the heating, melting and evaporation processes of a single spherical powder particle when irradiated by a CO₂ laser beam in coaxial laser cladding. The power particle has a size ranging from 20 to 200 μm and the intensity of the laser has been varied from 500 to 3000 W. The laser energy, initial powder velocity and size have been shown to have important effects on the temperature profile of the powder stream. It has also been shown that high powder evaporation due to high power laser radiation may induce significant loss in the powder particle mass, to as much as 25% of the initial size at certain conditions in the simulation.     

Heat conduction from a spherical nano-particle: status of modeling heat conduction in laser-induced incandescence

Laser-induced incandescence (LII) of nano-second pulsed laser heated nano-particles has been developed into a popular technique for characterizing concentration and size of particles suspended in a gas and continues to draw increased research attention. Heat conduction is in general the dominant particle cooling mechanism after the laser pulse. Accurate calculation of the particle cooling rate is essential for accurate analysis of LII experimental data. Modelling of particle conduction heat loss has often been flawed. This paper attempts to provide a comprehensive review of the heat conduction modelling practice in the LII literature and an overview of the physics of heat conduction loss from a single spherical particle in the entire range of Knudsen number with emphasis on the transition regime. Various transition regime models developed in the literature are discussed with their accuracy evaluated against direct simulation Monte Carlo results under different particle-to-gas temperature ratios. The importance of accounting for the variation of the thermal properties of the surrounding gas between the gas temperature and the particle temperature is demonstrated. Effects of using these heat conduction models on the inferred particle diameter or the thermal accommodation coefficient are also evaluated. The popular McCoy and Cha model is extensively discussed and evaluated. Based on its superior accuracy in the entire transition regime and even under large particle-to-gas temperature ratios, the Fuchs boundary-sphere model is recommended for modeling particle heat conduction cooling in LII applications. PACS 44.05.+e; 44.10.+i; 47.45.-n; 61.46.Df; 78.70.-g     

连续波DF化学激光器光斑上下游光谱测量

通过分析非稳腔DF化学激光器光腔内激光路径特性,指出非稳腔DF化学激光器输出光斑上下游光谱振荡路径不同导致输出光谱存在一定差异。试验测量了一台连续波DF化学激光器光斑上下游光谱,结果表明:非稳腔DF化学激光器光斑上下游光谱主要谱线成分未见显著差异;光斑上下游谱线相对强度存在一定差异;光斑上游各谱带相对强度最大值谱线转动量子数趋向于各谱带低转动量子数方向。根据实测光谱,对光斑上下游光谱所表征光腔温度和相对粒子数范围进行了估算,得到光腔上游平均温度要低于光腔下游平均温度。     

Interaction of gold nanoparticles with nanosecond laser pulses: Nanoparticle heating

Theoretical and experimental results on the heating process of gold nanoparticles irradiated by nanosecond laser pulses are presented. The efficiency of particle heating is demonstrated by in-vitro photothermal therapy of human tumor cells. Gold nanoparticles with diameters of 40 and 100 nm are added as colloid in the cell culture and the samples are irradiated by nanosecond pulses at wavelength of 532 nm delivered by Nd:YAG laser system. The results indicate clear cytotoxic effect of application of nanoparticle as more efficient is the case of using particles with diameter of 100 nm. The theoretical analysis of the heating process of nanoparticle interacting with laser radiation is based on the Mie scattering theory, which is used for calculation of the particle absorption coefficient, and two-dimensional heat diffusion model, which describes the particle and the surrounding medium temperature evolution. Using this model the dependence of the achieved maximal temperature in the particles on the applied laser fluence and time evolution of the particle temperature is obtained.     

Investigation on the direct laser metallic powder deposition process via temperature measurement

The direct laser metallic powder deposition process was investigated with the aid of a radiant thermometer by building thin walls. The measured infrared (IR) temperature signal showed good correlation with the deposition process and the quality of the deposited samples. The influence of the powder particle size and the z-increment on the quality of the deposited samples and the IR-temperature signal was examined. It was found that the particle size of the powders shows no significant influence on the measured IR-temperature signal and the deposition process. However, both the deposition process and the measured temperature signal depended strongly on the z-increment. The variation of the melt pool temperature and cooling rate resulted in an inhomogeneous dimension accuracy, microstructure and hardness of the deposited sample. An abnormal deposition process can be recognized by the IR-temperature signal.     

Influence of a high-speed dielectric spherical particle''s movement on its scattering characteristics

The scattered field and differential scattered section (DSS) of a moving spherical particle with a high speed are investigated numerically. The coordinate and vector transformations are used to establish a theoretical basis for studying the laser scattering of a moving particle. The DSS of a moving spherical particle is explained by the electric and magnetic field from Mie scattering theory. Assuming the laser wavelength of 1.06 μm, we compute the ratio of the laser DSS of the moving dielectric spherical particle to that of the static dielectric spherical particle, which changes with radii, speeds and scattering angles of the particle. The numerical results show that the laser DSS of the oving pherical particle is tightly connected with its speed and scattering zenith angle. If a spherical particle moves with high speed, the laser DSS due to movement of the particle could not be neglected. If the speed of the dielectric spherical particle is fluctuating, the Doppler effect and the frequency spectrum expansion play important roles.     

Pipe flow measurement by using a side-scattering holographic particle imaging technique

A side scattering holographic particle imaging technique has been developed and demonstrated to be a capable tool for obtaining good quality images of a particle field in a high Reynolds number pipe flow. Instantaneous three-dimensional velocity components can be measured. The streamwise velocity error is estimated to be about 5%. Limitations of this optical set-up are discussed. The methodology and results presented will be of use for designing a pulsed laser holographic technique for turbulent velocity measurement or particle diagnostics in a pipe flow.