Temporal oscillations of the shear stress and scattered light in a shear-banding-shear-thickening micellar solution

The results of optical and rheological experiments performed on a viscoelastic solution (cetyltrimethylammonium bromide + sodium salicylate in water) are reported. The flow curve has a horizontal plateau extending between two critical shear rates characteristic of heterogeneous flows formed by two layers of fluid with different viscosities. These two bands which also have different optical anisotropy are clearly seen by direct observation in polarized light. At the end of the plateau, apparent shear thickening is observed in a narrow range of shear rates; in phase oscillations of the shear stress and of the first normal stress difference are recorded in a shearing device operating under controlled strain. The direct observation of the annular gap of a Couette cell in a direction perpendicular to a plane containing the vorticity shows that the turbidity of the whole sample also undergoes time dependent variations with the same period as the shear stress. However no banding is observed during the oscillations and the flow remains homogeneous.     

Nonlocal effects in flows of wormlike micellar solutions

The flow curve of wormlike micelles usually exhibits a stress plateau sigma* separating high and low viscosity branches, leading to shear-banded flows. We study the flow of semidilute wormlike micellar systems in a confined geometry: a straight microchannel. We characterize their local rheology thanks to particle image velocimetry. We show that flow curves cannot be described by a simple constitutive equation linking the local shear stress to the local shear rate. We demonstrate the existence of nonlocal effects in the flow of wormlike micellar systems and make use of a theoretical framework allowing the measurement of correlation lengths.     

Nonaxisymmetric instability of shear-banded Taylor-Couette flow

Recent experiments show that shear-banded flows of semidilute wormlike micelles in Taylor-Couette geometry exhibit a flow instability in the form of Taylor-like vortices. Here we perform the nonaxisymmetric linear stability analysis of the diffusive Johnson-Segalman model of shear banding and show that the nature of this instability depends on the applied shear rate. For the experimentally relevant parameters, we find that at the beginning of the stress plateau the instability is driven by the interface between the bands, while most of the stress plateau is occupied by the bulk instability of the high-shear-rate band. Our work significantly alters the recently proposed stability diagram of shear-banded flows based on axisymmetric analysis.     

Yieldlike constitutive transition in shear flow of entangled polymeric fluids

We describe an unexpected constitutive transition in entangled polymer solutions. At and beyond a critical stress, the initial spatially homogeneous and well-entangled sample transforms from its entangled (coiled) state into a fully disentangled (stretched) state over a period during which the resulting shear rate increases in a spatially inhomogeneous fashion. In the mode of controlled shear rate, the sample exhibits a stress plateau over three decades. Flow birefringence and normal stress observations unravel additional features of these flow phenomena.     

Linear and nonlinear rheology of wormlike micelles

Several surfactant molecules self-assemble in solution to form long, cylindrical, flexible wormlike micelles. These micelles can be entangled with each other leading to viscoelastic phases. The rheological properties of such phases are very interesting and have been the subject of a large number of experimental and theoretical studies in recent years. We shall report our recent work on the macrorheology, microrheology and nonlinear flow behaviour of dilute aqueous solutions of a surfactant CTAT (Cetyltrimethylammonium Tosilate). This system forms elongated micelles and exhibits strong viscoelasticity at low concentrations (∼0.9 wt%) without the addition of electrolytes. Microrheology measurements of G(θ) have been done using diffusing wave spectroscopy which will be compared with the conventional frequency sweep measurements done using a cone and plate rheometer. The second part of the paper deals with the nonlinear rheology where the measured shear stress σ is a nonmonotonic function of the shear rate . In stress-controlled experiments, the shear stress shows a plateau for larger than some critical strain rate, similar to the earlier reports on CPyCl/NaSal system. Cates et al have proposed that the plateau is a signature of mechanical instability in the form of shear bands. We have carried out extensive experiments under controlled strain rate conditions, to study the time-dependence of shear stress. The measured time series of shear stress has been analysed in terms of correlation integral and Lyapunov exponent to show unambiguously that the behaviour is typical of low dimensional dynamical systems.     

Velocity profiles in shear-banding wormlike micelles

Using dynamic light scattering in heterodyne mode, we measure velocity profiles in a much studied system of wormlike micelles (CPCl/NaSal) known to exhibit both shear-banding and stress plateau behavior. Our data provide evidence for the simplest shear-banding scenario, according to which the effective viscosity drop in the system is due to the nucleation and growth of a highly sheared band in the gap, whose thickness linearly increases with the imposed shear rate. We discuss various details of the velocity profiles in all the regions of the flow curve and emphasize the complex, non-Newtonian nature of the flow in the highly sheared band.     

Asymmetry of the wall shear stress in a stimulated ascendant flow of a liquid with monodisperse bubbles

Results of an experimental investigation of the two-phase wall shear stress averaged over the tube perimeter and the pulsation of wall shear stress in a stimulated ascendant flow with monodisperse bubbles with an average diameter of 1.2 and 2.2 mm are presented. Regimes with various hydrodynamic parameters such as high shear stress on the wall, low and negative wall shear stress, a high level of shear stress pulsation on the wall, and possible decrease in this level of pulsation are found. An increase in the void gas fraction results in a monotonic increase of perturbation of the single-phase flow. The dependences of the ratio of two-phase and single-phase wall shear stresses for two average bubble diameters seem to be qualitatively similar. The analysis of data revealed a complex dependence of the shear stress pulsation on the bubble diameter. The averaged flow characteristics quantitatively change upon the decrease in the bubble diameter. A further decrease in the average bubble diameter at the same void gas fraction will probably increase the heat-and mass-transfer characteristics of the flow. This is an issue for the futures study.     

Experimental study of the Taylor bubbles shear stress in an upward flow in a vertical tube

The modification of electrodiffusional method of the wall shear stress measurements is applied for registration of the Taylor bubble shear stress in an upward liquid flow. Time realization of shear is considered as a structure frozen into the flow, which moves together with a bubble. Experiments were carried out in laminar and transitional liquid flows. The wall shear stress in the liquid film around bubble averaged over the tube perimeter is presented for different flow Reynolds numbers and different lengths of the bubble.     

Flow phase diagrams for concentration-coupled shear banding

After surveying the experimental evidence for concentration coupling in the shear banding of wormlike micellar surfactant systems, we present flow phase diagrams spanned by shear stress Σ (or strain rate ) and concentration, calculated within the two-fluid, non-local Johnson-Segalman (d-JS-φ) model. We also give results for the macroscopic flow curves Σ(ˉ,ˉφ) for a range of (average) concentrations ˉφ. For any concentration that is high enough to give shear banding, the flow curve shows the usual non-analytic kink at the onset of banding, followed by a coexistence “plateau” that slopes upwards, dΣ/dˉ > 0. As the concentration is reduced, the width of the coexistence regime diminishes and eventually terminates at a non-equilibrium critical point [Σ_c,ˉφ_c,ˉ_c]. We outline the way in which the flow phase diagram can be reconstructed from a family of such flow curves, Σ(ˉ,ˉφ), measured for several different values of ˉφ. This reconstruction could be used to check new measurements of concentration differences between the coexisting bands. Our d-JS-φ model contains two different spatial gradient terms that describe the interface between the shear bands. The first is in the viscoelastic constitutive equation, with a characteristic (mesh) length l. The second is in the (generalised) Cahn-Hilliard equation, with the characteristic length ξ for equilibrium concentration-fluctuations. We show that the phase diagrams (and so also the flow curves) depend on the ratio r ≡ l /ξ, with loss of unique state selection at r = 0. We also give results for the full shear-banded profiles, and study the divergence of the interfacial width (relative to l and ξ) at the critical point. Received: 20 December 2002 / Accepted: 24 April 2003 / Published online: 11 June 2003 RID="a" ID="a"e-mail: physf@irc.leeds.ac.uk RID="b" ID="b"e-mail: p.d.olmsted@leeds.ac.uk     

Processing Polymer Melts under Rheo-Fluidification Flow Conditions,Part 2: Simple Flow Simulations

The flow equations for melts submitted to conditions of Rheo-Fluidification processing described in Part 1 are determined and solved numerically. The pressure flow from an extruder feed end and drag flow from the modulated rotation of the rotor, i.e., under extrusion conditions with both cross-rotational and oscillatory flow, are combined. The value of pressure, shear stress, and viscosity along the flow path of the melt (a helicoidal motion around a divergent conic surface), for a given throughput and temperature, as the melt is moved through an annular gap of constant thickness are calculated. The simulation is restricted to the simpler case of low throughput where elongational flow can be assumed to be negligible and shear dominates the viscosity expression. The classic lubrication approximation hypothesis applied to a power law fluid is used. This assumption appears justified because of the geometry of the die, which consists of a thin annulus of 2 mm extended over a die length of 570 mm (see Part 1). The viscosity is expressed as a function of strain rate, which is calculated from the contribution of pressure flow, rotational flow, and superposed oscillation. The combined shear rate is calculated assuming a vectorial combination of the individual shear rates, following Cogswell who verified this hypothesis, and according to our own validation of this assumption on the same polymer, using a Couette without vibration.     

Calculation of the Viscosity of Polymer Melts Based on Measurements of the Recovered Rubber-Like Deformation

On the basis of a model of polymer flow, considering the forces of entropic elasticity of extended macromolecules within the Eyring's concept, the relationships between the shear rate, shear stress, viscosity, and recovered rubber-like deformation were derived. The reduction of activation energy of the flow, by an amount proportional to the recovered rubber-like deformation, leads to an exponential decrease of viscosity with increasing shear rates; this nonlinear dependence of viscosity on shear rate (and shear stress) is defined as the viscosity anomaly of polymers. The measurement of deformation recovery after the cessation of polymer flow in the mode of constant shear rate or shear stress on a rotational viscometer confirmed the validity of the theoretical dependences.     

Influence of bubbly clusters on the characteristics of the two-phase gas-liquid flow in a flat channel

Results of experimental investigation of a bubbly gas-liquid flow in horizontal and weakly inclined (from −20° to +20°) flat channel are presented. These measurements were carried out within the 0.2–1 m/s range of superficial velocities and volumetric gas flow rate ratio of up to 0.2. The hydrodynamic structure was measured by the electrochemical method with application of wall shear stress and conductivity microprobes. During the experiments signals of shear stress on the upper channel wall and local gas flow rate ratio were recorded completely. After numerical treatment of recorded signals the profiles of local gas flow rate ratio were obtained, average shear stress and its relative mean square pulsations on the upper channel wall were determined. It is shown that under the studied regimes the bubbles are grouped into clusters, and the bubbly flow is presented by alternation of bubbly clusters and single-phase liquid with separate bubbles and without them. Average wall shear stress and absolute shear stress pulsations in the range of bubbly clusters and beyond them were determined. Histograms of probability density distribution were obtained for the wall shear stress on the upper wall. It is shown that average shear stress and absolute pulsations in clusters are significantly higher than those in the flow zone free from bubbles. The work was financially supported by the Russian Foundation for Basic Research (No. 07-08-00405a).     

基于受激发光实验的生物光尾流特性

 基于生物受激发光与流场机械刺激间的相关性,构建了库埃特流场刺激下的生物受激发光实验平台,分析了影响生物发光的水动力因素剪应力。实验结果显示：引起多边膝沟藻受激发光的剪应力阈值为0.1 N/m²;当流场中的剪应力大于发光阈值后,生物发光强度随着剪应力的增大而增强。采用FLUENT软件模拟计算了不同航速下某潜艇尾流场中的剪应力,计算结果表明：剪应力随着尾流长度的增加而减小,在近场区域剪应力出现了类似正弦波振荡的减小,且航速越大减幅越大,减速越快;当潜艇航速大于4.1 m/s航行时, 2 000 m处尾流的剪应力仍然大于引起生物发光的剪应力阈值。     

Wall shear stress from single almost spherical and long Taylor bubbles in laminar upward tube flow

An experimental electrodiffusional technique with eight double probes is used to detect perturbation of the wall shear stress by a single bubble in laminar upward tube flow. Small almost spherical and long Taylor bubbles are tested. The wall shear stress perturbations by bubbles have a complex structure. It is possible to define three components of perturbation caused by a small bubble. The perturbation by Taylor bubble contains only two components due to the main flow symmetry around the bubble. An unexpectedly long shear stress pulsations zone is registered behind the Taylor bubbles.     

High Pressure High Temperature Dynamic Rheometry of Sulfonated Polyacrylamide Solutions in Electrolyte Media as Used for Oil Recovery Applications

Sulfonated polyacrylamide (SPAA) solutions were prepared and the effects of pressure, polymer concentration, and water temperature, pH and salinity on their rheological behavior were investigated using a concentric cylinder dynamic rheometer equipped with a high pressure cell. According to the rheological flow curves the shear stress of SPAA solutions increased less than in proportion to their shear rates; that is, a shear thinning effect occurred. For polymer solutions containing 15,000 ppm of SPAA, shear viscosity, and stress were nearly insensitive to pressure. However, the shear viscosity and stress of SPAA solutions were affected by temperature and this effect was more evident at lower pressure. The flow curves indicated the shear viscosity and stress of the samples increased with increasing SPAA concentration and pH of the water, but were decreased with increasing water salinity and temperature.     

Heat transfer and shear stress in a gas-liquid flow in an inclined flat channel

Results of experimental investigation of a bubbly gas-liquid flow in an inclined flat channel are presented. Themeasurements were carried out in the range of superficial liquid velocities of 0.3–1.1 m/s and with different values of the volumetric gas flow rate ratio. The hydrodynamic structure wasmeasured bymeans of an electrochemical method using miniature shear stress probes. Values of average shear stress and heat transfer coefficient for different orientation of the channel were found. It is shown that in a bubbly gas-liquid flow the shear stress and heat transfer depend substantially on the channel inclination angle.     

Local characteristics of the upward bubbly flow in an annular channel

Results of experimental investigation of the bubbly gas-liquid flow in a vertical annular channel are presented. The average and pulsation shear stresses and distributions of local void fraction were measured by the electrochemical method on both channel walls. It is shown that with a rise of gas flow rate ratio the value of wall shear stress increases significantly, and this effect becomes higher at a decrease in superficial liquid velocity. A presence of the gas phase effects significantly shear stress on the inner wall. Relative intensity of shear stress pulsations increases similarly on both channel walls.     

金属熔体近壁面流动剪切模型及其对金属凝固影响的理论研究

本文建立了金属熔体近壁面流动剪切模型, 并分析了流动剪切对金属凝固的影响. 针对A356合金计算结果表明:层流流动的熔体内部剪应力随垂直斜板表面距离的增大而减小, 随着流动长度的增加先急剧下降之后趋于稳定; 紊流流动的熔体所受的剪应力随着垂直倾斜板表面距离的增大先急剧下降之后趋于稳定, 随着流动长度的增加而不断增大; 斜板倾角越大, 斜板上相同位置的熔体层受到的剪应力越大; 熔体垂直斜板表面距离越小, 柱状晶所承受的弯曲应力越大; 斜角越大, 斜板上相同位置的柱状晶的弯曲应力越大; 随着熔体在倾斜板表面流动长度的增加, 在层流阶段, 倾斜板表面柱状晶根部所受的弯曲应力先急剧下降之后趋于平稳, 而在紊流阶段, 弯曲应力是缓慢增加的; 理论分析表明柱状晶在熔体近壁面流动过程受到的最大弯曲应力低于αup -Al晶粒的屈服强度, 所以斜板上熔体流动产生的弯曲力不能将柱状晶折断, 只能将晶粒冲刷游离到熔体中使晶粒增殖, 与实验结果相符合. 所以本模型可以很好地解释熔体近壁面流动过程中的剪切本构关系以及剪应力对凝固组织的影响.     

Surface roughness effects on the turbulence statistics in a low Reynolds number channel flow

A high-resolution particle image velocimetry was used to characterize a low Reynolds number turbulent flow in a channel. Experiments were conducted over a sand grain-coated surface of large relative roughness, and the results were compared with measurements over a smooth surface. The roughness perturbation significantly modified the outer layer. Even though the streamwise Reynolds stress shows less sensitivity in the outer layer to the boundary condition, significant enhancements were observed in the wall-normal Reynolds stress and the Reynolds shear stress. These modifications were considered as footprints of the larger-scale eddies transporting intense wall-normal motions away from the rough wall. A quadrant decomposition shows that strong and more frequent ejections are responsible for the larger values of the mean Reynolds shear stress over the rough wall. The results also indicate that spanwise vortex cores with mean vorticity of the same sign as the mean shear are the dominant smaller-scale vortical structures over the smooth and rough walls. A linear stochastic estimation-based analysis shows that the average larger-scale structure associated with these vortices is a shear layer that strongly connects the outer layer flow to the near-wall flow. A proper orthogonal decomposition of the flow suggests that the large-scale eddy is more energetic for the rough wall, and contributes more significantly to the resolved turbulent kinetic energy and the Reynolds shear stress than the smooth wall.     

Extended Lattice Boltzmann Model

Conventional lattice Boltzmann models for the simulation of fluid dynamics are restricted by an error in the stress tensor that is negligible only for small flow velocity and at a singular value of the temperature. To that end, we propose a unified formulation that restores Galilean invariance and the isotropy of the stress tensor by introducing an extended equilibrium. This modification extends lattice Boltzmann models to simulations with higher values of the flow velocity and can be used at temperatures that are higher than the lattice reference temperature, which enhances computational efficiency by decreasing the number of required time steps. Furthermore, the extended model also remains valid for stretched lattices, which are useful when flow gradients are predominant in one direction. The model is validated by simulations of two- and three-dimensional benchmark problems, including the double shear layer flow, the decay of homogeneous isotropic turbulence, the laminar boundary layer over a flat plate and the turbulent channel flow.