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Three semicarbazonyl ligands were synthesized and used to form six novel organometallic complexes with Ph2SnCl2 and Cp2ZrCl2. All these complexes were characterized by IR,1H NMR,MS and elemental analysis. 相似文献
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《Journal of Coordination Chemistry》2012,65(16):1835-1846
The crystal structures of [Mn(bpa)2](ClO4)2 (1), [bpa?=?bis(2-pyridylmethyl)amine], and Mn(6-Mebpa)2(ClO4)2 (2), [6-Mebpa?=?(6-methyl-2-pyridylmethyl)(2-pyridylmethyl)amine] have been determined. In 1, two facial [Mn(bpa)2]2+ isomers are observed in the same unit cell, one with C i (1a) and the other with C2 (1b) symmetries. In 2, only the isomer with C2 symmetry is observed. The structure of [Mn(bpa)2]2+ with only C2 symmetry has been reported previously (Inorg. Chem., 31, 4611 (1992)). The bond length order Mn–Namine?>?Mn–Npyridyl, observed in the C2 and the C i isomers in the crystals of 1, is the reverse of the order observed in the structure of [Mn(bpa)2](ClO4)2 which contains only the C2 isomer in the unit cell. The structure of 2 in which only the C2 isomer is found, also shows the bond length order Mn–Npyridyl?>?Mn–Namine. In cyclic voltammetric experiments in acetonitrile solutions, 1 and 2 show irreversible anodic peaks at E p?=?1.60 and 1.90?V respectively, (vs. Ag/AgCl), assigned to the oxidation of Mn(II) to Mn(III). The substantially higher oxidation potential of 2 is attributable to a higher rearrangement energy in complex 2 due to the steric effect of the methyl substituent. 相似文献
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Bis(diphenylphosphano)alkane- and 1-Diphenylphosphano-2-(2-pyridino)ethane-N-arylsulfinylamine Nickel(0) Complexes Synthesis and properties of the bis(diphenylphosphano)alkane-N-phenyl-sulfinylamine-nickel(0) complexes [Ni{Ph2P(CH2)nPPh2}(PhNSO)] (n = 2 dppe, n = 3 dppp, n = 4 dppb) as well as of the 1-(diphenylphosphano)-2-(2-pyridino)ethane nickel(0) complexes [Ni(dpppe)2], [Ni(dpppe)(p-TolNSO)] and [Ni(dpppe)(PPh3)2] are described. These compounds have been characterized by i. r. and 31P n.m.r. spectroscopy. The N-arylsulfinylamine ligands are η2-(N, S)-side on coordinated. 相似文献
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以2,6,6-三甲基环己-2-烯-1,4-二酮为原料, 经选择性羰基保护、Wittig反应、脱保护基、 腈基水解和还原等5步反应合成了目标化合物, 总产率可达6.0%. 相似文献
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The nucleophile [ArTe−] generated in situ borohydride solution of Ar2Te2, reacts with 2-(chloromethyl) tetrahydrofuran and 2-(2-bromoethyl)-1,3-dioxolane resulting in L1 and L2, respectively. The complexes of palladium(II) and platinum(II) with L1/L2 having stoichiometries [MCl2·L2], [ML2](ClO4)2, [(DPPE)ML2](ClO)4)2, [(PPh3)2ML2](ClO4)2 and [(phen)ML2](ClO4)2 (where L = L1/L2 DPPE = Ph2PC H2CH2PPh2, PHEN = 1,10-phenanthroline and M = Pd/Pt) have been synthesized. IR, 1H, 125Te{1H} and 31P{1H} NMR and UV-vis spectral data of these species in conjunction with their molar conductance and molecular weight data have been used to authenticate the new species. In all complexes (1–20) the ligands L1 and L2 are coordinated through tellurium and in the complexes of formula [ML2](ClO4)2 (M = Pd, Pt) the ligand is bidentate with the oxygen atom used in complexation. In solution, complexes PtCl2L2 exist as a mixture of cis and trans isomers whereas only the trans isomer was observed for the palladium analogues. The [(phen)PdL2](ClO4)2(Q) quenches 1O2 readily. The plot of log [Q] vs time is linear. Mechanism compatible with the experimental observations is proposed. 相似文献
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1INTRODUCTIONTheSchiffbasesderivedfromb-diketonesandaliphaticamineshavebeenshowntoexistastheketo-amines.However,ifsubstituentseitherattheketooraminogrouparearomatic,itmaybeexpectedtheenoliminewillbethefavoredtautomericform[1].Recently,someSchiffbasesderivedfromTTA(4,4,4-trifluoro-1-(2-thienyl)-1,3-butanedione)andPMBPhavebeenstudiedbyWang[2]andYu[3]etal.Inordertostudytherelationshipbetweenthestructuresandperformancesofthesecompounds,thetitlecom-poundwillbereportedherein.2EXPERIMENT… 相似文献
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《Journal of Coordination Chemistry》2012,65(1):13-24
Abstract The ligand 2-(2-pyridyl)benzothiazole (L) can act both as an N-N and an N-S chelating donor. The latter coordination mode is expected to be preferred when it is involved in coordination to Ru(II) which is a soft acceptor centre However, in the title compound, chlorobis(acetonitrile)triphenylphosphino-2-(2-pyridyl)benzothiazole-N,N-ruthenium(II) chlride, [Ru(L)(PPh3(CH3CN)2Cl]Cl, the ligand acts in N,N-bidentate manner and the Ru(II) ion is found to be present in an N4PCl coordination environment. PPh3 and Cl are trans to each other and the two CH3CN ligands occupy cis positions facing the NN donor atoms of ligand L. 相似文献
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Ali Kakanejadifard Toraj Hayati Azam Rezayat 《Phosphorus, sulfur, and silicon and the related elements》2013,188(7):1511-1515
A series of Schiff bases containing four to six coordination sites N2S2 X2(X = O,N) 2-(2-(2-(aryl)methyleneamino)phenylthio)ethylthio)-N-((aryl)methylene)benzeneamine (2c–f) were prepared from the reaction of 1,2-di(2-aminophenylthio)ethane (1) with aromatic aldehydes. All compounds were characterized by means IR, mass, 1H and 13C NMR spectroscopy, and elemental analysis, and in the case of 2b with a single crystal X-ray diffraction. The X-ray crystal structure of 2b showed that the resonance occurs between aromatic rings, through the C=N bonds of the molecule. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file. 相似文献
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2-(2-喹啉偶氮)-1,5-苯二酚光度法测定钢铁样品中镍 总被引:11,自引:0,他引:11
合成了新试剂 2 (2 喹啉偶氮 ) 1,5 苯二酚 (QADHB) ,并研究了其与镍的显色反应 ,在pH 9.0的氯化铵 氨水缓冲介质中 ,CTMAB存在下 ,QADHB与镍反应生成 2∶1稳定络合物 ,λmax为 5 90nm ,ε为 1.0 5× 10 5L·mol- 1·cm- 1。镍含量在 0~ 10 μg/ 2 5ml内符合比耳定律 ,方法用于钢铁样品中镍含量的测定 ,结果满意。 相似文献
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The free-radical copolymerization of two N-substituted acrylamide monomers, the ionic AMPS (2-acrylamido-2-methyl-1-propanesulfonic acid) and the non-ionic HEAm (2-hydroxyethylacrylamide) is presented. Despite bearing similar polymerizable functionalities, HEAm is more reactive toward free-radical addition than AMPS in water. In a mixed aqueous solvent containing salt, (0.5 M LiNO3, 50 wt%) and ethanol (50 wt%), the reactivity ratio was found to be rAMPS = 0.53 and rHEAm = 1.06 indicating that copolymers with a nearly random distribution of sulfonic and hydroxy functionalities can be prepared. 相似文献
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Yongshu Xie Xiaoyu Wang Min Zhang Kaiju Wei Qingliang Liu Shieming Peng 《应用有机金属化学》2005,19(1):175-175
The zinc(II) atom in the complex cation of [Zn(tpda)2][ZnBr4]·H2O is octahedrally coordinated, whereas the zinc(II) atom in the anion is tetrahedrally coordinated. The cations and the anions are connected by hydrogen bonds, affording a two‐dimensional network. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
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The title complex [CoIII(2, 2?-bpy)2(N3)2]@NO3@2H2O was obtained by an auto-oxidization reaction of cobalt nitrate with 2, 2?-bpy and sodium azide in aqueous solution at room temperature, and violet single crystals were prepared in ethanol solution. The structure was determined by X-ray crystallography. The crystal is of triclinic, space group P ī with a = 8.285(4), b = 11.990(8), c = 12.596(7) ?, ( = 86.630(3), ( = 86.280(5), ( = 71.130(10)°, C20H20CoN11O5, Mr = 553.40, Z = 2, V = 1180.6(12) ?3, F(000) = 568, Dc = 1.557 g/cm3, ( = 0.784 mm-1, R = 0.0403 and wR = 0.1008. The title complex consists of a [CoⅢ(2, 2?-bpy)2(N3)2]+ cation, a NO3- anion and two lattice water molecules. The center CoⅢ ion coordinated by two chelating 2, 2?-bpy ligands and two terminal azide groups with a CoN6 coordination environment exhibits a distorted octahedral geometry. 相似文献
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《Analytical letters》2012,45(9):1675-1684
Abstract The reaction between lead(II) and 2-(2-Thiazolylazo)-p-Cresol(TAC) in the presence of TERGITOL NPX (4 mg/ml) at an apparent pH 9.0–10.0 results in an intensely colored complex which is stable for at least 4 hr. The composition of the complex is 1:2 cation: TAC and the log of the formation constant is 11.92 ± 0. 40. Beer's law is obeyed up to 6.0μg.ml?1 of lead(II) at 650nm. The apparent molar absorptivity at 650 nm is 2.07 × 104 1. mole?1.cm?1 and the detection limit was obtained as 10.0 ng.ml?1 of lead(II). The method is applied to determination of lead(II) in copper-base alloy. 相似文献
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配合物Cu(phen)2 (dca)2的合成及晶体结构 总被引:7,自引:0,他引:7
合成了配合物Cu(phen)2 (dca)2(phen=C12H8N2为1,10-邻菲啰啉,dca-为二氰基氨基阴离子),用IR对其结构进行了初步表征,并测定了配合物的晶体结构.该晶体属单斜晶系,空间群为P21/c;晶胞参数a=0.8869(2)nm,b=1.4691(2)nm,c=1.9298(2)nm,β=100.90(1)°;V=2.4691(8)nm3,Z=4,F(000)=1132.00,Dc=1.496g/cm3,R=0.051,RW=0.068.中心铜(Ⅱ)离子分别与两个phen中的四个N原子和两个dca-的两个N原子配位,形成六配位的变形八面体结构. 相似文献
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以Mg(NTf2)2为催化剂,在室温由2-氨基芳基酮和α-亚甲基酮通过Friedl(a)nder缩合反应合成了喹啉衍生物.该法操作简便,反应条件温和,产率高,反应时间短. 相似文献
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用一维NMR方法研究了新型电化学发光探针Ru(dcbpy)(phen)2(PF6)2的立体结构,借助二维^1H-^1H COSY和^1H-^13C COSY实验对其氢谱和碳谱进行了完全的归属,并给出了其氢谱和碳谱的化学位移值。 相似文献