What is 'unfreezable water', how unfreezable is it,and how much is there?

Water that remains unfrozen at temperatures below the equilibrium bulk freezing temperature, in the presence of ice, is sometimes called unfreezable or bound. This paper analyses the phenomenon in terms of quantitative measurements of the hydration interaction among membranes or macromolecules at freezing temperatures. These results are related to analogous measurements in which osmotic stress or mechanical compression is used to equilibrate water of hydration with a bulk phase. The analysis provides formulas to estimate, at a given sub-freezing temperature, the amount of unfrozen water due to equilibrium hydration effects. Even at tens of degrees below freezing, this hydration effect alone can explain an unfrozen water volume that considerably exceeds that of a single 'hydration shell' surrounding the hydrophilic surfaces. The formulas provided give a lower bound to the amount of unfrozen water for two reasons. First, the well-known freezing point depression due to small solutes is, to zeroth order, independent of the membrane or macromolecular hydration effect. Further, the unfrozen solution found between membranes or macromolecules at freezing temperatures has high viscosity and small dimensions. This means that dehydration of such systems, especially at freezing temperatures, takes so long that equilibrium is rarely achieved over normal experimental time scales. So, in many cases, the amount of unfrozen water exceeds that expected at equilibrium, which in turn usually exceeds that calculated for a single hydration shell.     

Where is an object before you look at it?

According to the standard interpretation of quantum mechanics (QM), no meaning can be assigned to the statement that a particle has a precise value of any one of the variables describing its physical propertes before having interacted with a suitable measuring instrument. On the other hand, it is well known that QM tends to classical statistical mechanics (CSM) when a suitable classical limit is performed. One may ask therefore how is it that in this limit, the statement, meaningless in QM, that a given variable has always a precise value independently of having been measured, gradually becomes meaningful. In other words, one may ask how can it be that QM, which is a theory describing the intrinsically probabilistic properties of a quantum object, becomes a statistical theory describing a probabilistic knowledge of intrinsically well determined properties of classical objects.In the present paper we try to answer to this question and show that an inconsistency arises between the conventional interpretation of CSM which presupposes objectively existing Newtonian trajectories, and the standard interpretation of QM. We conclude that the latter needs revisiting unnless we wish to adopt a strictly subjective conception of the world around us, implying that macroscopic objects as well are not localized anywhere before we look at them.     

Entanglement Sudden Death in Quantum Optics： What is it and why does it happen？

It is well known in quantum optics that fluctuations and dissipation inevitably intervene in the dynamics of open quantum systems. Density matrix elements may all decay exponentially and smoothly but we show that two-party entanglement, a valuable quantum coherence, may nevertheless abruptly decrease to zero in a finite time. This is Entanglement Sudden Death. In this talk we show how entanglement sudden death occurs under either phase or amplitude noise, either quantum or classical in origin. Moreover, we show that when two or more noises are active at the same time, the effects of the combined noises is even more unexpected.     

The Higgs boson: shall we see it soon or is it still far away?

The status of the Higgs boson mass in the Standard Model and its supersymmetric extensions is reviewed and the perspectives of Higgs searches are discussed. The parameter space of the Minimal Supersymmetric Standard Model (MSSM) is analysed with the emphasis on the lightest Higgs mass. The infrared behaviour of renormalization group equations for the parameters of MSSM is examined and infrared quasi-fixed points are used for the Higgs mass predictions. They strongly suggest the Higgs mass to be lighter than 100 or 130 GeV for low and high tan β scenarios, respectively. Extended models, however, allow one to increase these limits for low tan β up to 50%.     

Surface pressure in clusters and small particles—is it real?

Using the methods of statistical mechanics and applying the conditions of thermal equilibrium for an ensemble of interacting molecules, it is proved that there is no excess pressure, nor internal and surface stresses, in clusters and small particles that are not subjected to the action of external forces. With this premise taken into account the thermodynamics of spherical and faceted small particles is developed. In a particle-vapour system surrounded by a rigid impervious shell, Kelvin's and Thomson's formulae and Wulff's rule are derived. For a particle-melt system at a constant external pressure it is expected that the melting points of a particle and a bulk solid should be equal. It is noted that, if a particle is not subjected to the action of external fields or bodies, its molecules occupy their natural equilibrium positions, and it is from them that deformations and internal stresses should be counted off. These equilibrium positions differ from those occupied by the same molecules in a bulk solid, which is what usually gives rise to the illusions of the stressed state of a small particle and its deformation caused by the “uncompensated” surface forces.     

Identification and discrimination of rise time: is it categorical or noncategorical?

Previous studies have reported that rise time of sawtooth waveforms may be discriminated in either a categorical-like manner under some experimental conditions or according to Weber's law under other conditions. In the present experiments, rise time discrimination was examined with two experimental procedures: the traditional labeling and ABX tasks used in speech perception studies and an adaptive tracking procedure used in psychophysical studies. Rise time varied from 0 to 80 ms in 10-ms intervals for sawtooth signals of 1-s duration. Discrimination functions for subjects who simply discriminated the signals on any basis whatsoever as well as functions for subjects who practiced labeling the endpoint stimuli as " pluck " and "bow" before ABX discrimination were not categorical in the ABX task. In the adaptive tracking procedure, the Weber fraction obtained from the jnds of rise time was found to be a constant above 20-ms rise time. The results from the two discrimination paradigms were then compared by predicting a jnd for rise time from the ABX discrimination data by reference to the underlying psychometric function. Using this method of analysis, discrimination results from previous studies were shown to be quite similar to the discrimination results observed in this study. Taken together the results demonstrate clearly that rise time discrimination of sawtooth signals follows predictions derived from Weber's law.     

The problem of pseudoreplication in neuroscientific studies: is it affecting your analysis?

Background  

Pseudoreplication occurs when observations are not statistically independent, but treated as if they are. This can occur when there are multiple observations on the same subjects, when samples are nested or hierarchically organised, or when measurements are correlated in time or space. Analysis of such data without taking these dependencies into account can lead to meaningless results, and examples can easily be found in the neuroscience literature.     

Band splitting for Si(557)-Au: is it spin-charge separation?

It has been proposed that the Si(557)-Au surface exhibits spin-charge separation in a one-dimensional electron liquid. Two narrowly spaced bands are found which exhibit a well-defined splitting at the Fermi level. That is incompatible with the assignment to a spinon-holon pair in a Luttinger liquid. Instead, we propose that the two bands are associated with two nearly degenerate atomic chains, or a chain of step atoms with two broken bonds. Such an assignment explains why the surface is metallic despite an even number of electrons per unit cell.     

What is modified gravity and how to differentiate it from particle dark matter?

An obvious criterion to classify theories of modified gravity is to identify their gravitational degrees of freedom and their coupling to the metric and the matter sector. Using this simple idea, we show that any theory which depends on the curvature invariants is equivalent to general relativity in the presence of new fields that are gravitationally coupled to the energy-momentum tensor. We show that they can be shifted into a new energy-momentum tensor. There is no a priori reason to identify these new fields as gravitational degrees of freedom or matter fields. This leads to an equivalence between dark matter particles gravitationally coupled to the standard model fields and modified gravity theories designed to account for the dark matter phenomenon. Due to this ambiguity, it is impossible to differentiate experimentally between these theories and any attempt of doing so should be classified as a mere interpretation of the same phenomenon.     

Simultaneous EEG-fMRI acquisition: how far is it from being a standardized technique?

Simultaneous EEG–fMRI is a powerful tool to study spontaneous and evoked brain activity because of the complementary advantages of the two techniques in terms of temporal and spatial resolution. In recent years, a significant number of scientific works have been published on this subject. However, many technical problems related to the intrinsic incompatibility of EEG and MRI methods are still not fully solved. Furthermore, simultaneous acquisition of EEG and event-related fMRI requires precise synchronization of all devices involved in the experimental setup. Thus, timing issue must be carefully considered in order to avoid significant methodological errors.

The aim of the present work is to highlight and discuss some of technical and methodological open issues associated with the combined use of EEG and fMRI. These issues are presented in the context of preliminary data regarding simultaneous acquisition of event-related evoked potentials and BOLD images during a visual odd-ball paradigm.     

The “Peierls stress” for pure metals (evidence that it is negligible)

It is argued that the “Peierls stress” for dislocations in pure metal crystals is negligible. The resistance to dislocation motion is not quasistatic but viscous. Direct observations of the viscous behaviour are cited and internal friction measurements are mentioned. The measured viscosity coefficients are very small (less than?mPa?s). It is pointed out that the yield points of pure metals are not associated with Peierls stresses but with the interaction of the stress dependences of dislocation velocities and the kinetics of dislocation multiplication. The negligible values of the stresses needed to move dislocations are rationalized in terms of the small dependence of the cohesive energies of simple metals on their atomic patterns.     

If "discrete breathers" is the answer,what is the question?

Intense work on discrete breathers or intrinsic localized modes in recent years has revealed a wealth of new properties of classical energy localization. Relaxation and mobility in particular may be two of the critical links with biomolecular processes. We review some of the basic discrete breather properties that we think are pertinent to biomolecules and make conjectures as to their possible biological utility.     

Anomalous fluoride concentration in groundwater—is it natural or pollution? A stable isotope approach

Fluoride anomalies (up to 11 mg/l) have been detected in groundwater of the central region of Rio Grande do Sul State, Southern Brazil, in an area where fluorosis is endemic. Two hypotheses are investigated concerning the fluoride origin: lithochemical affiliation from regional rock or contamination by fertilisers application. These hypotheses are discussed based on the stable isotope data of water, nitrate, and sulphate, which indicates that the local precipitation is the main groundwater recharge source. The isotopic composition of groundwater sulphate is similar to that of fertiliser sulphate. However, a conclusive assignment of groundwater sulphate to fertiliser origin is not indicated because further possible sulphate sources fall into the same isotopic range. In contrast, the isotopic composition of dissolved nitrate suggests that there is no direct relationship to the use of NPK fertilisers. Hence, an origin of the high fluoride content in groundwater related to long-term rock–water interactions seems likely.     

Anomalous fluoride concentration in groundwater - is it natural or pollution? A stable isotope approach

Fluoride anomalies (up to 11 mg/l) have been detected in groundwater of the central region of Rio Grande do Sul State, Southern Brazil, in an area where fluorosis is endemic. Two hypotheses are investigated concerning the fluoride origin: lithochemical affiliation from regional rock or contamination by fertilisers application. These hypotheses are discussed based on the stable isotope data of water, nitrate, and sulphate, which indicates that the local precipitation is the main groundwater recharge source. The isotopic composition of groundwater sulphate is similar to that of fertiliser sulphate. However, a conclusive assignment of groundwater sulphate to fertiliser origin is not indicated because further possible sulphate sources fall into the same isotopic range. In contrast, the isotopic composition of dissolved nitrate suggests that there is no direct relationship to the use of NPK fertilisers. Hence, an origin of the high fluoride content in groundwater related to long-term rock-water interactions seems likely.     

Renal diffusion tensor imaging: is it possible to define the tubular pathway? A case report

The authors report a case of unilateral xanthogranulomatous pyelonephritis, associated with chronic lithiasis studied by standard clinical magnetic resonance imaging protocol and diffusion tensor imaging (DTI). Maps of apparent diffusion coefficient (ADC) and fractional anisotropy (FA) and tractography were reconstructed on both healthy and pathologic kidney. ADC and FA values are in agreement with the literature. Tractography reconstruction of tubular renal architecture was confirmed by histology. This result suggests the potential ability of DTI to detect structural alterations in the architecture of the kidney, as noninvasive tool, preceding the onset of clinical-laboratory alterations.     

From where do quantum groups come?

The phase space realizations of quantum groups are discussed using *-products. We show that on phase space, quantum groups appear necessarily as two-parameter deformation structures, one parameter (v) being concerned with the quantization in phase space, the other () expressing the quantum groups as deformation of their Lie counterparts. Introducing a strong invariance condition, we show the uniqueness of the -deformation. This suggests that the strong invariance condition is a possible origin of the quantum groups.Dedicated to Asim Barut with all our friendship.     

Photons can hide where they have been

Recently,the nested Mach–Zehnder interferometer[Phys.Rev.Lett.111,240402(2013)]was modified by adding Dove prisms in a paper[Quantum Stud.:Math.Found.2,255(2015)],and an interesting result is that,after the Dove prisms were inserted,a signal at the first mirror of the nested interferometer was obtained.But,according to the former original paper,the photons have never been present near that mirror.In this work,we interpret this result naturally by resorting to the three-path interference method.Moreover,we find that even though the photons have been somewhere,they can hide the trace of being there.