EPR spectroscopy of weak exchange interactions between Co2+ ions in ZnO

Electron paramagnetic resonance (EPR) is used to identify the next nearest neighbour Co²⁺ pairs coupled by spin–spin interaction in Co‐doped ZnO single crystals grown by the hydrothermal technique. These dimer centers are described by a spin Hamiltonian with exchange coupling terms written as interaction between identical effective spins S^eff = 1/2 of the lowest ground state Kramers doublets of the two Co²⁺ ions. The exchange parameters of weakly ferromagnetically coupled next nearest neighbor Co²⁺ pairs are estimated. (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Probing the paramagnetic interactions between the unpaired electronic spins of carbon atoms and the nuclear spins of hydrogen molecules with Raman spectroscopy

Carbon materials typically have a high density of unpaired electronic spins but the exact nature of the defect sites that give rise to their magnetic properties are not yet well understood. In this work, the paramagnetic interactions between the unpaired electronic spins of carbon atoms and the nuclear spins of hydrogen molecules were probed with Raman spectroscopy by monitoring the relative population of H₂ rotational states. For H₂, the symmetries of nuclear spin and rotational wave functions are correlated. Because of the weak interactions between H₂ nuclear spins, the transitions between odd and even rotational states are normally hindered. The magnetic field generated by unpaired electronic spins relaxes the selection rules and promotes transitions between H₂ rotational levels of different symmetry. This affects the rotational levels' relaxation kinetics toward equilibrium and makes H₂ molecules useful to study unpaired electrons in paramagnetic materials. It is suggested that simultaneous electron paramagnetic resonance and Raman measurements on carbon materials interacting with hydrogen molecules could result in a better understanding of the nature of paramagnetic defects in carbon materials, which could have a substantial impact on Li‐ion batteries or for understanding the graphene electronic properties. Copyright © 2011 John Wiley & Sons, Ltd.     

Modulations of exchange coupling in oxoferrylporphyrin cation radical complexes detected by Mössbauer and EPR measurements

Oxoferrylporphyrin cation radical complexes were generated using the prophyrin dianions: tetrakis 2,6-dichlorophenyl (TDCPP) and tetrakis 2,4,6-trimethoxyphenyl (TTMPP). Spin coupling between ferryl iron (S=1) and porphyrin radical S′=1/2), ligand field interaction and hyperfine parameters of iron were studied by Mössbauer and EPR measurements and corresponding spin Hamiltonian analyses. Samples of [Fe^IV=0 TDCPP], which had to be prepared in CH₂Cl₂, were “vacuum dried” in order to obtain Mössbauer spectra.     

Li-defect interactions in electron-irradiated n-type silicon by EPR measurements

Single crystal silicon, both with and without oxygen, has been diffused with lithium to concentrations ～10¹⁷/cm², irradiated with 1 to 1.5 MeV electrons, and the ensuing defects studies by EPR measurements. The presence of oxygen strongly affects the properties of these defects. Measurements have indicated the presence of two new defects which involve Li-one in O-containing material and one in O-free material. The defects are observed in their electron-filled state, and indicate a net electron spinof ½. The defect spectra disappear (with time) at room temperature, and can be explained by the formation of other Li-involved defects which lie deeper in the energy bandgap and are not visible by EPR. Electron irradiation at 40 °K followed by annealing at higher temperatures show that both EPR defects described above begin to form at about 200 °K and begin to decrease at about 275 °K-just as does the 250 °K reverse annealing observed generally for n-type Si. Based on these data, and the work of others, it is suggested that both defects form as a result of the motion of Si interstitials which produce a (Li-O-interstitial) complex in O-containing Si, and a (Li-interstitial) complex in O-free Si.     

A weak coupling model for high-spin states

Weak coupling of a rotating core and an odd particle is used to explain the appearance of pure rotational bands, as well as decoupled aligned state bands by simple geometrical properties.     

A confining model of the weak interactions

The weak interactions are analyzed as the low-energy effective interactions of a strong coupling gauge theory whose scale is $\text{G}{}_{\mathrm{<mtext>F</mtext>}}{}^{\mathrm{<mtext>?</mtext><mtext>1</mtext><mtext>2</mtext>}}$. The light fermions are shown to be bound states obeying 't Hooft's consistency conditions. The symmetries of the theory are used to analyzed the low-energy interactions. Instanton mediated baryon violations are discussed and experimental signatures at high energy are presented.     

Nonperturbative field-theoretical model of leptonic weak interactions

Acta physica Academiae Scientiarum Hungaricae - In this work the problem of the four-leptonic weak processes is studied in the theory with an intermediate vectorW-meson. Neglecting 1.m lept., 2....     

On Heisenberg exchange of high spins

The well-known Kaplan-Alexander equations for chemical exchange are generalized to include Heisenberg exchange of high spins (S > 1/2). General expressions are obtained for the effect of the exchange on the shape and width of lines and on the population of spin eigenstates. The broadening action of an arbitrary spin on a spin of 1/2 is taken as an example.     

Six-quark model of weak and electromagnetic hadron interactions

The consequences of a six-quark model of weak and electromagnetic hadron interactions are considered for highly inelastic lepton- hadron scattering.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 20–24, May, 1977.I wish to thank V. A. Kuz'min, A. N. Tavkhelidze, and K. G. Chetyrkin for useful discussions.     

Limit on right handed weak coupling parameters from inelastic neutrino interactions

Right handed weak quark currents coupled to the usual left handed weak lepton current would be seen in inclusive antineutrino scattering on nuclei as a contribution at largey with the quark (not antiquark) structure function. We do not see such a term, and can therefore put an upper limit on the relative strengths of such right handed currents: \(\varrho ^2 = \frac{{\sigma _R }}{{\sigma _L }}< 0.009\) , 90% confidence. This measurement puts limits on the mixing angle of left-right symmetric models. In distinction to similar limits derived from muon decay or β decay, our limits are also valid if the right handed neutrino is heavy.     

Concentration by centrifugation for gas exchange EPR oximetry measurements with loop-gap resonators

Measurement of the bimolecular collision rate between a spin label and oxygen is conveniently carried out using a gas permeable plastic sample tube of small diameter that fits a loop-gap resonator. It is often desirable to concentrate the sample by centrifugation in order to improve the signal-to-noise ratio (SNR), but the deformable nature of small plastic sample tubes presents technical problems. Solutions to these problems are described. Two geometries were considered: (i) a methylpentene polymer, TPX, from Mitsui Chemicals, at X-band and (ii) Teflon tubing with 0.075 mm wall thickness at Q-band. Sample holders were fabricated from Delrin that fit the Eppendorf microcentrifuge tubes and support the sample capillaries. For TPX, pressure of the sealant at the end of the sample tube against the Delrin sample holder provided an adequate seal. For Teflon, the holder permitted introduction of water around the tube in order to equalize pressures across the sealant during centrifugation. Typically, the SNR was improved by a factor of five to eight. Oxygen accessibility applications in site-directed spin labeling studies are discussed.     

Unique solution for the weak neutral current coupling constants in purely leptonic interactions

By combining results from the MARK-J at PETRA on Bhabha scattering, μ⁺μ^- and τ⁺τ^- production with recent world data from neutrino-electron scattering experiments, we determine unique values for the leptonic weak neutral current coupling constants g_V and g_A in the framework of electroweak models containing a single Z⁰. In contrast to previous analyses, we only use data from purely leptonic interactions, and therefore avoid the inherent uncertainties resulting from the use of hadronic targets. From the MARK-J data alone in the context of the standard SU(2) ? U (1) model of Glashow, Weinberg and Salam, we find sin²θ_W=0.24±0.11.     

A model of weak and electromagnetic interactions of nucleons

Using the concept of spontaneous breakdown of the symmetry in the framework of the Yang-Mills-Higgs-Kibble formalism, the unified model of weak and electromagnetic interactions of point nucleons is suggested.     

A supersymmetric left-right confining model of the weak interactions

We extend the supersymmetric, confining theory of weak interactions to a left-right symmetric model. This model is based on the gauge group SU(M)_SC×SU(2)_R×SU(2)_L×SU(3)_c×U(1) and is more natural as far as supersymmetry breaking is concerned. Supersymmetry protects chiral symmetries from spontaneous breakdown and allows a solution to the strong CP problem. This model can accommodate at most three generations of quarks and leptons.     

An interpretation of decoupled bands by the weak coupling model

The band structure and mechanism of formation of odd-A decoupled rotational bands are studied using the weak coupling model of de-Shalit. The geometrical relation between the spin of the core and the particle can be shown explicitly because of the fact that the interaction matrix elements are written in terms of the angle between these two spins. This scheme is shown to be a good representation in describing decoupled bands and to have wave functions with large overlaps with those resulting from the coupling scheme introduced by Stephens.     

Molecular-orbital model of heat-induced effective exchange coupling in magnetic multilayers

Heat-induced effective exchange coupling between two ferromagnets across a semiconductor spacer layer is described by the interaction of localized, weakly bound electron states which are situated at the two interfaces. These states overlap across the spacer layer and form large molecular orbitals. The energies of these orbitals depend on the spin configuration of the electrons and therefore determine the exchange coupling. Thermal repopulation of the levels yields a positive temperature coefficient of the coupling. The results are found to well reproduce the experimental observations.     

EPR studies of photoinduced electron transfer in triad model compounds of photosynthesis

Time-resolved EPR spectra are reported for porphyrin-quinone-quinone and porphyrin-porphyrin-quinone triads obtained after photoexcitation in the nematic and soft glass phase of liquid crystals. Spin-polarized EPR spectra were observed for the triplet states of the porphyrin created by spin-selective intersystem crossing (ISC) from the excited singlet state and those of the charge-separated radical pair states (RP) generated by electron transfer (ET) processes. The EPR polarization patterns of the RP are discussed in terms of the favored decay channel of the photoexcited singlet state of the porphyrin donor. The decay pathway may either be singlet ET to the quinone(s) followed by singlet/triplet mixing to yield RPs with triplet character or triplet ET after ISC from the porphyrin singlet to the triplet state, or a superposition of both pathways. It is demonstrated that the nature of the linking bridge between donor and acceptor, i.e., aliphatic cyclohexylene or aromatic phenylene, significantly influences the ET mechanism and thus the polarization patterns of the RP spectra. Using liquid crystals, information about the orientation of the guest molecules in the liquid crystal matrix with respect to the long axes of the liquid crystal molecules can be obtained. In the porphyrin-porphyrin-quinone triads the energy and ET processes strongly depend on the type of metallation of the porphyrins, specifically, whether the distal, the vicinal or both porphyrins bear a zinc atom.