<Superscript>57</Superscript>Fe NMR study of multiferroic BiFeO<Subscript>3</Subscript>

The effects of the ⁵⁷Fe isotope content and high-frequency magnetic field amplitude h ₁ on the shape of the NMR spectrum of multiferroic BiFeO₃ at T = 4.2 K are studied by pulsed nuclear magnetic resonance. The NMR spectrum shape and transverse relaxation time T ₂ are found to depend strongly on the ⁵⁷Fe isotope content and h ₁ in multiferroic BiFeO₃ in the presence of a spatial spin-modulated structure of a cycloid type. In a sample with a high ⁵⁷Fe isotope content, the Suhl-Nakamura interaction contributes substantially to T ₂. When these dynamic effects are taken into account for analysis of the NMR spectrum shape, an undisturbed (without an anharmonicity effect) spatial spin-modulated structure of a cycloid type is shown to exist in BiFeO₃.     

Inner-shell excited quartet states in Li-like O<Superscript>5+</Superscript> and Ne<Superscript>7+</Superscript> ions

First laser spectroscopic measurements of the 6s5d³D₁-6s6p¹P₁ and 6s5d³D₂-6s6p¹P₁ transitions in several isotopes of atomic barium have been performed. The hyperfine structure of these transitions was optically resolved and isotope shifts for even and odd isotopes were determined. The isotope shifts show a deviation from their expected behavior for odd isotopes in an analysis based on King-plots. This observation puts atomic structure calculations at test because available theories do not predict this. A profound understanding of the wavefunctions for heavy alkaline earth systems like barium (Ba) and radium (Ra) is essential for a theoretical evaluation of their sensitivity to fundamental symmetry breaking effects such as they could be observed, e.g., through permanent electric dipole moments. Further the absolute frequency of the 6s^{2 1}S₀-6s6p³P₁ intercombination line in ¹³⁸Ba was determined to be 12 636.6232(1) cm^-1.     

Description of elastic scattering in the <Superscript>16</Superscript>O + <Superscript>16</Superscript>O and <Superscript>16</Superscript>O + <Superscript>12</Superscript>C systems

The objective of the present study was to describe more precisely experimental data on elastic scattering in the ¹⁶O + ¹⁶O system at E _lab = 124, 145, 250, 350, and 480 MeV and in the ¹⁶O + ¹²C system at E _lab = 132, 170, 181, 200, 230, 260, and 281 MeV. The role of exchange interaction in the region of backward angles is investigated. The coefficient of incompressibility of nuclear matter is estimated at K = 205 MeV ± 15%.     

Asymmetry of hyperfine-structure components of the 5 <Superscript>1</Superscript>S<Subscript>0</Subscript>-5<Superscript>3</Superscript>P<Subscript>1</Subscript><Superscript>113</Superscript>Cd line perturbed by argon

Experimental results of a systematic study of profiles of the hyperfine-structure components of the intercombination 5¹S₀ – 5 ³P₁ line of the even-odd ¹¹³Cd isotope perturbed by argon performed by means of a laser-induced fluorescence method are reported. We have found that the values of total line asymmetries of both hfs line components are different.     

Hyperfine magnetic anomaly in isotopic pairs <Superscript>151, 152</Superscript>Eu and <Superscript>152, 153</Superscript>Eu

High-resolution laser spectroscopy measurements of optical hyperfine splitting on the ^{151, 152, 153}Eu isotopes were performed on the atomic transition 4f ⁷6s ^{2 8} S _7/2 → 4f ⁷6s6p ⁶ P _5/2 at λ ≈ 564.58 nm. Values of the nuclear magnetic dipole and electric quadrupole moments are obtained from the measured hyperfine splitting and the magnetic hyperfine anomalies in the isotope pairs ^{151, 152}Eu and ^{152, 153}Eu are deduced. The absolute values of the hyperfine anomaly in both cases are unusually large: 5 (1)%. The possible sources causing these anomalies are discussed.     

A miniature tunable TEA CO<Subscript>2</Subscript> laser using isotope <Superscript>13</Superscript>C<Superscript>16</Superscript>O<Subscript>2</Subscript> and <Superscript>12</Superscript>C<Superscript>16</Superscript>O<Subscript>2</Subscript>

A miniature tunable TEA CO₂ laser using isotope ¹³C¹⁶O₂ as the active medium is developed to extend the spectral range of CO₂ lasers for further application. The optimization of the energy parameters of the tunable TEA ¹³C¹⁶O₂ laser and the same laser using ¹²C¹⁶O₂ are studied. When a gas mixture (¹³C¹⁶O₂: N₂: He = 1: 1: 3) at a total pressure of 6.4 × 10⁴ Pa is used, the TEA ¹³C¹⁶O₂ laser of a 45-cm³ active volume obtains 51 emission lines in the [00⁰1–10⁰0] and [00⁰1–02⁰0] bands. The maximum pulse energy of the TEA ¹³C¹⁶O₂ laser is about 357 mJ. The same laser using the conventional gas mixture (¹²C¹⁶O₂: N₂: He = 1: 1: 3) at a pressure of 6.66 × 10⁴ Pa is measured to obtain 69 laser emission lines and the maximum pulse energy of laser radiation is about 409 mJ.     

Yields of multiparticle photoneutron reactions on the <Superscript>209</Superscript>Bi isotope

The relative yields of multiparticle photoneutron reactions on the ²⁰⁹Be isotope with emission of two to seven neutrons from the nucleus are measured. The experiment was carried out with the bremsstrahlung beam from the RTM-70 pulsed race-track microtron (INP, MSU) with a maximum photon energy E _γ ^m = 67.7 MeV.     

Red,Yellow, Blue and Green Emission from Eu<Superscript>3+</Superscript>, Dy<Superscript>3+</Superscript> and Bi<Superscript>3+</Superscript> Doped Y<Subscript>2</Subscript>O<Subscript>3</Subscript>nano-Phosphors

Rare earth elements (RE = Eu³⁺& Dy³⁺)and Bi³⁺ doped Y₂O₃ nanoparticles were synthesized by urea hydrolysis method in ethylene glycol, which acts as reaction medium as well as a capping agent, at a low temperature of 140 °C,followed by calcination of the obtained product. Transmission electron microscope (TEM) images reveals that ovoid shaped Y₂O₃ nanoparticles of around 22–24 nm size range were obtained in this method. The respective RE and Bi³⁺ doped Y₂O₃ precursor nanoparticles when heated at 600 and 750 °C, retains the same shape as that of the as-synthesized Y₂O₃ precursor samples. From EDAX spectra, the incorporation of RE ions into the host has been studied. XRD pattern reveals the crystalline nature of the heated nanoparticles and indicate the absence of any impurity phase other than cubic Y₂O₃.However, the as-synthesized nanoparticles were highly amorphous without the presence of any sharp XRD peaks. Photoluminescence study suggests that the synthesized samples could be used as red (Eu³⁺), yellow (Dy³⁺), blue and green (Bi³⁺)emitting phosphors.     

<Superscript>57</Superscript>Fe NMR study of amorphous and rapidly quenched crystalline Fe-B alloys

Amorphous and crystalline Fe-B alloys (5–25 at % B) were studied using pulsed ⁵⁷Fe nuclear magneticr esonance at 4.2 K. The alloy samples were prepared from a mixture of the ⁵⁷Fe and ¹⁰B isotopes by rapid quenching from the melt. In the microcrystalline Fe-(5–12 at %) B alloys, the resonance frequencies were measured for local states of ⁵⁷Fe nuclei in the tetragonal and orthorhombic Fe₃B phases and also in α-Fe. The resonance frequencies characteristic of ⁵⁷Fe nuclei in α-Fe crystallites with substitutional impurity boron atoms in the nearest neighborhood were also revealed. In the resonance frequency distribution P(f) in the amorphous Fe-(18–25) at % B alloys, there are frequencies corresponding to local Fe atom states with short-range order of the tetragonal and orthorhombic Fe₃B phases. As the boron content decreases below 18 at %, the P(f) distributions are shifted to higher frequencies corresponding to ⁵⁷Fe NMR for atoms exhibiting a short-range order of the α-Fe type. The local magnetic structure of the amorphous Fe-B alloys is also considered.     

Multineutron photonuclear reactions on the <Superscript>197</Superscript>Au isotope

An experiment on irradiation of the ¹⁹⁷Au isotope by a beam of bremsstrahlung γ-rays of maximum energy E _γ ^m = 70 MeV has been carried out at the RTM-70 race-track microtron of the INP MSU. Residual activity spectra of the irradiated sample were measured. Multiparticle photonuclear reactions on the ¹⁹⁷Au nucleus are observed. Photonuclear reactions with emission of as many as six neutrons are observed for the first time.     

Leading-order 2πγ exchange NN interaction: Central potentials proportional to g<Subscript>A</Subscript><Superscript>0</Superscript> and g<Subscript>A</Subscript><Superscript>2</Superscript>

We calculate at two-loop order in chiral perturbation theory the electromagnetic corrections to the leading-order 2π exchange NN interaction proportional to g _A ⁰ and g _A ². The resulting 2πγ exchange potential contains isospin-breaking components which reach up to about -2% of the corresponding isovector 2π exchange potential. With a value of only -17keV at r = m _π ^-1 = 1.4fm the charge-independence breaking central potential obtained here is negligibly small in comparison to the one generated by the isoscalar c₃ contact vertex. Our calculation confirms that the largest long-range isospin-violating NN potentials arise from the 2πγ exchange diagrams involving the large low-energy constants c ₄ ≃ - c ₃ ≃ 3.3GeV^-1 representing the important Δ(1232) dynamics.     

Alpha-decay properties of <Superscript>261</Superscript>Bh

The isotope ²⁶¹Bh was produced in the reaction ²⁰⁹Bi(⁵⁴Cr, 2n)²⁶¹Bh and its \( \alpha\) decay has been remeasured. It was found that it populates by an unhindered transition of \( \approx\) 10 MeV an excited level at E ^* > 350 keV in the daughter nucleus ²⁵⁷Db . The latter decays by internal transitions either into the isomeric state or the ground state. A somewhat improved half-life value of T _1/2 = 11.8^+3.9 _-2.4 ms was obtained for ²⁶¹Bh . The data support the previous assignment of the \( \alpha\) activities ²⁵⁷Db (1) and ²⁵⁷Db (2) to the isomer and to the ground state, respectively. No evidence for an isomeric state in ²⁶¹Bh decaying by \( \alpha\) emission was found. Based on the experimental results and theoretical calculations a partial decay scheme of ²⁶¹Bh including spin and parity assignments of the ground-state and excited levels in the daughter nucleus ²⁵⁷Db populated by the \( \alpha\) decay and succeeding internal transitions have been suggested. ²⁶¹Bh represents so far the heaviest nucleus for which such an attempt has been made. No spontaneous fission (SF) events that could be attributed to ²⁶¹Bh were observed, resulting in an SF branching b _SF < 0.05 . The measured production cross-section is (64±15) pb at E ^* = 22 MeV.     

Spectroscopy of the <Superscript>5</Superscript>H superheavy hydrogen isotope

The formation of the ⁵H superheavy hydrogen isotope was experimentally sought in the reactions induced by stopped π^? mesons absorbed by ⁹Be nuclei. Peaks in missing-mass spectra were observed in two reaction channels, ⁹Be(π^?, pt)X and ⁹Be(π^?, dd)X, and were attributed to the ⁵H resonance states. The lowest state has parameters Er=5.5±0.2 MeV and Г=5.4±0.5 MeV [E_r is the resonance energy measured from the (triton + two neutrons) threshold]. Therefore, ⁵H is bound more weakly than ⁴H. Excited states of ⁵H were also observed. All three resonance levels (E_1r=10.6±0.3 MeV, Г_1r=6.8±0.5 MeV; E_2r=18.5±0.4 MeV, Г_2r=4.8±1.3 MeV; E_3r=26.7±0.4 MeV, Г_3r=3.6±1.3 MeV) can decay into five free nucleons.     

Investigations into the alpha-decay of <Superscript>195</Superscript>At

The low-energy nuclear structure and decay properties of the neutron-deficient isotopes ¹⁹⁵At and ¹⁹¹Bi have been studied. ¹⁹⁵At was produced in the reaction ¹⁴²Nd(⁵⁶Fe,p2n)¹⁹⁵At and ¹⁹¹Bi as the daughter activity of ¹⁹⁵At. The activities were implanted in a position-sensitive silicon detector after being separated from the primary beam by a gas-filled recoil separator. The 1/2⁺ intruder state was determined to be the ground state in ¹⁹⁵At with an alpha-decay energy of E _α = 6953(3) keV and a half-life T _1/2 = 328(20) ms. Another state with an alpha-decay energy E _α = 7075(4) keV and a half-life T _1/2 = 147(5) ms was found to decay to a 148.7(5) keV excited state in ¹⁹¹Bi for which a spin and parity of 7/2^- were deduced. Consequently, the same 7/2^- character was assigned to the initial state at 32(7) keV in ¹⁹⁵At on the basis of unhindered alpha-decay. The 9/2^- state, being the ground state in heavier odd-mass astatine isotopes, was not observed. Received: 16 September 2002 / Accepted: 19 December 2002 / Published online: 25 March 2003 RID="a" ID="a"e-mail: heikki.kettunen@phys.jyu.fi RID="b" ID="b"Present address: Laboratory of Radiochemistry, P.O. Box 55, FIN-00014, University of Helsinki, Finland. RID="c" ID="c"Present address: Radiation and Nuclear Safety Authority, P.O. Box 14, FIN-00881 Helsinki, Finland. Communicated by W. Henning     

Kinetics of the sorption of <Superscript>3</Superscript>He by C<Subscript>60</Subscript> fullerite. The quantum diffusion of <Superscript>3</Superscript>He and <Superscript>4</Superscript>He in fullerite

The kinetics of the sorption and subsequent desorption of gaseous ³He in a C₆₀ fullerite powder has been studied in the temperature range of 2–292 K. The temperature dependences of the diffusion coefficients of ³He and ⁴He impurities in fullerite have been plotted using the measured characteristic times of filling of octahedral and tetrahedral interstices, as well as previous data. These temperature dependences of the diffusion coefficients of ³He and ⁴He impurities in fullerite are qualitatively similar. A decrease in the temperature from 292 to 79 K is accompanied by a decrease in the diffusion coefficients, which corresponds to the dominance of the thermally activated diffusion of helium isotopes in fullerite. A further decrease in the temperature to 8–10 K leads to an increase in the diffusion coefficients by more than an order of magnitude. The diffusion coefficients of ³He and ⁴He are independent of the temperature below 8 K, indicating the tunnel character of the diffusion of helium in C₆₀ fullerite. The isotope effect is manifested in the difference between the absolute values of the diffusion coefficients of ³He and ⁴He atoms at the same temperatures.     

Functionalized TiO<Subscript>2</Subscript> nanoparticles labelled with <Superscript>225</Superscript>Ac for targeted alpha radionuclide therapy

The ²²⁵Ac radioisotope exhibits very attractive nuclear properties for application in radionuclide therapy. Unfortunately, the major challenge for radioconjugates labelled with ²²⁵Ac is that traditional chelating moieties are unable to sequester the radioactive daughters in the bioconjugate which is critical to minimize toxicity to healthy, non-targeted tissues. In the present work, we propose to apply TiO₂ nanoparticles (NPs) as carrier for ²²⁵Ac and its decay products. The surface of TiO₂ nanoparticles with 25 nm diameter was modified with Substance P (5-11), a peptide fragment which targets NK1 receptors on the glioma cells, through the silan-PEG-NHS linker. Nanoparticles functionalized with Substance P (5-11) were synthesized with high yield in a two-step procedure, and the products were characterized by transmission electron microscopy (TEM), dynamic light scattering (DLS) and thermogravimetric analysis (TGA). The obtained results show that one TiO₂-bioconjugate nanoparticle contains in average 80 peptide molecules on its surface. The synthesized TiO₂-PEG-SP(5-11) conjugates were labelled with ²²⁵Ac by ion-exchange reaction on hydroxyl (OH) functional groups on the TiO₂ surface. The labelled bioconjugates almost quantitatively retain ²²⁵Ac in phosphate-buffered saline (PBS), physiological salt and cerebrospinal fluid (CSF) for up to 10 days. The leaching of ²²¹Fr, a first decay daughter of ²²⁵Ac, in an amount of 30% was observed only in CSF after 10 days. The synthesized ²²⁵Ac-TiO₂-PEG-SP(5-11) has shown high cytotoxic effect in vitro in T98G glioma cells; therefore, it is a promising new radioconjugate for targeted radionuclide therapy of brain tumours.     

Distribution of <Superscript>28</Superscript>Si, <Superscript>29</Superscript>Si,and <Superscript>30</Superscript>Si isotopes under plastic deformation in subsurface layers of Si: B crystals

The redistribution of ²⁸Si, ²⁹Si, and ³⁰Si isotopes in subsurface layers of Si: B single crystals after their plastic deformation has been revealed. It has been found that the distribution profile of ²⁸Si and ²⁹Si isotopes becomes smoother after deformation, whereas the ³⁰Si isotope distribution remains unchanged. A change in the subsurface profile of the ²⁹SiO oxide is observed, which indicates the migration of the ²⁹Si isotope in the composition of oxygen complexes during plastic deformation.     

Comparative Investigation on Nanocrystal Structure and Luminescence Properties of Gadolinium Molybdates Codoped with Er<Superscript>3+</Superscript>/Yb<Superscript>3+</Superscript>

This paper reports on the comparative investigation of nanocrystal structure and luminescence properties of Er³⁺/Yb³⁺-codoped gadolinium molybdate nanocrystals Gd₂(MoO₄)₃ and Gd₂MoO₆ synthesized by the Pechini method with citric acid and ethylene glycol. Their crystallization, structure transformation, and morphologies have been investigated by X-ray diffraction, thermogravimetric/differential scanning calorimetry, and transmission electron microscopy. It is noticed that Er³⁺/Yb³⁺-codoped monoclinic Gd₂(MoO₄)₃ nanocrystals have shown an intense upconversion through a sintering of the organic complex precursor at 600°C. Furthermore, it transforms to orthorhombic Gd₂(MoO₄)₃ when the precursor is sintered at 900°C. In counterpart of monoclinic Gd₂MoO₆, however, the monoclinic structure remains unchanged when the precursor is sintered at a temperature ranging from 600°C to 900°C. Intense visible emissions of Er³⁺ attributed to the transitions of ²H_11/2, ⁴S_3/2–⁴I_15/2 at 520 and 550 nm, and ⁴F_9/2–⁴I_15/2 at 650 nm have been observed upon an excitation with a UV source and a 980 nm laser diode, and the involved mechanisms have been explained. It is quite interesting to observe obvious differences both in the excitation and the upconversion emission spectra of Er³⁺/Yb³⁺-codoped Gd₂(MoO₄)₃ respectively with monoclinic and orthorhombic structure. The quadratic dependence of fluorescence on excitation laser power has confirmed that two-photons contribute to upconversion of the green–red emissions.     

New limit on the mass of 14.4-keV solar axions emitted in an <Emphasis Type="Italic">M</Emphasis>1 transition in <Superscript>57</Superscript>Fe nuclei

Axions of energy 14.4 keV that originated from the M1 transition in ⁵⁷Fe nuclei in the Sun were sought by using the resonance-absorption reaction A+⁵⁷Fe → ⁵⁷Fe* → ⁵⁷Fe+γ (14.4 keV). Asectioned Si(Li) detector arranged in a low-background facility was used to record photons from this reaction. This resulted in setting a new limit on the axion couplings to nucleons, |−1.19g _AN ⁰ + g _AN ³| ≤ 3.0×10⁻⁶. Within the hadronic-axion model, the respective constraint on the axion mass is m _A ≤ 145 eV (at a 95% C.L.).