基于静电纺丝实验法的氧化石墨烯复合无纺布光热转换性能的特性研究

氧化石墨烯是工业常用的化学试剂。为了测试其光热转换性能,采用了改进的Hummers方法制取氧化石墨烯(GO)分散液,进而通过静电纺丝制备PVA-GO复合膜,运用紫外吸收漫反射光谱(UVRS)分析了PVA-GO复合膜的吸光性能,通过电子天平连接计算机软件测量PVA-GO蒸发水量。结果表明,在一定范围内,随着GO质量浓度的增加,PVA-GO蒸发水量不断增加。当GO质量浓度达到7%时,PVA-GO复合膜能够较好地被静电纺丝成纤维网状结构,同时又具有良好的光热转换效果。通过扫描电镜(SEM)分析PVA-GO复合膜的表面特征,发现无添加GO的PVA膜是纤维丝状结构,表面光滑,且纤维直径大小一致,分布均匀。当在PVA中填充7%GO时,纤维网接而成,部分GO均匀包裹纤维丝。在真空环境下,423 K高温处理后,PVA-GO复合膜致密度增加,GO附着纤维丝程度提升。当使用980 nm红外激光辐射时,PVA-GO复合膜的蒸发速率为0.81 kg/(m²·h),约是聚乙烯醇膜的两倍。同时,蒸发效率达到51%。这不仅提高了光热转换性能,增加了光能利用率,还可以为海水淡化的工业应用提供参考...     

Fabrication and Characterization of Ultrathin Graphene Oxide/Poly(Vinyl Alcohol) Composite Films via Layer-by-Layer Assembly

Novel multilayer ultrathin films comprised of graphene oxide (GO) and poly(vinyl alcohol) (PVA) were fabricated through a layer-by-layer (LBL) assembly technique. GO could self-assemble onto quartz substrates alternately with PVA via hydrogen-bonding interactions. X-ray diffraction, atomic force microscopy, and transmission electron microscopy analysis revealed that GO was exfoliated to monolayers. The ultrathin films, with PVA/GO multilayer structures fabricated by LBL assembly, were characterized by ultraviolet-visible spectroscopy and X-ray diffraction analysis, confirming that the assembly of the multilayer films was quantitative and reproducible.     

基于聚噻吩/聚己内酯共混物的有机薄膜晶体管

选择聚3-己基噻吩(P3HT)/聚己内酯(PCL)双晶共混体系制备了不同配比的共混物有机薄膜晶体管。电学性能研究发现,随着共混物中P3HT含量降低,薄膜晶体管的场效应迁移率、开关电流比和阈值电压等性能缓慢降低。当P3HT质量分数为40%时,共混物薄膜仍具有较好的场效应性能,迁移率为0.008 cm²·V^-1·s^-1,开关电流比为5×10³,阈值电压为45.5 V。原子力显微镜测试结果表明:共混物成膜时发生明显的垂直相分离,在界面处形成连续的半导体层,有利于载流子传输。