共查询到20条相似文献,搜索用时 31 毫秒
1.
在采用体积相加原理计算混合物物态方程的基础上,建立了一种物理模型确定混合物温度。根据混合物中各组分温度和压强平衡条件,采用压强-密度迭代方法计算给出混合物物态方程,编制了两种组分的混合物物态方程计算程序。为检验建立的温度模型的合理性及程序的有效性,分析了不同密度、温度状态的氢(H2)和钨(W)组成的混合物状态参量,计算了以下情形及其组合情形的混合物物态方程:H2和W以不同质量比混合;质量比固定,单组分状态不同;温度区间和密度区间不同。研究表明:实际应用中在建立的混合物温度模型基础上确定的混合物物态方程是合理的。 相似文献
2.
在采用体积相加原理计算混合物物态方程的基础上,建立了一种物理模型确定混合物温度。根据混合物中各组分温度和压强平衡条件,采用压强-密度迭代方法计算给出混合物物态方程,编制了两种组分的混合物物态方程计算程序。为检验建立的温度模型的合理性及程序的有效性,分析了不同密度、温度状态的氢(H2)和钨(W)组成的混合物状态参量,计算了以下情形及其组合情形的混合物物态方程:H2和W以不同质量比混合;质量比固定,单组分状态不同;温度区间和密度区间不同。研究表明:实际应用中在建立的混合物温度模型基础上确定的混合物物态方程是合理的。 相似文献
3.
The distributions of zeros of the partition function of lattice gas models of Fisher (at some temperature) and of Temperley are obtained. The former is a closed loop crossing the real axis and the latter is a part of the negative real axis. 相似文献
4.
A. V. Matveev 《Russian Physics Journal》2007,50(7):646-652
Within the framework of the electron density functional, a technique is developed for calculation of the adsorption energy
and variation in the electron work function for metal substrates due to metal atom adsorption. The corrections to the local
density approximation, which are associated with non-uniformity of the electron density in the subsurface region and discontinuous
ion charge distribution over the crystal lattice sites, are included into consideration. It is shown that adsorption of alkali
metal atoms results in lower electron work function, while that of transition metals (cobalt, iron, and chromium) might both
decrease and increase the electron work function. Formation of a variety of adsorption structures from metal atoms depending
on the temperature is discussed.
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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 7, pp. 14–19, July, 2007. 相似文献
5.
《Solid State Communications》1986,57(7):519-522
Electrolysis of interlayer water of crystallisation has been established by a direct d.c. electrolysis experiment on molybdic acid. The dihydrate MoO3middot; 2H2O gets converted into its monohydrate. This is confirmed by IR and Laser Raman Spectra. The increase in a.c. electrical conductivity with increasing d.c. bias, a.c. signal level and ambient humidity also supports the above viewpoint. 相似文献
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傅里叶望远镜外场实验性能改进和结果分析 总被引:4,自引:0,他引:4
为了实现对傅里叶望远镜成像系统更接近实际的仿真,改进了外场实验系统结构。采用反射式目标,利用准直扩束镜替代空间滤波器和准直透镜,使用大靶面电荷耦合器件作为监视器。在无大气和包含200m水平大气两种情况下,分别对2.5mm的4种不同空间频谱分布目标进行实验。实验选用9×9,17×17,33×33和65×65傅里叶分量分别进行重构。最高成像角分辨率为3.5″。结果表明含大气与无大气重构结果的Strehl比值相近,从而证明傅里叶望远镜成像系统能够克服下行链路低阶大气扰动的影响。 相似文献
8.
New methods of interpretation of meteor observations were developed and published in [1?C9]. The interpretation of ground-based observations of meteors and bolides available today in the scientific literature all over the world suffers from serious contradictions. Observers use the so-called photometric approach for determination of extra-atmospheric masses of meteoric bodies. This approach is based on the formula proposed in 1933 [10] and very simple ideas of how to describe the interaction between the atmospheric air and the surface of a meteoric body. These ideas are provisionally suitable to describe the flow around a body in a free molecular regime. Subsequently, the photometric approach was applied to all the meteor events including bolides. The main effort aimed to elaborate the approach included a choice of new formulas for the radiative efficiency. 相似文献
9.
The temperature dependence of the self-reversal of magnetization of polycrystalline nickel wire at temperatures from room temperature to the Curie point is examined and interpreted. The critical field for self-reversal and the reversed magnetization decrease steadily towards the Curie point and are affected by tension and the prehistory of the specimen.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 52–55, January, 1973. 相似文献
10.
多介质流体动力学过程的数值模拟往往涉及混合物状态方程的计算. 做图法和Newton 法是混合物状态方程计算常采用的方法, 前者虽直观精度却差, 后者计算效率高却只具有局部收敛性, 当解与其初始猜测值相差较远时Newton法不一定能够获得收敛解. 为此, 本文给出一种具有大范围收敛性的嵌入算法(imbedding method)求解混合物状态方程, 其基本思想是通过引入嵌入参数, 将待解的混合物状态方程和易解的混合物状态方程线性组合, 构成嵌入方程组, 当嵌入参数从0连续地变化到1 时, 嵌入方程组的解由易解的混合物状态方程的解连续地变化为待解的混合物状态方程的解. 嵌入方程组可由Newton法迭代求解, 也可转化为以嵌入参数为自变量的常微分方程组, 从而易于由成熟的计算方法如梯形法等进行求解. 进一步利用热力学基本关系, Maxwell形式的微分方程描述了压力和温度随嵌入参数的演化速率与应变速率和组分质量分数演化速率的关系. 对铅锡混合物热力学量的计算表明了本文算法的有效性. 相似文献
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K. A. Rustamov 《International Journal of Theoretical Physics》1989,28(6):695-698
General results on the algebraic properties of integrodifferential equations are used to obtain coherent and squeezed states and Green functions for the matrixdifferential models of condensed matter theory. 相似文献
13.
P. F. C. Menezes H. Imasato J. Ferreira V. S. Bagnato J. R. Perussi 《Laser Physics》2007,17(4):461-467
Photodynamic therapy (PDT) is an approved modality for cancer treatment, which involves the administration of a photosensitive drug (PS) that is selectively accumulated in neoplastic tissues and their vasculature and subsequently can be activated with light at the appropriate wavelength to generate reactive molecular species that are toxic to tissues. In PDT, a great part of the used PS suffers degradation by light (photobleaching) that involves a decrease in the absorption and intensity of fluorescence of the photosensitizer as well as photoproduct formation evidenced by the appearance of a new absorption band. In this study, we investigated the correlation of cytotoxicity and depth of necrosis of Photogem and its photoproducts obtained previously by irradiation at 514 and 630 nm. The cytotoxicity for degraded Photogem decreases with the previous irradiation time of Photogem solution suggesting that the photoproducts of Photogem are less cytotoxics than the original formulation. A transition between the necrosed epithelium and healthy epithelium of normal liver of rats after irradiation at 630 nm was observed with irradiated and nonirradiated PS. It is observed that the depth of necrosis only at irradiation dose of 150 J/cm2 in both concentrations is greater for Photogem followed by Photogem degradated previously at 514 and then at 630 nm. The results obtained suggest that the threshold of necrosis values is lower for Photogem followed by its photoproducts formed, suggesting that the photoproducts present a low photodynamic activity. If the photosensitizer degradation happens at the same time as tumor destruction, the drug degradation can be complete before reaching the threshold of necrosis; then it is very important to control the drug concentration and light intensity of irradiation during PDT. 相似文献
14.
Various models for determination of the temperature dependence of thermal pressure are critically examined in the light of
experimental data. We have considered Mg2SiO4, Olivine, MgAl2O4, Pyrope rich garnet, Fe2SiO4, Grossular garnet, MnO, NaCl and KCl. The superiority of one model over others is discussed. The model is extended to study
the compression behaviour at different temperatures, and the combined effect of pressure and temperature on thermal pressure
of San Carlo Olivine. A good agreement obtained between theory and experiment demonstrates the validity of the present approach. 相似文献
15.
A. H. Martirosyan 《Journal of Contemporary Physics (Armenian Academy of Sciences)》2009,44(6):296-299
A new method for determining the density of polymer materials based on determination of the path-length differences in moiré
patterns is proposed. The method is characterized by simplicity and accuracy of results. The densities of polychloropren and
polystirol have been determined with high accuracy. Knowledge of the dependence of the polymer density on the stretching degree
enables one to reveal the dynamics of changes in the permolecular structure at deformation of polymers. 相似文献
16.
在磁场作用下水的特性的变化和它的变化机理 总被引:7,自引:0,他引:7
我们研究了在磁场作用下水的光学性质和电学性质等的变化,实验发现它们的这些特性和未受磁场作用的水有重大改变特别是在红外光谱和拉曼光谱中的变化更加明显,这种现象就称为水的磁化。我们从水的中红外光谱得知在3000~3800 cm-1的范围内有奇特的六个峰值存在,从水分子结构和红外光谱的特性出发了解到它们分别代表了自由水分子的OH键的对称与反对称的振动,众多水分子通过氢键连接而成的线性链和环形链的OH键的对称与反对称振动,于是从这个实验我们看到了在这个水中存在有众多水分子结合成的环形氢键链的存在。我们用水分子的极化特性,一阶相变的特性和实验进一步证实了这些环形链的客观存在,根据质子或氢离子在氢键系统中传递理论得知在磁场的罗仑兹力作用下处于水中环形氢键链中质子能够进行传导产生环形电流.这些环形电流象一个分子电流或是个小磁体,它们能彼此相互作用或与外加磁场相互作用,从而改变了水分子的分布和结构状态,导致了水的一些特性的变化,这就是水的磁化的分子机理,我们用这个机理解释了我们从实验中所发现的磁处理过的水的特性如饱和效应和记忆效应等,因此这是非常有趣的实验和现象. 相似文献
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V. A. Alekseev 《Optics and Spectroscopy》2006,100(2):178-187
The formation of triatomic excimer molecules Rg2X and Rg’RgX by VUV excitation of mixtures of halogens with rare gases is discussed. The remarkable simplicity of the electronic structure and kinetics of these molecules offers interesting possibilities for studying the role of different collisional processes in recombination in the high-and low-pressure limits. 相似文献
20.
A mathematical model for the determination of physical constants in equations of state at the interface between a metal and an inert gas medium has been developed in terms of the surface physics and thermodynamics of nonequilibrium processes with due regard for internal stresses induced by a redistribution of conduction electrons. Physical characteristics of a surface layer, in particular, at the copper-inert gas medium interface and the silicon-inert gas medium interface, have been determined using experimental values of surface tensions and energies for contacting media. 相似文献