Magnetic properties of terbium dihydrides

Magnetization measurements of terbium dihydride samples with different hydrogen concentration, TbH_1.92, TbH_1.99, TbH_2.03 and TbH_2.09, in the temperature range from 1.8 to 300 K and at an applied field of 1 kOe are reported. Two first-order antiferromagnetic transitions have been registered in the narrow temperature range between 15–18 K for all hydride compositions. Isothermal magnetization ($\sigma {\left(H\right)}_{T=\mathrm{const}}$) measurements at several temperatures in the vicinity of magnetic transitions have been carried out and used for the magnetic-entropy change, $\Delta S_{\sigma }$, calculations. The magnetic-entropy changes have negative values, and in an applied magnetic field of 5 T they reach 2.5 J/kg K, which is only about 26% of the $\Delta S_{\sigma }\left(H\right)$ value expected from thermal measurements. A much larger magnetic field must be applied for terbium hydrides to be used as refrigerant materials for low-temperature needs.     

Unusual superconducting behavior in HfV2Ga4

Bulk superconductivity in HfV₂Ga₄ with critical temperature close to 4.1 K was determined via magnetic susceptibility, electrical resistivity and specific heat measurements. Both the upper and lower critical field dependence with reduced temperature ($T/T_c$) exhibit non-conventional behavior. The electronic component of specific heat shows a double-jump, the first close to $T_c$ and the other close to $0.75T_c$. We speculate about the nature of the douple jump observed in specific heat considering two plausable scenarios: bulk inhomogeneities and the existence of a second gap.     

Electronic structure and optical properties of ABP2O7 double phosphates

Luminescence and luminescence excitation under VUV radiation of ${\mathrm{ABP}}_2{\mathrm{O}}_7$ ($\mathrm{A}=\mathrm{Na}$, K, Cs; $\mathrm{B}=\mathrm{Al}$, In) double phosphates are studied. Two emission bands peaking near 330 and 420 nm are common for investigated ${\mathrm{ABP}}_2{\mathrm{O}}_7$ crystals. The band structure and partial densities of electronic states of perfect ${\mathrm{KAlP}}_2{\mathrm{O}}_7$, ${\mathrm{LiInP}}_2{\mathrm{O}}_7$ and ${\mathrm{NaTiP}}_2{\mathrm{O}}_7$ crystals are calculated by the full-potential linear-augmented-plane-wave (FLAPW) method. It is found that the structures of the conduction bands of ${\mathrm{ABP}}_2{\mathrm{O}}_7$ crystals, which have different B cations, are appreciably different. Experimental results are compared with results of calculations of the electronic structure. Assumptions concerning the origin of luminescence in double phosphates are made.     

Shannon and Fisher entropies for a hydrogen atom under soft spherical confinement

We calculate Shannon and Fisher entropies in the position and momentum space, and some complexity measures for a variationally described hydrogen atom confined in soft and hard spherical boxes of varying dimension $r_c$ and selected values of strength $U_0$. We include calculations for a free particle trapped in impenetrable boxes. It is found that the Shannon entropy $S_r$ becomes negative for small cavity radii and large values of $U_0$, due to the highly localized nature of the particle. For soft confinement and small cavity dimensions, the entropies change very rapidly over short radial intervals.     

Spin-glass behavior in the antiperovskite manganese nitride Mn3CuN codoped with Ge and Si

Antiperovskite manganese nitrides ${\mathrm{Mn}}_3\left({\mathrm{Cu}}_{0.6}{\mathrm{Si}}_x{\mathrm{Ge}}_{0.4?x}\right)N$ ($x=0.05$, 0.1, 0.15) were prepared and their negative thermal expansion, magnetic and specific heat properties were investigated. A frozen state with a freezing temperature was found at ～207 K in ${\mathrm{Mn}}_3\left({\mathrm{Cu}}_{0.6}{\mathrm{Si}}_{0.15}{\mathrm{Ge}}_{0.25}\right)N$. This indicates that ${\mathrm{Mn}}_3\left({\mathrm{Cu}}_{0.6}{\mathrm{Si}}_{0.15}{\mathrm{Ge}}_{0.25}\right)N$ exhibits a spin glass state at low temperatures. We discussed the cause of spin glass behavior and correlated this spin glass behavior with broadening of the negative thermal expansion operation-temperature window of the manganese nitrides ${\mathrm{Mn}}_3\left({\mathrm{Cu}}_{0.6}{\mathrm{Si}}_{0.15}{\mathrm{Ge}}_{0.25}\right)N$.     

Leibniz algebras associated with representations of filiform Lie algebras

In this paper we investigate Leibniz algebras whose quotient Lie algebra is a naturally graded filiform Lie algebra $n_{n,1}$. We introduce a Fock module for the algebra $n_{n,1}$ and provide classification of Leibniz algebras $L$ whose corresponding Lie algebra $L/I$ is the algebra $n_{n,1}$ with condition that the ideal $I$ is a Fock $n_{n,1}$-module, where $I$ is the ideal generated by squares of elements from $L$.We also consider Leibniz algebras with corresponding Lie algebra $n_{n,1}$ and such that the action $I\times n_{n,1}\to I$ gives rise to a minimal faithful representation of $n_{n,1}$. The classification up to isomorphism of such Leibniz algebras is given for the case of $n=4$.     

Percolation on infinitely ramified fractal networks

We study how fractal features of an infinitely ramified network affect its percolation properties. The fractal attributes are characterized by the Hausdorff ($D_H$), topological Hausdorff ($D_{tH}$), and spectral ($d_s$) dimensions. Monte Carlo simulations of site percolation were performed on pre-fractal standard Sierpiński carpets with different fractal attributes. Our findings suggest that within the universality class of random percolation the values of critical percolation exponents are determined by the set of dimension numbers ($D_H$, $D_{tH}$, $d_s$), rather than solely by the spatial dimension (d). We also argue that the relevant dimension number for the percolation threshold is the topological Hausdorff dimension $D_{tH}$, whereas the hyperscaling relations between critical exponents are governed by the Hausdorff dimension $D_H$. The effect of the network connectivity on the site percolation threshold is revealed.     

The privileged spectrum of cnoidal ion holes and its extension by imperfect ion trapping

The fundamental properties of nonlinear ion hole modes propagating in current-driven collisionless plasmas are derived. Making use of Schamel's alternative method their spatial structure $?(x)$ and phase velocities $u_0$ are analyzed and found to depend crucially on the used trapped ion distribution $f_{it}$. A regular $f_{it}$ represents a continuous spectrum, which is called privileged or perfect since it yields a definite $u_0$ and appears most realistic. A singular $f_{it}$, on the other hand, involving jumps and moderate slope singularities at the separatrix, does reveal further classes of hole equilibria at the cost, however, of a well-defined $u_0$. This explains why Bernstein, Greene, Kruskal (BGK)-solutions of the Vlasov–Poisson system, exhibiting a strong slope singularity of their derived trapped particle distribution, can principally not provide definite $u_{0}s$. The nonlinear dispersion relation (or $u_0$) of privileged ion holes, on the other hand, is equivalent with that of cnoidal electron holes, i.e. in addition to the ordinary ion acoustic branch there exists a correspondence to the “Langmuir” branch and to the multiple “slow electron acoustic” branches, reflecting different trapping scenarios.     

Effects of photon field on heat transport through a quantum wire attached to leads

We theoretically investigate photo-thermoelectric transport through a quantum wire in a photon cavity coupled to electron reservoirs with different temperatures. Our approach, based on a quantum master equation, allows us to investigate the influence of a quantized photon field on the heat current and thermoelectric transport in the system. We find that the heat current through the quantum wire is influenced by the photon field resulting in a negative heat current in certain cases. The characteristics of the transport are studied by tuning the ratio, $?{\omega }_{\gamma }/k_{\mathrm{B}}\mathrm{\Delta }T$, between the photon energy, $?{\omega }_{\gamma }$, and the thermal energy, $k_{\mathrm{B}}\mathrm{\Delta }T$. The thermoelectric transport is enhanced by the cavity photons when $k_{\mathrm{B}}\mathrm{\Delta }T>?{\omega }_{\gamma }$. By contrast, if $k_{\mathrm{B}}\mathrm{\Delta }T<?{\omega }_{\gamma }$, the photon field is dominant and a suppression in the thermoelectric transport can be found in the case when the cavity-photon field is close to a resonance with the two lowest one-electron states in the system. Our approach points to a new technique to amplify thermoelectric current in nano-devices.