壳聚糖及其衍生物对金属离子的吸附研究(下)

壳聚糖是一种天然高分子,在其分子结构的重复单元中有-NH2和-OH,因而对金属离子有较好地吸附和配位能力。本文较全面的综述了壳聚糖及其衍生物对金属离子的吸附性能,简述了它们与金属离子形成配合物的结构及吸附机理。其中下篇主要讲述了壳聚糖及其衍生物与金属离子形成配合物后的结构以及吸附机理,并对其发展前景作了展望。     

壳聚糖及其衍生物对金属离子的吸附研究(上)

壳聚糖是一种天然高分子,在其分子结构的重复单元中有-NH2和-OH,因而对金属离子有较好地吸附和配位能力.本文较全面地综述了壳聚糖及其衍生物对金属离子的吸附性能,简述了它们与金属离子形成配合物的结构及吸附机理,并对其发展前景作了展望.其中上篇主要讲述了壳聚糖及其衍生物对金属离子吸附性能的研究进展.     

Cu~(2 )壳聚糖螯合物及壳聚糖吸附Cu~(2 )机理的XPS研究

壳聚糖能选择性地吸附Ｍｇ2 、Ｎｉ2 、Ａｌ3 、Ａｇ 、Ｐｂ2 等金属离子[1],在环境保护、水处理、贵金属精制和回收等领域有广泛的应用前景[2 ].目前对壳聚糖吸附金属离子尤其是对Ｃｕ2 吸附的研究十分活跃 ,对壳聚糖吸附了Ｃｕ2 后形成的螯合物的研究也有报道[3,4 ].Ｉｎａｋｉ等[5]认为壳聚糖吸附Ｃｕ2 的机理是通过其表面—ＮＨ2 及其邻近的—ＯＨ与Ｃｕ2 进行络合反应从而吸附了Ｃｕ2 .本文用Ｘ射线光电子能谱 (ＸＰＳ)研究了壳聚糖及吸附Ｃｕ2 后形成的Ｃｕ2 壳聚糖螯合物表面的元素组成及其结合能的变化 ,根据结合能的变…     

壳聚糖及其衍生物对重金属离子的吸附

壳聚糖的结构中含有大量的—NH₂和—OH,因此其对重金属离子有优良的吸附作用。但是作为天然高分子物质,壳聚糖的吸附性能又受到其自身物理形态、原料来源、脱乙酰度及体系pH值的影响,因此,对其进行物理和化学改性是提高壳聚糖吸附性能、扩大应用范围的必要手段。本文综述了壳聚糖的改性方法及其衍生物对重金属离子吸附作用的研究进展,并对其在重金属污染废水处理方面的前景作了展望。     

N-羧甲基壳聚糖的制备及其对重金属离子吸附研究

采用氯乙酸和壳聚糖为原料制备了N-羧甲基壳聚糖,并研究了其对重金属离子Pb2+、Co2+、Ni2+、Cd2+的吸附行为。采用了XRD、FT-IR、1H-NMR对N-羧甲基壳聚糖进行了表征,对N-羧甲基壳聚糖的4种金属离子配合物进行了FT-IR表征。结果表明,N-羧甲基壳聚糖对Pb2+、Co2+、Ni2+、Cd2+的吸附能力优于壳聚糖,分子中羧基是主要的螯合基团。     

含硫壳聚糖衍生物的应用研究进展

本文综述了近年来含硫壳聚糖衍生物的制备及应用研究进展,主要介绍了巯基化壳聚糖、硫脲衍生物修饰壳聚糖在金属离子吸附分离中的应用及磺化壳聚糖在生物医药方面的应用。     

交联壳聚糖的结构及其对不同金属离子的吸附性能

交联壳聚糖的结构及其对不同金属离子的吸附性能;交联壳聚糖;Cu2+;Co2+;Ni2+;结构;吸附性能     

二乙烯三胺接枝壳聚糖的合成与表征

以壳聚糖为基体,与环氧氯丙烷反应,然后与二乙烯三胺反应,制得二乙烯三胺接枝壳聚糖(CTSN)。经红外光谱FTIR分析和X-射线衍射分析表征了结构,在活化及接枝过程中未破坏壳聚糖中的吡喃苷六元环结构,其结构与预期结构吻合。初步研究了它对Pd2 、Ag 、Ni2 、Cu2 、Co2 、Cd2 金属离子的静态吸附性能,试验结果表明,CTSN对金属离子有较大的吸附容量,对Pd2 、Ag 离子的吸附容量分别为1.29mmol/g和1.15mmol/g。     

壳聚糖分离-原子吸收光谱法测定水中铜、锌、钴、镍、铅和镉

研究了天然高分子吸附剂-壳聚糖对Cu^2 、Zn^2 、Co^2 、Ni^2 、Pb^2 和Cd^2 6种离子的吸附行为以及在不同pH值、干扰离子存在时对壳聚糖吸附6种离子的影响,建立了壳聚糖柱同时分离六种离子,火焰原子吸收法测定含量的分析方法,并应用于自来水和电镀废水中6种金属离子分离和测定。     

不同组分下三乙烯四胺交联壳聚糖对重金属离子的吸附性能

三乙烯四胺;交联;壳聚糖;重金属离子;吸附     

二氧化碳和丙烯直接合成甲基丙烯酸的NiPMo/TiO2催化剂的研究

用溶胶-凝胶法以磷钼酸(MPA)的镍盐溶液水解钛酸四丁酯制备了NiPMo/TiO2催化剂.使用ICP、 XRD、 TG-DTA、 IR、 TPD-MS和微反应技术研究了催化剂的化学组成、热稳定性、化学吸附性质和催化反应性能.杂多钼酸盐与TiO2通过O2-在TiO2表面发生了键合.在623 K下,杂多阴离子仍保持原有的Keggin结构.CO2在Lewis酸位Ni(Ⅱ)和Lewis碱位Ni-O-Mo的桥氧协同作用下生成CO2卧式吸附态Ni(Ⅱ)←O-(CO)←(O--Ni).丙烯有多种吸附态在催化剂上吸附.在563 K、 1 MPa和空速1500 h-1的反应条件下,丙烯的摩尔转化率为3.2%,产物MAA选择性为95%.     

Toward new camptothecins. Part 6: Synthesis of crucial ketones and their use in Friedländer reaction

In the context of the preparation of camptothecin and luotonin A analogs, the synthesis of some key keto-precursors and their use in Friedländer condensation are described. This paper also focuses on the stability of these keto intermediates and emphasizes the major differences between indolizinones and pyrroloquinazolinones series. Noteworthy is also the report of some original structures isolated as by-products of some experiments.     

α-Amino acid derived enaminones and their application in the synthesis of N-protected methyl 5-substituted-4-hydroxypyrrole-3-carboxylates and other heterocycles

A new and simple synthesis of novel N-protected methyl 5-substituted-4-hydroxypyrrole-3-carboxylates, which exist in equilibrium with their 4-oxo tautomers, has been developed in two steps starting from N-protected α-amino acids. The key intermediates are enaminones, which can also be isolated, characterized, and used for the construction of other functionalized heterocycles, before they spontaneously decompose to pyrrole products. 4-Hydroxypyrroles are prone to partial aerial oxidation but can be efficiently alkylated or reduced to stable polysubstituted pyrrolidine derivatives.     

Specific intramolecular aromatic CH insertion of diazosulfonamides

The chemoselectivity in the intramolecular CH insertion of various diazosulfonamides has been experimentally studied. The results reveal that the aliphatic 1,4-, 1,5-, or 1,6-C(sp³)?H insertions of diazosulfonamides are not accessible, while the aromatic 1,5-C(sp²)?H insertion can be realized specifically by adjusting the diazo-adjacent group. In addition, the general chemoselectivities in the intramolecular CH insertions of diazosulfonyl compounds are summarized. Generally, diazosulfones undergo both aromatic 1,5-C(sp²)?H and aliphatic 1,5- and 1,6-C(sp³)?H insertions, while diazosulfonates undergo aliphatic 1,5- and 1,6-C(sp³)?H insertions. However, diazosulfonamides only undergo aromatic 1,5-C(sp²)?H insertion.     

CoFe2O4自形成磁性液体场致结构化对磁化的影响

The Langevin paramagnetic theory can’t describe the relation between magnetization of ferrofluids and applied magnetic field. The structuralization of ferrofluids, which is considered the main influence factor of the magnetization, is regarded. The part of magnetization works is deposited when the structure is forming. This action influences the magnetization of ferrofluids directly or indirectly. On the base of the “compressing” model, the Langevin function that usually describes the magnetization of ferrofluid is modified, and a well-fitted curve is obtained. An equation of the relation between the equivalent volume fraction after being “compressed” and the intensity of magnetic field is discovered, which approximately describes the process of magnetization. The relation between the approximate initial susceptibility and the volume fraction can be obtained from modified formula.     

KMnO4-mediated oxidative CN bond cleavage of tertiary amines: Synthesis of amides and sulfonamides

KMnO₄-mediated oxidative CN bond cleavage of tertiary amines producing secondary amine was introduced, which was trapped by electrophiles (acyl chloride and sulfonyl chloride) to form amides and sulfonamides. The reaction could take place at mild condition, tolerating a wide range of function groups and affording products in moderate to excellent yields.     

Chemistry of heterocyclic compounds at the A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, over 50 years (Review)

The review contains a concise historical account and information on the most significant researches undertaken by the staff at the A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences on the Chemistry of Heterocyclic Compounds. Dedicated to Academician of the Russian Academy of Sciences B. A. Trofimov on his 70th jubilee. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1443–1502, October, 2008.     

Highly regioselective Buchwald–Hartwig amination at C-2 of 2,4-dichloropyridine enabling a novel approach to 2,4-bisanilinopyridine (BAPyd) libraries

The highly regioselective Buchwald–Hartwig amination at C-2 of the cheap and readily accessible reagent, 2,4-dichloropyridine with a range of anilines and heterocyclic amines is described. This new methodology is robust and provides a facile access to 4-chloro-N-phenylpyridin-2-amines on 0.25 mol scale. These intermediates undergo a further Buchwald–Hartwig amination at higher temperature to enable rapid exploration of the chemical space at C-4 and to provide a library of 2,4-bisaminopyridines.     

N-Heterocyclic carbene-palladacyclic complexes: synthesis,characterization and their applications in the C-N coupling and α-arylation of ketones using aryl chlorides

N-Heterocyclic carbene-palladacyclic complexes 3 were successfully achieved in a one-pot procedure under mild conditions. The structure of 3a was unambiguously confirmed by X-ray single crystal diffraction and it was an active catalyst in the Buchwald-Hartwig amination and α-arylation of ketones even at very low catalyst loadings (0.01?mol%).     

Iodine-mediated oxidative Pictet-Spengler reaction using terminal alkyne as the 2-oxoaldehyde surrogate for the synthesis of 1-aroyl-β-carbolines and fused-nitrogen heterocycles

An efficient iodine-mediated oxidative Pictet-Spengler reaction in dimethyl sulphoxide (DMSO) using terminal alkynes as the 2-oxoaldehyde surrogate for the synthesis of aryl (9H-pyrido[3,4-b]indol-1-yl)methanones is described. The scope of the protocol includes the total synthesis of Fascaplysin, Eudistomins Y₁ and Y₂. The methodology is extended for preparing pyrrolo[1,2-a]-quinoxaline and indolo[1,5-a]quinoxaline derivatives. The utility of 1-aroyl-β-carbolines was demonstrated by performing palladium-catalyzed β-carboline directed ortho-C(sp2)-H functionalization of the phenyl ring with thiomethyl (SMe) group using DMSO as source and for accessing 4-aryl-canthin-6-ones.