共查询到20条相似文献,搜索用时 15 毫秒
1.
2.
3.
4.
5.
6.
7.
The reaction of the meso-diol, Δ,Λ-[(en)2Rh(OH)2Rh(en)2]4+, with aqueous H2O2 and 1 equiv. of NaOH at 90° forms the μ-peroxo-μ-hydroxo-bridged species Δ,Λ-[(en)2Rh(O2,OH)Rh(en)2]3+ in a yield of ca. 50%. The compound was crystallized as perchlorate and trifluoromethanesulfonate salts. The structure of the latter salt was determined by single-crystal X-ray diffraction. The crystals are triclinic with space group P1 and lattice constants a = 11.895(5), b = 12.491(4), c = 13.053(5) Å, α = 103.98(3), β = 92.59(3), γ = 119.52(6)°. The distances of the metal centres to the bridging peroxo ligand are 1.999(8) and 1.983(6) Å. The O? O distance in the peroxo group is 1.521(14) Å, and the dihedral angle of the Rh? O? O? Rh unit deviates 65° from planarity. The peroxo complex reacts reversibly with acid, and spectrophotometric studies suggest that the reaction involves protonation of the peroxo bridge, with pKa = 2.70(2) at 25° in 1M NaClO4. 相似文献
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.