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1.
Functional groups with the capability of hydrogen bonding are widely used in the molecular design and preparation of liquid crystalline supramolecular systems, a rapidly growing area of materials showing a high sensitivity towards external stimuli. A series of novel imidazole-containing Schiff's bases replenishing the family of supramolecular liquid crystals has been synthesised and characterised by proton nuclear magnetic resonance, Fourier transform infrared, and ultraviolet–visible spectroscopy, and elemental analyses. Variation of lengths of the terminal alkyl substituents in the obtained amphiphilic imidazoles within 6, 8, 10, 12, 14 and 16 carbon atoms leads to significant changes in their thermal behaviour, micro-segregation and supramolecular self-assembly. Lower homologues were non-mesomorphic, while intermediate members of the homologous series exhibited monotropic bilayered smectic and columnar mesophases. A higher homologue with 16 carbon atoms has an increased trend towards crystallisation of the aliphatic chains and did not exhibit mesomorphism again. The liquid crystalline mesophases were identified and investigated by polarised optical microscopy, differential scanning calorimetry, X-ray diffraction and thermal emission microscopy methods. According to X-ray diffraction characteristics, the smectic mesophase has a bilayered structure where the hydrophilic imidazole groups form a continuous hydrogen bonded network. The interface curvature created by the second alkyl chain leads to the appearance of columnar nanostructures in homologues with 12 and 14 aliphatic carbon atoms. 相似文献
2.
The display parameters and the stability of the various mesophases of a newly synthesised racemic mixture of anti-ferroelectric liquid crystals (AFLCs) have been boosted with the help of the electron beam irradiation. The mixture has phase sequence of isotropic–smectic C–smectic CA crystal. The effective macroscopic polarisation and transition temperatures of the various mesophases of the irradiated mixture have increased as compared with the pure mixture. The macroscopic polarisation of the mixture has increased from 21 to 27 nC/cm2 due to the irradiation. From various studies, we have observed that the temperature range of the smectic CA phase has increased by 20.6°C with marginal decrease in the temperature range of the smectic C phase. 相似文献
3.
Synthesis and characterization of non-symmetrical liquid crystals containing a cholesteryl ester moiety 总被引:1,自引:0,他引:1
Duo Wei Zhang Wei Huang Guo Hui Pan Wan Li He Yu Bo Cao Jin Bao Guo Hui Cao Huai Yang 《中国化学快报》2009,20(5):562-565
In this paper,a series of chiral non-symmetrical liquid crystals(nBA-chol)consisting of a cholesteryl ester moiety as chiral entity and a biphenyl aromatic core with different terminal alkyl chain has been synthesized and investigated for their liquid crystalline properties.Effects of numbers of methylene units in the terminal alkyl chain on the phase transition temperatures and on the temperature-dependent pitch lengths of the chiral liquid crystals have been studied.The long terminal alkyl chain tends ... 相似文献
4.
AbdulKarim-Talaq Mohammad H. T Srinivasa Hariprasad Suresh Guan-Yeow Yeap 《Liquid crystals》2016,43(9):1174-1183
New substituted derivatives of 5-vinyl-1,3-dimethylbarbituric acid were synthesised and evaluated for liquid crystal properties. Two sets of molecules were prepared. One end of all the molecules possesses the 1,3-dimethylbarbituric core. The first set comprises biphenyl ethers, 4a–n and the second set biphenyl esters, 5a–g. Liquid crystalline properties were investigated by POM and DSC techniques. All the compounds exhibited enantiotropic smectic A and nematic mesophases. The LC properties were found to depend on the spacer and terminal alkoxy- chain and alkoxy- ester moiety of the molecules. Smaller alkyl chain members showed a smectic phase, while higher alkyl chain members showed a nematic phase. 相似文献
5.
A series of 2-(4-biphenylyl)-1,3,4-oxadiazoles bearing alkyl or alkoxy substituents at the 4? position, and a hydrogen, or alkyl substituent (linear, branched, fluorinated or functionalised) at the 5 position were synthesised and characterised (51 compounds). Their mesogenic properties were evaluated using differential scanning calorimetry and polarising optical microscopy. Results show that substitution of the 1,3,4-oxadiazole ring for a terminal benzene ring in a conventional p-terphenyl enriched the mesogenic properties. Most of the new oxadiazole compounds exhibit either monotropic or enantiotropic smectic A mesophases with widths ranging from 3 to 50°C. A few compounds (short tailed) exhibit nematic phases and some compounds with branched or fluorinated alkyl substituents at the 5 position are also mesogenic. 相似文献
6.
R. G. Santos-Martell A. Ceniceros-Olguín L. Larios-López R. J. Rodríguez-González B. Donnio 《Liquid crystals》2013,40(8):787-797
Molecules containing a terphenylene core, two alkyl chains and a pyridinium ring associated with its bromine counterion were synthesised and their liquid crystalline properties were studied by differential scanning calorimetry, polarising optical microscopy and X-ray diffraction. The results were compared with those of chemical intermediates, which also develop a liquid crystalline behaviour. Both intermediates and pyridinium salts showed a rich polymorphism at temperatures ranging from around 100 to 200°C and 115 to 220°C, respectively. X-ray results indicate that both intermediates and pyridinium salts develop tilted smectic mesophases with molecules stacked in single and double layers, respectively. The tilt angle of some of these compounds decreases so markedly upon cooling that molecules attain almost an orthogonal position. The stacking of molecules in the smectic layers was explained in terms of the mutual repulsion interactions between the terphenylene core, the alkyl chains and the ionic species (the pyridinium ring associated with its counterion) and it was proposed that the π–π interactions between the long aromatic cores counterbalance the strong forces between the ionic species, leading to a full segregation of these molecular parts in periodic sublayers. A molecular arrangement model is proposed for these salts. 相似文献
7.
M. Cvetinov M. Stojanović D. Obadović S. Rakić A. Vajda K. Fodor-Csorba N. Éber 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2014,88(7):1142-1146
Unit cell parameters calculated from X-ray powder diffraction data are presented for the crystalline phase of a liquid crystal 4-butyloxyphenyl 4′-decyloxybenzoate: a = 23.098 (4) Å, b = 5.974 (6) Å, c = 12.357 (10) Å, β = 121.5283 (788)°, unit-cell volume V = 1453.56 Å3. Temperature dependent X-ray diffraction data confirmed the existence of smectic A and smectic C mesophases and a more ordered, tilted crystalline smectic phase. Possibility of existence of previously reported smectic B phase as well as another crystalline phase was refuted. 相似文献
8.
A series of non-symmetric liquid crystal compounds consisting of two different semi-rigid anisometric cores, namely 1,3,4-oxidiazole and biphenyl units, and two short terminal groups, have been synthesised in good yield. It has been shown by polarising optical microscopy and differential scanning calorimetry that all these compounds display liquid crystalline behaviour, with nematic and/or smectic A mesophases. The nature of the mesophases is dependent on the electronic properties of the terminal groups. In methylene chloride solution all the compounds displayed a room temperature emission with λmax at 358–396 nm and quantum yields of 0.29–0.56. The effect of the terminal groups on the mesomorphic and photoluminescent properties is briefly discussed in the context of their electronic characteristics. 相似文献
9.
Micael D. Miranda Fabián Vaca Chávez Teresa M.R. Maria M. Ermelinda S. Eusebio P.J. Sebastião Manuela Ramos Silva 《Liquid crystals》2013,40(12):1743-1751
A series of thermotropic hydrogen-bonded liquid crystalline structures based on 4,4′-bipyridyl and aliphatic carboxylic acids was prepared by a mechanosynthesis technique. This series was characterised by polarising optical microscope, differential scanning calorimetry, Fourier transform infrared spectroscopy, X-ray powder diffraction and 1H NMR relaxometry experimental techniques. In these complexes, the bipyridyl component, a non-mesogenic substance by itself, acts as a double H-bond acceptor, whereas the alkylbenzoic acid acts as a H-bond donor, in a 1:2 proportion. The so-formed complexes exhibit mesophases that are not observed by the single components. A characteristic phase (smectic A) is identified and shown to be affected by the alkyl chain length. The isotropisation temperature is increased by the supramolecular aggregation through the H-bonds. 相似文献
10.
U. Caruso B. Panunzi A. Roviello A. Sirigu D. Spasiano 《Journal of polymer science. Part A, Polymer chemistry》2001,39(13):2342-2349
Rigid‐chain metallomesogenic polymers containing Cu(II) or VO(II) were prepared and characterized. All the polymers were soluble and melted without decomposition. They showed a thermotropic liquid–crystal (LC) behavior, and the mesophases were invariably preserved for a long time at room temperature in a metastable condition, with respect to the semicrystalline state. The nature of the mesophases of the Cu(II)‐containing polymers was similar to that observed in analogous organic rigid‐chain polymers having long lateral alkyl chains packed as extended ribbons. The VO(II)‐containing polymers showed an LC polymorphism involving a smectic A and a nematic phase. For all the polymers in a smectic or smecticlike state at room temperature, X‐ray diffraction data suggested short mean distances among the metal ions arranged in layers. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 2342–2349, 2001 相似文献
11.
Butschies M Frey W Laschat S 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(10):3014-3022
Ionic liquid crystals are mesogenic compounds that consist of cations and anions, usually rod-like cations and spherical anions. Herein we report a new method for the synthesis of ionic liquid crystals by using cations and anions of the same molecular shape with oppositely charged head groups. Thus, 4-alkoxyphenylpentamethylguanidinium 4-alkoxyphenylsulfonate ion pairs have been synthesised. 4-Alkoxyphenylpentamethylguanidinium iodides were also prepared to determine the influence of congruently shaped anions, in comparison with their spherical counterparts, on mesophase behaviour, which was investigated by differential scanning calorimetry (DSC), polarising optical microscopy (POM) and X-ray diffraction (XRD). All the liquid crystalline salts exhibit smectic A mesophases with strongly interdigitated bilayer structures. The guanidinium sulfonate ion pairs show mesomorphic properties from shorter alkyl chain lengths (≥C(9)) and lower melting points (≈10 K), whereas the corresponding guanidinium iodides are liquid crystalline for longer alkyl chain lengths (≥C(14)). For chains with ≥C(18), however, the mesophase range decreases for the sulfonate ion pairs, but not for the iodide salts. 相似文献
12.
The synthesis and mesomorphic (liquid crystal) properties of new binuclear dihalocopper(II) complexes derived from N- and ring-substituted salicylaldimine Schiff bases are reported, together with the mesomorphic properties of their monomeric precursor complexes. With just N-substituents both the dichlorodicopper(II) binuclear complexes and their mononuclear analogues are waxy solids with melting points that increase with their N-chain length. However, with both N- and ring-substituents in the 4-positions, the mononuclear and binuclear complexes are each liquid crystalline or mesogenic, except in case of the mononuclear complexes where the N-substituent is straight chain alkyl. The other mononuclear complexes exhibit a variety of liquid crystal phases: smectic A, C, and E (SA, SC, and SE, respectively). The liquid crystal phase SA is observed in the binuclears with shorter chain N-substituents p-R-O-C6H4- and shorter chain ring-substituents. The chain lengths were increased until the phase behavior expanded to a further form SC in the case of an N-substituent p-C14H29O-C6H4- and a -OC12H25 ring substituent. This points the way toward achieving multiphase behavior with these binuclear systems. The Cu-Br analogues of the binuclear complexes behave similarly but with significant qualitative differences, specifically lower mesophase stability and higher melting temperatures. The structures of the nonmesogenic binuclears ([Cu(N-dodecylSal)X]2, X=Cl, Br) were determined with the aid of X-ray crystallography. These are prototypes for the structures of the binuclear complexes and especially for the shape of the central Cu2O2 X2 core in the binuclears: distorted planar coordination about the copper with distortion toward tetrahedral measured by a characteristic twist angle tau (0 degrees planar; 90 degrees tetrahedral). The binuclear complexes also show magnetic coupling which can be used to estimate the geometry. For [Cu(N-dodecylSal)X]2 tau>36 degrees, which corresponds to weaker coupling than observed in the mesogenic binuclears where a stronger magnetic coupling indicates a geometry closer to planar (tau=25 degrees). The mesophases were characterized by differential scanning calorimetry (DSC) analysis and optical polarized microscopy. 相似文献
13.
Approximately thirty 4-(alkenyloxy)phenyl 4'-alkyl/alkoxy-4-biphenyl-1-carboxylates incorporating a chiral centre at the point of branching of the terminal alkyl/alkoxy chain have been synthesized. The three carbon chains investigated were 2-methylbutyl, 3-methylpentyl and 2-methylbutoxy. The configuration of the chiral centre is (S) in each case. The effect of the alkenyloxy chain length on the liquid crystal transition temperatures of the three homologous series prepared has been studied systematically. Chiral smectic C and chiral nematic mesophases, as well as a smectic A mesophase in several cases, were observed over a wide temperature range for most of the esters prepared. 相似文献
14.
Abstract Approximately thirty 4-(alkenyloxy)phenyl 4′-alkyl/alkoxy-4-biphenyl-1-carboxylates incorporating a chiral centre at the point of branching of the terminal alkyl/alkoxy chain have been synthesized. The three carbon chains investigated were 2-methylbutyl, 3-methylpentyl and 2-methylbutoxy. The configuration of the chiral centre is (S) in each case. The effect of the alkenyloxy chain length on the liquid crystal transition temperatures of the three homologous series prepared has been studied systematically. Chiral smectic C and chiral nematic mesophases, as well as a smectic A mesophase in several cases, were observed over a wide temperature range for most of the esters prepared. 相似文献
15.
Pradip K. Bhowmik Shane T. Killarney Jessa Rose A. Li Jung Jae Koh Haesook Han Lewis Sharpnack 《Liquid crystals》2018,45(6):872-885
A series of extended, symmetric viologen triflimides were synthesised by the metathesis reaction of lithium triflimide with the respective viologen tosyalates in methanol. Their chemical structures were characterised by Fourier Transform Infrared, 1H and 13C Nuclear Magnetic Resonance spectroscopy and elemental analysis. Their thermotropic liquid-crystalline (LC) properties were examined by a number of experimental techniques including differential scanning calorimetry, thermogravimetric analysis, polarising optical microscopy and variable temperature X-ray diffraction. The viologen salts containing alkyl chain of two carbon and three carbon atoms were relatively low melting salts. Those of alkyl chains of four carbon and five carbon atoms formed ionic liquids at 88 and 42°C, respectively. Those of alkyl chain of 9, 10 and 11 carbon atoms were high melting salts, as high as 166°C. Those of higher alkyl chains of 16, 18 and 20 carbon atoms showed thermotropic LC phases forming SmC, SmA and an unidentified smectic (SmX) phases, and showed SmA to isotropic transitions at high temperatures. As expected, all the viologen triflimides had excellent stabilities in the temperature range of 338–365°C. 相似文献
16.
J. Belmar 《Liquid crystals》1999,26(1):75-81
Two new series of calamitic liquid crystals containing the isoflavone moiety within the central core have been prepared and their liquid crystalline properties studied. The compounds exhibit typical nematic, smectic A and C mesophases. The influence of the linking group between a terminal alkyl chain and the central core has been proven to determine the variety of mesomorphism displayed by the compounds. 相似文献
17.
Abstract Three homologous series of 4-(5-alkyl-2-pyridinyl)phenyl alkanoates have been prepared. The synthesis and the liquid crystal transition temperatures of these esters are reported. Many members of these three ester series exhibit enantiotropic, wide range smectic F mesophases and some narrow range smectic C mesophases. However, in admixture with a chiral smectic C base mixture, the esters often induce a substantial increase in the chiral smectic C–smectic A transition temperature and, at the same time, decrease the temperature of crystallization. Thus, the temperature range of the chiral smectic C mesophase is substantially extended at both high and low temperatures. Ordered smectic mesophases are only observed at very low temperatures, if at all. These chiral smectic C mixtures are characterized by short switching times in surface-stabilized ferroelectric liquid crystal displays (SSFLCD). These novel esters are of especial interest for short-pitch chiral smectic C mixtures for short pitch bistable ferroelectric liquid crystal displays (SBFLCD) with short response times. 相似文献
18.
Hye Won Chae 《Liquid crystals》2013,40(1):53-60
New mesogenic heteropolynuclear complexes of Cu(II), Pd(II), Ni(II) and VO(IV) with the [3]ferrocenophane‐containing Schiff's base, and Cu(II) and Pd(II) complexes with the [3]ferrocenophane‐containing β‐aminovinylketone have been synthesised. The obtained heterometallic mesogenes are identified by elemental analysis, proton nuclear magnetic resonance, infrared and ultraviolet–visible spectroscopies. Liquid crystalline properties are studied by thermal polarising optical microscopy and differential scanning calorimetry techniques. Both ligands and heteropolynuclear complexes exhibit thermotropic nematic and smectic C mesophases in various temperature ranges except for the Ni(II) complex. Mesomorphism of the prepared complexes is correlated with the geometry of their central chelate core. Considerably broader mesophases and lower transition temperatures are achieved in the synthesised metallomesogens by using the alkylidene‐bridged ferrocene as a building unit. 相似文献
19.
Xu F Matsumoto K Hagiwara R 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(43):12970-12976
A series of 1‐alkyl‐3‐methylimidazolium fluorohydrogenate salts (CxMIm(FH)2F, x=8, 10, 12, 14, 16, and 18) have been characterized by thermal analysis, polarized optical microscopy, IR spectroscopy, X‐ray diffraction, and anisotropic ionic conductivity measurements. Liquid crystalline mesophases with a smectic A interdigitated bilayer structure are observed from C10 to C18, showing a fan‐like or focal conic texture. The temperature range of the mesophase increases with the increase in the alkyl chain length (from 10.1 °C for C10MIm(FH)2F to 123.1 °C for C18MIm(FH)2F). The distance between the two layers in the smectic structure gradually increases with increasing alkyl chain length and decreases with increasing temperature. Conductivity parallel to the smectic layers is around 10 mS cm?1 regardless of the alkyl chain length, whereas that perpendicular to the smectic layers decreases with increasing alkyl chain length because of the thicker insulating sheet with the longer alkyl chain. 相似文献
20.
Three series of cholesteryl-containing supramolecular hydrogen-bonded (H-bonded) liquid crystal (LC) complexes with different number of fluoro-substituent were synthesised and characterised. Cholesteryl isonicotinate as proton acceptor and 4-n-alkoxybenzoic acids with or without fluoro-substituent as proton donor had been mixed in tetrahydrofuran to obtain H-bonded LC complexes. The effect of lateral substitution and the length of terminal chain in the H-bonded precursors on the formation of the supramolecular complexes had been examined. It was found that the introduction of fluoro substituent on the induced mesogens could widen the molecular width and thus reduce the molecular aspect ratio of the complexes, therefore it could lead to compress the formation of the LCs. However, the fluoro substituent played a positive role in enhancing the intermolecular interactions and stabilising the H-bond structure of the complexes. The influence of terminal length on the mesogenic behaviours is also discussed. On increasing the spacer length, the clear point and the thermal range of induced mesophase-like cholesteric phase decreased, and an induced chiral smectic phase began to appear in some complexes with long terminal tails. 相似文献