A stochastic derivation of the Sivashinsky equation for the self-turbulent motion of a free particle

Within the framework of the Kershaw approach and of a hypothesis on spatial stochasticity, the relativistic equations of Lehr and Park, Guerra and Ruggiero, and Vigier for stochastic Nelson mechanics are obtained. In our model there is another set of equations of the hydrodynamical type for the drift velocityv _i(x _j,t) and stochastic velocityu _i(x _j,t) of a particle. Taking into account quadratic terms in l, the universal length, we obtain from these equations the Sivashinsky equations forv _i(x _j,t) in the caseu _i →0. In the limit l →0, these equations acquire the Newtonian form.     

Millimeter-wave spectrum of the C4v molecule IOF5: l-type doubling of the kl = −1 transitions in the v11(E) = 1 state spectrum

Measurements of the rotational spectrum of the C_4v molecule IOF₅ are reported for the excited vibrational state v₁₁(E) = 1 for the transitions J13 ← 12, 14 ← 13, 16 ← 15, and 17 ← 16 (55–72 GHz) including the observation of the kl = −1 (q⁻), l-doubling effect. Detailed assignments of the E-state spectrum are presented based on the overlapping quadrupole structure. These data are analyzed together with earlier results for the excited vibrational state v₆(B₁) = 1 to give information concerning the ν₆(B₁)-ν₁₁(E) Coriolis interaction and the (Δl, Δk) = (2, 2) (q⁺) and (2, −2) (q⁻)l-resonance interactions. It is found that q₁₁⁻ = −2.57(10) MHz, |q₁₁⁺| = 0.094(20) MHz, Δ = ν₆ − ν₁₁ = 45.2(7) cm⁻, ζ_11,11^z = +0.18(1) and |ζ_6,11^y| = 0.73(4).     

Contribution of the inhomogeneous waves in angular-spectrum representations

Angular-spectrum representations of wave fields separate naturally into two parts, V_h(R,t) containing only homogeneous plane waves and V_i(R,t) containing only inhomogeneous plane waves. Some properties of V_i(R,t) are presented here. We conclude that, for some problems, V_i(R,t) has several unphysical properties, and that under certain specified conditions, V_i(R,t) can not be neglected compared to V_h(R,t), even far from the sources of the field.     

Zerfallende Zustände als physikalisch nichtisolierbare Teilsysteme

Presently the investigations of decaying quantum mechanical systems lack a well-founded concept, which is reflected by several formal difficulties of the corresponding mathematical treatment. In order to clarify in some respect the situation, we investigate, within the framework of nonrelativistic quantum mechanics, the resonant scattering of an initially well localized partial wave packet ϕ_l(r, t). If the potential decreases sufficiently fast for r → ∞, ϕ_l(r, t) can be expressed at sufficiently long time after the scattering has taken place, as ϕ_l(r, t) = I(r, t) + ∑ N_iϕl(K_i, r) exp {–iK_i² t/2M} × Θ(k_i – γ_i – Mr/t), ϕ_l(K_i, r) being the resonant solution with complex “momentum” K_i = k_i – iγ_i. From this heuristic relation one can deduce not only the probability for the creation of unstable particles but also obtain some hints to a connection between decaying states and physically nonisolable partial systems. On the other hand, this connection can perhaps display the inadequacy of attempts which suggest to solve the problem of decaying states within the usual Hilbert space methods.     

Analytical properties of the forward elastic scattering amplitudes following from microcausality

The forward elastic scattering amplitudes T_i(v,q²), (i = 1,2), of the virtual photon with the mass q² are considered in variables σ and ? where σ and ? are related to q² and v by the formulae q² = exp (2σ) and v = exp (σ) ch?. It has been proved that microcausality requirement implies the analyticity of amplitudes in the tube region [Im σ + π/2] + |Im?| < π/2 as a function of both complex variables σ and ?. Formulae are obtained expressing amplitudes T_l(v,q²) at arbitrary v and q² through functions W_l^(?)(v, q²) describing the electroproduction process ?2v < q² < 0.     

Localization and transmission coefficient for two coupled metal chains with disorder

The equation for distribution of probabilities for the transmission coefficient T has been obtained for an electron passing through the finite section of the length L, consisting of two coupled disordered chains. The behavior of the mean 〈lnT〉 = - L/l_loc suggests localization of the electron on the length l, which depends on the coupling energy t between the chains. The ratio l_loc(t =)/l_loc(t?v_F/l) is found to be equal to 1 ? 1/π.     

The High-Resolution Spectra of the ν11 Band of Triacetylene near 622 cm−1: Revised Assignments for Hot Bands

The rovibrational spectra of triacetylene (C₆H₂) were recorded for the ν₁₁ band in high resolution by FTIR spectroscopy. The assignments for the hot-band system (v₁₁, v₁₃) = (1, 1) ← (0, 1) have been fully revised, and reliable molecular parameters have been determined including the rotational and vibrational l-type doubling constants. The assignments have been confirmed by a simulation of the absorption profile in the Q-branch region. The intensity perturbation caused by the l-type resonance in the (v₁₁, v₁₃) = (1, 1) state has been observed and discussed.     

Moments of a Single Entry of Circular Orthogonal Ensembles and Weingarten Calculus

Consider a symmetric unitary random matrix V = (v _ij )_{1 ≤ i, j ≤ N} from a circular orthogonal ensemble. In this paper, we study moments of a single entry v _ij . For a diagonal entry v _ii , we give the explicit values of the moments, and for an off-diagonal entry v _ij , we give leading and subleading terms in the asymptotic expansion with respect to a large matrix size N. Our technique is to apply the Weingarten calculus for a Haar-distributed unitary matrix.     

Construction of kernels of the nonlinear collision integral in the Boltzmann equation using laplace transformation

It is shown that the relation between kernels L _l (v, v ₁) of the linear collision integral and kernels G _l,0 ^l (v, v ₁, v ₂) of the nonlinear collision integral can be reduced to the Laplace transformation. Analytic expressions for nonlinear kernels G _0,0 ⁺⁰ (v, v ₁, v ₂) and G _1,0 ⁺¹ (v, v ₁, v ₂) are determined for hard spheres and pseudo-Maxwellian molecules.     

Dynamical spin system: Exact solution and mean recurrence time

A model involving a chain of N ≥ 2 spins s_i = ±1, i = 1,…,N, evolvi ng syncronously in discrete time t via a nonlinear, autonomous transformation s_i(t+1) = s_i(t)s_i+1(t), i = 1,…,N−1; s_N(t+1) = s_N(t), is presented. The transformation equations are solved explicitly and the detailed decomposition of state space into ergodic sets is found. On the assumption of equally likely initial states, the mean recurrence time is calculated and its variance is discussed. The model displays a strikingly sensitive dependence on the number of spins, and this is reflected in the “staircase” behavior of the mean recurrence time. Remarks are made regarding the connection between the behavior of the model and the ground states of a related two-dimensional Ising model.     

Electroproduction of π+ n, π- p andK + Λ,K + 2211; 0 final states above the resonance region

The reactionsΣ _v p→π⁺ n,K ⁺ Λ,K ⁺ ∑ ⁰ andΣ _v n→π⁺ n were studied at invariant hadronic masses around 2.2. GeV forQ ²=0.06, 0.28, 0.70, and 1.35 GeV². The main results are: At small |t| the π⁺ production is dominated by longitudinally polarized photons and can be described by one pion exchange. At low |t| the transverse (π⁺ n) cross section drops steeply withQ ², but remains roughly constant forQ ²≧0.5 GeV². For |t?≧0.8 GeV², (π⁺ n/dt) is almost independent ofQ ². The integrated cross section (π⁺ n) shows a similarQ ²-dependence asσ _tot (γ _v p) forQ ²≧0.28 GeV². The ratioσ(π^- p)/σ(π⁺ n) atQ ²=0.70 and 1.35 GeV² for |t|≧0.6 GeV² is smaller than in photoproduction and close to 1/4. The ratioσ(K ⁺ ∑ ⁰ decreases steeply withQ ² following roughly the predictions of the quark-parton model.     

Determination of the positions of impurity centers in a dislocation core in a NaCl crystal from magnetoplasticity spectra

The spectra of the mean free paths l(ν) of edge dislocations have been studied in NaCl crystals exposed in the electron paramagnetic resonance scheme to the crossed magnetic fields: the Earth’s field (50 μT) and the pump field (2.5 μT, 5–440 kHz). The spectra have been measured for a series of angles θ = 0°–5° of rotation of the sample around its edge [100] with respect to the Earth’s field. The fine structure of the spectra contains a series of peaks whose resonance frequencies are described by the empirical expression v _i ^± = Asin(θ ± Δθ _i ) ≈ A(θ ± Δθ _i ). The parameters Δθ _i are independent of the angle θ within the experimental errors. Within the model of “frozen” magnetic moments associated with impurity center Ca⁺-Cl⁰, the angles Δθ _i characterize the deviation of the axis of the center from the 〈100〉 direction in the core of a dislocation. These angles can be expressed in terms of the spectra obtained: Δθ _i = (? _i ⁺ ? v _i ^? )/2A. The computer simulation of the edge dislocation core provides the set of the angles Δθ _i close to the measured values. The spin-lattice relaxation time of the center on dislocation has been estimated from the low-frequency edge of the spectrum l(ν) as τ _{s ? l} ～ 10^?4 s.     

Bi-solitons for a class of non-linear equations with quadratic non-linearity. II

We generalize to any order q, the methods developed in a companion paper for q = 2,3 for finding bi-solitons, solutions of the class of non-integrable non-linear equations L_qK = K²; L_q = ? + Σ_i+j≤qa_ij?_xⁱ?_lⁱ, ? ≠ 0 in 1 + 1 dimensions. We call bi-solitons K(ω₁,ω₂) of the exponential type variables ω_i = exp(γ_ix + ρ_it), i = 1,2 and deal only with the so-called “non trivial” solutions which may be written as a finite sum K = Σ^lmax₀ω¹₂F_i(Z)_, F₁ rational function of Z = ω₁Z = ω₁ + ω₁. To any such polynomial K, we associate a linear transformation such that L_qK has only the power ω¹₂ of K² and we find that there are particular polynomialswhere the above restriction provide a factorization of the linear operator L_q in the product of smaller order differential operators. After this linear phase, we show in a second step that these forms yield solutions for the full non linear equation which can be derived in an intrinsic manner. Examples in the monomial and binomial cases are given.     

Stochastic processes originating in deterministic microscopic dynamics

We investigate the probability distribution of the scaled trajectory of a test particle moving in an equilibrium fluid according to the laws of classical mechanics, i.e., ifQ(t) is the displacement of the test particle we letQ _A(t) =Q(At)/√A and consider the distribution of the trajectory Q_A(t) in the limit A→∞. The randomness of the motion is due entirely to the randomness of the initial state of the fluid, test particle, or both, and the process is generally non-Markovian. Nevertheless, it can be proven in some cases and we expect it to be true in many more that Q_A (t) looks like Brownian motion in the limit A→∞. Some results for simple model systems are presented.     

Quasi-classical rate constants for the inelastic process O2(υi≫ 1) + O2 → O2(υf) + O2

Rate constants have been calculated using quasi-classical trajectories (QCT) for the vibrational relaxation of highly excited O₂:O₂(X³Σ?,v_i) + O₂(X³Σ?,0) → O₂(X³Σ?,v_f) + O₂(X³Σ?) with 22 ≤v_i≤28. The present full-dimensional QCT results agree very well with recent quantum reduced dimensionality calculations, giving further support to the hypothesis that the observed experimental jump in depletion rates would be due partially to enhanced vibrational relaxation.     

A comparison of πππ, Kππ, πKKKK system produced in the reactions meson +p→3 mesons + p

A comparison is made of the low-mass three-meson systems (πππ), (Kππ), $\text{(π}\text{K}\text{K}\text{)}$ and $\text{(}\text{K}\text{K}\text{K}\text{)}$ diffractively produced in the reaction meson + proton → three mesons + proton. Several striking similarities and a few important differences are observed: (i) the reactions are consistent with the assumption that the three mesons decay entirely into a 0^? meson and a 0⁺, 1^? or 2⁺ resonance; (ii) the three-meson mass spectra have a peak ≈ 250 MeV above the effective threshold M_eff of the dominant decay mode and then fall off approximately as (mass)^?3;(iii) the average spin 〈J〉 = 0.55 + 1.1 Q_eff, where Q_eff = M - M_eff; (iv) the average orbital angular momentum 〈l〉 increases according to 〈l〉 = 0.75 Q_eff; (v) the three-meson states are produced dominantly in unnatural spin-parity states and no evidence for their being resonant is found; (vi) the only natural spin-parity states found are the well-established 2⁺ resonances A₂ and K¹ (1420); they have similar properties to the non-resonant unnatural parity states except for a dip at t = 0 in the dσ/dt distributions; (vii) both the unnatural and natural spin-parity states are produced mostly by an exchange of natural parity; (viii) there is evidence for two types of production mechanism with different polarization properties, one approximately conserving helicity in the t-channel and the other in the s-channel.     

Stability for the Korteweg-de Vries equation by inverse scattering theory

The stability problems for the Korteweg-de Vries equation, where linear stability fails, are investigated by the inverse scattering method. A rather general solution u(t, x) of the K-dV equation is shown to depend, for fixed time t, continuously on the initial condition u(0, x). For a continuum solution u_c(t, x), this continuity holds uniformly in t (stability), but for a soliton solution this is not true. A soliton solution can be uniquely decomposed into a continuum and discrete (soliton) part: u(t, x) = u_e(t, x) + u_d(t, x). Then the perturbed solution u is close to u after a suitable t-dependent “shift” of the soliton part (form stability).     

Symmetries of the pseudo-diffusion equation and related topics

We show in details how to determine and identify the algebra g = {A_i} of the infinitesimal symmetry operators of the following pseudo-diffusion equation (PSDE) LQ ≡ \(\left[ {\frac{\partial }{{\partial t}} - \frac{1}{4}\left( {\frac{{{\partial ^2}}}{{\partial {x^2}}} - \frac{1}{{{t^2}}}\frac{{{\partial ^2}}}{{\partial {p^2}}}} \right)} \right]\) Q(x, p, t) = 0. This equation describes the behavior of the Q functions in the (x, p) phase space as a function of a squeeze parameter y, where t = e ^2y. We illustrate how G _i(λ) ≡ exp[λA _i] can be used to obtain interesting solutions. We show that one of the symmetry generators, A ₄, acts in the (x, p) plane like the Lorentz boost in (x, t) plane. We construct the Anti-de-Sitter algebra so(3, 2) from quadratic products of 4 of the A _i, which makes it the invariance algebra of the PSDE. We also discuss the unusual contraction of so(3, 1) to so(1, 1)? h². We show that the spherical Bessel functions I ₀(z) and K ₀(z) yield solutions of the PSDE, where z is scaling and “twist” invariant.     

Theoretical study of the spin-orbit coupling in the X2Π state of OH

The spin-orbit coupling constant, A(r), as a function of internuclear distance (r) was computed for the X²Π state of OH, using the microscopic spin-orbit Hamiltonian, extended basis sets, and extensive configuration-interaction wavefunctions. Our best theoretical results are in excellent agreement with the “experimental” A(r) functions deduced from an inversion of the observed A_v. Our calculated first-order contributions to A_v, v ≤ 10, obtained by vibrationally averaging our theoretical A(r) function using the X²Π RKR potential, differ from experiment by less than 0.12%. A minimum occurs in the A_v at v = 7 in agreement with experiment, reflecting the local minimum in A(r) near 2.8 bohr. The second-order contributions to A_v are only about 0.1% for v ≤ 10. They arise mainly from the A²Σ⁺ state for the lower vibrational levels, but each of the A²Σ⁺, B²Σ⁺, (1)²Σ^?, (1)⁴Σ^?, and (1)²Δ states contributes significantly for higher vibrational levels. Spin-orbit centrifugal distortion parameters, A_Dv and a_Dv, are reported for v ≤ 6. The theoretical A_Dv are also in excellent agreement with experiment when the “experimental” A(r) function has the same slope at the equilibrium separation as that obtained from the effective spin-rotation constants of OH, OD, and OT.