The influence of annealing in different atmospheres on the absorption and dielectric losses of pure NaCl crystals

The influence of annealing in atmospheres of HCl, CO₂, nitrogen and air on the absorption and dielectric losses of NaCl crystals is examined. The reasons for a decrease or even the disappearance of the absorption band near 1900 Å in unannealed hydrolized crystals are discussed. Further, the causes of the shift of the relaxation maximum of the dielectric losses of pure NaCl crystals were studied.We should like to express our gratitude to Dr. Bohun for a discussion of the results, to Dr. Trnka for the preparation of the crystal and to Z. Klímová for performing the absorption measurements.     

Average coordination-number dependence of glass-transition temperature in Ge-In-Se chalcogenide glasses

Twenty-six glassy compositions, belonging to the Ge_xIn₆Se_94-x and Ge_xIn₁₂Se_88-x families of the Ge-In-Se system, were prepared from high purity constiment elements. Differential Scanning Calorimetry (DSC) measurements were carried out on these glasses. The DSC thermograms were used to determine the glass transition temperatures (T _g) for the compositions examined. TheT _g-composition dependence of the Ge_xIn₆Se_94-x family shows a minimum inT _g at a value of the average coordination number, r, equal to 2.4. For both families of the glasses examined, theT _g-r dependence displays maxima at r=2.75 and r=2.83 for Ge_xIn₆Se_94-x and Ge_xIn₁₂Se_88-x families, respectively. These results are interpreted by using the Phillips model of rigidity percolation and Chemically Ordered Covalent Network (COCN) model.     

Free carrier scattering mechanism in Bi2Se3 crystals

The single valley model proposed byKöhler andLandwehr is used for the calculation of transport parameters corresponding to pure Bi₂Se₃ crystals. From the measurements of transmission, reflectivity and the Hall constant the effective masses are determined,m _c =0·13m ₀ andm _c=0·56m ₀; using a simplification described in the paper the Fermi level is calculated to lie 0·14 eV above the bottom of the conduction band. This result allows us to conclude that a mixed mechanism of free carrier scattering exists inn-Bi₂Se₃ crystals, viz., the scattering by acoustic phonons prevails contributing about 75% and the scattering on ionized impurities contributes the remaining 25%. This result applies to pure Bi₂Se₃ crystals with free electron concentration 2×10¹⁹cm^–3.     

Two-way reversible deformation in titanium nickelide

A systematic study has been made of the shape-memory effects which arise in titanium nickelide after prestraining under isothermal conditions. It has been found that under thermal cycling in the free state a broad spectrum of phenomena is observed — repeatedly reversible shape memory, reversible deformation, deformation of an oriented transformation, etc., each of which can be realized independently of the others in the temperature range of the B2 R and R B19' transformations. When summing up the observed laws of the mechanical behavior of the material we used concepts of heterogeneous development of deformation in crystals, structurally hereditary properties of alloys with a shape-memory effect, as well as the principle of independent initiation of various channels of deformation.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 8, pp. 71–76, August, 1988.     

Study of the influence of iron and lanthanum oxides on the band structure of Pb(Zr,Ti) O3

The measurements of diffuse reflectance spectra in the range of 400; 2500 nm and of photoacoustic spectra in the range of 350; 800 nm were used for the study of the influence of iron (III) oxide and lathanum oxide additions on the band structure of polycrystalline lead zirconate — lead titanate solid solutions. The molar ratio of zirconium and titanium in the studied solid solutions was 60 40, and the concentrations of the dopants werex FeO_1.5, andy LaO_1.5, werex 0; 0·05 mol, andy 0; 0·10 mol, respectively. The diffuse reflectance spectra were expressed in terms of the Kubelka-Munk function values versus incident electromagnetic radiation energy. These dependences were decomposed into partial absorption bands using a computer. Transitions of charged carriers between energy levels or bands which differ mutually by the energy of 0·9, 1·2–1·3, 1·6, 1·65–1·7, 2·4–2·5, 2·75–2·8, 2·9–3·2, 3·4–3·8 eV, were identified. Their intensities depend on the concentration of Fe and/or on La in the Pb(Zr_0.60 Ti_0.40) solid solutions.The authors are very grateful to Mrs. Iva Havlasová, Vra Andrsová, Ing. Jan Netuka, and Mrs. Liana Karlíková from the first authors' institute, for their technical assistance.     

Square lattice Ising antiferromagnet in an external magnetic field

We study the anisotropic square lattice Ising antiferromagnet in terms of three parameters: an external magnetic field B, an effective temperature and an anisotropy parameterK. The model, i.e., partition function and free energy, is solved exactly in the anisotropic limit,K0, for arbitrary temperature and field by using the transfer matrix method. We also calculate the first corrections beyond this limit. The limit is non trivial and the phase transition is completely preserved. It is of the expected Ising type. The transition temperature _c (B, K) is determined exactly for bothK0 andK and the results are used to check the validity of a recently conjectured formula by Müller-Hartmann and the author.     

The electronicg-factor anisotropy determined from measurements near the magic field of anomalous muonium in silicon and germanium

The field dependences of the anomalous muoniumSR frequencies have been measured in Si and Ge around the magic field. The results show a clear electronicg-factor anisotropy exists for Ge withg _¦-g₁=0.033, while that of Si is much smaller and essentially zero within the experimental accuracy.Work supported by National Science Foundation Grant DMR-79-09223.     

Structure and physical properties of ceramics in a section of the system Mg-Cu-Fe-O

The concentration dependences of the crystal lattice parameter and the Curie temperature of the magnetic ceramic, obtained in air at a calcination temperature of 1100°C from charges with the composition (1–x)MgFe₂O₄+x(0.5 CuO × 1.25 Fe₂O₃), where 0x1, were studied. The dependences of the magnetic parameters of the hysteresis loop as well as the resistivity on the composition of the charge were investigated. The single-phase ceramic, having the structure of spinel, is formed for x < 0.5, and in samples with x > 0.5 a tetragonal phase and -Fe₂O₃ are present. The maximum squareness ratio of the hysteresis loop (SHL) is observed in the region x=0.1–0.4. The region of high values of the squareness ratio is also the region of solid solutions containing defects, when -Fe₂O₃ quasiparticles, having the structure of imperfect spinel, are present in the solution.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 12, pp. 84–86, December, 1990.     

High-spin states and band structures in the doubly odd <Superscript>136</Superscript>La nucleus

High-spin states of ¹³⁶La have been investigated with the reaction ¹³⁰Te( ¹¹B, 5n) at a beam energy of 60 MeV. The level scheme with three collective bands has been updated with spin up to 20 . The observed h_11/2 h_11/2 band shows -instability with increasing spin according to the TRS calculations. The band crossing and the signature splitting and inversion have been discussed. Other two collective bands based on 12^-and 16⁺ levels were proposed as oblate deformation with -60^°. They most probably originate from four- and six-quasiparticle configurations, that is, h_11/2 g_7/2h_11/2² and g_7/2 g_7/2²d_5/2h_11/2² respectively.     

Luminescent properties of A1N activated by europium

The concentration and temperature dependence of emission and excitation spectra was measured on powder A1NEu phosphors. It was shown that A1N: Eu has two luminescent modifications which depend on the activator concentration. At low activator concentration the wide emission band is found in the blue-green region, while at high concentration it is in green region. The excitation spectra of A1NEu consist of wide bands extended from 40×10³ cm^–1 to 22 × × 10³ cm^–1. The emission and excitation spectra are interpreted as transitions between energy levels of Eu²⁺ ions (4f⁷4f⁶ 5d transitions). The structure of the Eu²⁺ luminescent centres and the temperature dependence of luminescence are discussed.The authors thank Dr. M.Polcarová for the RTG measurements and Mrs. I.Míková for the spectral analysis of the A1N: Eu samples. The authors are also grateful to Prof. M.Trlifaj, Dr. J.Pastrák and Dr. J.Kubátová for valuable discussions.     

The effects of inkomogeneous center structure on the shape of the ESR spectra of alkali-rich glasses

The paper considers the effect of nonuniform structure in the centers on the ESR spectrum for the case of axial anisotropy in the g factor; it is shown that if (² >² , _¦ >), the model enables one to describe fairly completely the spectrum of a glass containing 33% Na₂O and 67% SiO₂. Good agreement with all experimental evidence is not obtained for potassium silicate glasses.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii Fizika, No. 6, pp. 86–90, June, 1971.     

On the interpretation of the thickness dependence of the coercive field of BaTiO3 single crystals

It is shown in the paper that the thickness dependence of the coercive field of unetched and of successively etched BaTiO₃ single crystals can be explained by the presence of a ferroelectric surface layer with decreased permittivity. In contrast to the Merz model [1], which considered a homogeneous layer, the authors assume that the permittivity inside the layer gradually decreases in the direction to the surface. By using experimental results it has been found for the constant, characterizing (according to [1]) the thickness dependence of the coercive field of unetched crystals, that=1.6 V, which is in satisfactory agreement with experiment.The authors thank V. Dvoák C.Sc, J. Fousek C.Sc, and Z. Málek C.Sc. for stimulating discussions.     

The Features of Ionospheric Radio Sounding Performed using the “Mir” Space Station

We present the results of numerical simulations of ionospheric parameters, which permit one to explain the occurrence of additional features in the ionograms obtained in the experiment onboard the Mir space station. During this experiment, the station flew below the electron-density maximum of the ionospheric F₂ layer. It is shown that the lower traces of the ionograms can be evidence of the presence of a horizontal gradient in the ionospheric parameters.     

Thermal conductivity of amorphous As2Se3 with copper

Phonon thermal conductivity of amorphous As₂Se₃ with the content of copper is studied in the temperature range between 100 and 300°K. The mean free path of phonons is calculated and using the measured values of the velocity of the longitudinal acoustic waves, microhardness, softening temperature and of the density, the possibility of the arrangement of the basic structure units of the semiconducting As₂Se₃ glass is discussed.Thanks are due to Mrs J. Trepeová for the measurement of the thermal conductivity of the samples.     

Experimental survey of the sticking problem in muon catalyzed dt fusion

The sticking process dt + n, which constitutes the most severe limit to the number of fusions which a muon can catalyze, is reviewed. Many attempts were made to determine by calculations and measurements the probability for initial sticking _s ⁰ (immediately after dt fusion) and for final sticking _s (after the came to rest). Previous results based on neutron disappearance rates and on the observation of -X-rays were controversial and also in some disagreement with theory. New data are reported from PSI on direct observation of final sticking, using a setup with the St. Petersburg ionization chamber. These data mark a significant improvement in reliability and may clarify questions concerning previous discrepancies. The new results is _s(0.56±0.04)%, lower than the theory prediction _s=(0.65±0.03)%, at medium density.     

On the equivalence of boundary conditions

We show that ifb andb are two boundary conditions (b.c.) for general spin systems on ^d such that the difference in the energies of a spin configuration in ^d is uniformly bounded, |H _,b ()–H _,b()|C < , then any infinite-volume Gibbs states and obtained with these b.c. have the same measure-zero sets. This implies that the decompositions of and into extremal Gibbs states are equivalent (mutually absolutely continuous). In particular, if is extremal,=. Application of this observation yields in an easy way (among other things) (a) the uniqueness of the Gibbs states for one-dimensional systems with forces that are not too long-range; (b) the fact that various b.c. that are natural candidates for producing non-translation-invariant Gibbs states cannot lead to such an extremal Gibbs state in two dimensions.Supported in part by NSF Grant PHY 78–15920 and by the Swiss National Foundation For Scientific Research.     

Survival probability in one dimension for theA+B→B reaction with hard-core repulsion

We study the effect of hard-core repulsion (known as the bus effect) betweenB particles on the reaction-diffusion systemA+BB in the continuous-time random walk model in one dimension with theA particles stationary. We show rigorously that the survival probability of theA particles is asymptotically bounded asC ₁lim _t{[–logS(t)]/t ^0.5}C ₂, whereC ₁ andC ₂ are constants. We also do simulations to confirm our results.     

Field inversion of the sign of the hall coefficient in Hg1−xMnxTe1−ySey

In the temperature range T=77–300 K and H1–18 kOe, the dependence of the Hall coefficient (R_H) of crystals of Hg_1–xMn_xTe_1–ySe_y (0H=f(H), as well as the inversion of the sign of R_H as H increases for Hg_1–xMn_xTe_1–ySe_y (x0.1 and y=0.05) are explained by the presence in the samples of three types of charge carriers: holes, and heavy and light electrons.Chernovitskii University. Translated from Izvestiya Vysshykh Uchebnykh Zavedenii, Fizika, No. 4, pp. 11–14, April, 1994.     

Far infrared properties of SbSI-SbSeI mixed crystals

Far infrared reflectivity of eight SbS_1–x Se _x I mixed single crystals was measured in 50–400 cm^–1 region in polarized light at 25 and –170 C. While the low-frequency ferroelectric mode shows clear one-mode behaviour the second B_1u mode in 126–180 cm^–1 region shows two-mode behaviour. The existence of local and gap modes in this case is discussed.The author thanks ing. K.Nejezchleb from College of Chemical Technology in Pardubice for the crystals, L.Novák for helpful discussions, Z.Híová for computations and N.Dvoáková for help and figure drawing.     

Radiation Source in the Ranges 2.1–2.3 and 3.7–4.3 μm for the Spectroscopy of the Atmosphere

To expand the possibilities of spectroscopic systems based on a CO₂ laser, we have mixed the frequencies of its radiation with the radiation of erbium lasers. Simultaneous use of Er³⁺:CaF₂ ( = 2.76 m) and Er³⁺:YAG lasers ( = 2.96 m) makes it possible for the spectrum of generated sum and difference frequencies to overlap the ranges 2.2–2.3 and 3.6–4.3 m that coincide with the atmospheric transparency windows. Generation of the difference frequencies of radiation of erbium lasers and of the 10.6-m radiation of a CO₂ laser were observed in CdSe at a phase-matching angle of 72°40. In a bleached CdSe crystal of length 40 mm the efficiency of transformation has attained 12%. To sum up the frequencies, 4.5-mm ZnGeP₂ crystals were used, with the efficiency of transformation being 3% and the phase-matching angle being equal to 52°.