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Thomas E. Enright Michael F. Cunningham Barkev Keoshkerian 《Macromolecular rapid communications》2005,26(4):221-225
Summary: Nitroxide‐mediated polymerization of styrene in a continuous tubular reactor has been demonstrated for the first time. The polymerization kinetics in the tubular reactor are similar to those in a batch reactor. The number average molecular weight increases linearly with conversion, and chain extension experiments were successful, indicating that the living nature of the polymerization is maintained in the tubular reactor.
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