Catalytic Formation of Acrylate from Carbon Dioxide and Ethene |
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| Authors: | Dr. Coen Hendriksen Dr. Evgeny A. Pidko Dr. Gang Yang Dr. Benjamin Schäffner Prof. Dr. Dieter Vogt |
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| Affiliation: | 1. School of Chemistry, University of Edinburgh, Joseph Black Building, Edinburgh, Scotland EH9 3JJ (UK);2. Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (the Netherlands);3. Institute for Complex Molecular Systems, Eindhoven University of Technology (the Netherlands);4. CREAVIS ‐ Science to Business, Evonik Industries AG, 1420/18, Paul Baumann‐Strasse 1, 45772 Marl (Germany) |
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| Abstract: | With regard to sustainability, carbon dioxide (CO2) is an attractive C1 building block. However, due to thermodynamic restrictions, reactions incorporating CO2 are relatively limited so far. One of the so‐called “dream reactions” in this field is the catalytic oxidative coupling of CO2 and ethene and subsequent β‐H elimination to form acrylic acid. This reaction has been studied intensely for decades. However up to this date no suitable catalytic process has been established. Here we show that the catalytic conversion of ethene and CO2 to acrylate is possible in the presence of a homogeneous nickel catalyst in combination with a “hard” Lewis acid. For the first time, catalytic conversion of CO2 and ethene to acrylate with turnover numbers (TON) of up to 21 was demonstrated. |
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| Keywords: | acrylates carbon dioxide homogeneous catalysis Lewis acids lithium sustainable chemistry |
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