| 4,4-双叠氮联苯光解中间体的多重态研究 |
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| 引用本文： | 黄骏廉,于同隐. 4,4-双叠氮联苯光解中间体的多重态研究[J]. 影像科学与光化学, 1986, 4(2): 37-42. DOI: 10.7517/j.issn.1674-0475.1986.02.37 |
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| 作者姓名： | 黄骏廉 于同隐 |
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| 作者单位： | 复旦大学材料科学研究所 |
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| 摘 要： | 本文用顺磁共振和色谱分析等方法,证明了4,4'-双叠氮联苯光解产生的叠氮氮烯和双氮烯都是三重态;而热分解产生的中间体则是由单重态双氮烯所组成。因此4,4'-双叠氮联苯的热分解反应很可能具有和光分解反应完全不同的机理。
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| 收稿时间： | 1985-05-06 |
A STUDY ON THE MULTIPLE STATE OF THE INTERMEDIATE FORMED IN THE PHOTO-DECOMPOSITION OF 4,4'-DIAZIDOBIPHENYL |
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| HUANG JUN-LIAN,YU TONG-YIN. A STUDY ON THE MULTIPLE STATE OF THE INTERMEDIATE FORMED IN THE PHOTO-DECOMPOSITION OF 4,4'-DIAZIDOBIPHENYL[J]. Imaging Science and Photochemistry, 1986, 4(2): 37-42. DOI: 10.7517/j.issn.1674-0475.1986.02.37 |
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| Authors: | HUANG JUN-LIAN YU TONG-YIN |
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| Affiliation: | Institute of Material Science, Fudan University |
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| Abstract: | By means of ESR and chromatographic analysis,it was confirmed that the azido-nitrene and dinitrene which produced by the photo-decomposition of 4,4'-diazidobiphen-yl were triplets,the photo-decomposing reaction carried on in two steps.But the intermediate which produced by the thermo-decomposition of 4,4'-diazidobi-phenyl was singlet dinitrene only. So the mechanism of the thermo-decomposition of 4,4'-diazidobiphenyl was totally different from that of the photo-decomposition. |
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