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Polymer‐Induced Surface Modifications of Pd‐based Thin Films Leading to Improved Kinetics in Hydrogen Sensing and Energy Storage Applications |
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| Authors: | Dr. Peter Ngene Dr. Ruud J. Westerwaal Sumit Sachdeva Dr. Wim Haije Dr. Louis C. P. M. de Smet Prof. Dr. Bernard Dam |
| Affiliation: | 1. Materials for Energy Conversion and Storage (MECS), Department of Chemical Engineering, Delft University of Technology, Delft (The Netherlands);2. Organic Materials & Interface (OMI), Department of Chemical Engineering, Delft University of Technology, Delft (The Netherlands);3. Energy Research Centre of the Netherlands (ECN), P.O Box 1, 1755 ZG Petten (The Netherlands) |
| Abstract: | The catalytic properties of Pd alloy thin films are enhanced by a thin sputtered PTFE coating, resulting in profound improvements in hydrogen adsorption and desorption in Pd‐based and Pd‐catalyzed hydrogen sensors and hydrogen storage materials. The remarkably enhanced catalytic performance is attributed to chemical modifications of the catalyst surface by the sputtered PTFE leading to a possible change in the binding strength of the intermediate species involved in the hydrogen sorption process. |
| Keywords: | heterogeneous catalysis metal hydrides polymers sensors thin films |