| 具有三维交叉孔道的新型亚磷酸锌的合成与结构 |
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| 引用本文： | 陈文斌,李牛,项寿鹤. 具有三维交叉孔道的新型亚磷酸锌的合成与结构[J]. 中国化学, 2005, 23(3): 255-260. DOI: 10.1002/cjoc.200590255 |
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| 作者姓名： | 陈文斌 李牛 项寿鹤 |
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| 作者单位： | 南开大学化学学院新催化材料科学研究所, 天津 300071 |
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| 摘 要： | 本文报道了一种新型三维亚磷酸锌[HO(CH2)2NH3]2•[Zn3(HPO3)4]的合成和晶体结构。在它的结构中，ZnO4和HPO3严格按照顶点连接的方式交替相连。骨架结构存在两个沿着不同方向无限延伸的由ZnO4和HPO3组成的四元环链，在[0 1 0]、[0 4 15]和[0 -4 15]三个方向形成了三个交叉8元环孔道，有机胺阳离子起着平衡电荷和稳定骨架的结构。它的晶体数据为：[HO(CH2)2NH3]2•[Zn3(HPO3)4],M=640.21, 正交晶系, Fdd2空间群, a=2.8528, b=0.8426, c=1.6159nm, Z=8, V=3.884nm3, R1=0.0219, wR2=0.0544。
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| 关 键 词： | 化学结构 三维空间体系 有机金属化合物 锌 多微孔结构 |
| 收稿时间： | 2004-03-01 |
| 修稿时间： | 2004-11-12 |
Synthesis and Structure of a Novel Three‐dimensional Organo‐zincophosphite with Three Intersecting Channels |
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| Chen Wen‐Bin,Li Niu,Xiang Shou‐He. Synthesis and Structure of a Novel Three‐dimensional Organo‐zincophosphite with Three Intersecting Channels[J]. Chinese Journal of Chemistry, 2005, 23(3): 255-260. DOI: 10.1002/cjoc.200590255 |
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| Authors: | Chen Wen‐Bin Li Niu Xiang Shou‐He |
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| Abstract: | The hydrothermal synthesis and X‐ray single crystal diffraction analysis of a novel three‐dimensional organo‐zincophosphite, [HO(CH2)2NH3]2·[Zn3(HPO3)4], are described. The framework is built up from strictly alternating vertex‐linked ZnO4 tetrahedron and HPO3 pseudo pyramid incorporating ethanolamine (EOA) cations into its channels. The structure is formed through ZnO4 tetrahedron connecting with two kinds of four‐membered ring chains along different directions. There are three intersecting channels with eight‐membered ring windows along [0 1 0], [0 4 15] and [0 – 4 15], which have not been found in organo‐zincophosphites before. Crystal data: [HO(CH2)2NH3]2·[Zn3(HPO3)4], Mr=640.21, Orthorhombic, Fdd2, a=2.8528 nm, b=0.8426 nm, c=1.6159 nm, Z=8, V=3.884 nm3, R1=0.0219, wR2=0.0544. |
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| Keywords: | zincophosphite hydrothermal synthesis three‐dimensional framework intersecting channels |
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