| 新型吡啶基修饰的尾式卟啉的合成及性质 |
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| 引用本文： | 刘美,闫伟伟,臧娜,阮文娟,朱志昂. 新型吡啶基修饰的尾式卟啉的合成及性质[J]. 高等学校化学学报, 2009, 30(8): 1501-1508 |
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| 作者姓名： | 刘美 闫伟伟 臧娜 阮文娟 朱志昂 |
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| 作者单位： | 南开大学化学学院,天津,300071;南开大学化学学院,天津,300071;南开大学化学学院,天津,300071;南开大学化学学院,天津,300071;南开大学化学学院,天津,300071 |
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| 摘 要： | 报道了一种新型尾式锌卟啉(o-PyOC6H12OTPPZn)的合成及表征, 采用紫外-可见光谱滴定法对该化合物与5种吡啶类小分子间的轴向配位反应的热力学性质进行了研究. 轴配体系的热力学数据显示, 5种吡啶类配体的平衡常数按K(4-MePy)>K(Py)>K(3-MePy)>K(2,4,6-triMePy)>K(2-MePy)依次减小, 吡啶类小分子对主体的配位能力按4-MePy>Py>3-MePy>2,4,6-triMePy>2-MePy依次减弱, 同时分子模拟的理论研究得到了与实验完全一致的结果. 通过Z-扫描实验对该化合物的非线性光学性质的研究表明, 该样品具有较强的反饱和吸收特征.
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| 关 键 词： | 尾式锌卟啉 热力学性质 非线性光学性质 |
| 收稿时间： | 2009-03-03 |
Synthesis and Properties of Novel Porphyrin Modified by Pyridine Derivative |
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| LIU Mei,YAN Wei-Wei,ZANG Na,RUAN Wen-Juan,ZHU Zhi-Ang. Synthesis and Properties of Novel Porphyrin Modified by Pyridine Derivative[J]. Chemical Research In Chinese Universities, 2009, 30(8): 1501-1508 |
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| Authors: | LIU Mei YAN Wei-Wei ZANG Na RUAN Wen-Juan ZHU Zhi-Ang |
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| Affiliation: | College of Chemistry, Nankai University, Tianjin 300071, China |
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| Abstract: | A new kind of tailed zinc porphyrin modified by pyridine derivative(o-PyOC6H12OTPPZn) was synthesized and characterized by elementary analysis,UV-Vis,1H NMR,IR,and MS spectra.The axial coordination reaction was studied between o-PyOC6H12OTPPZn and pyridine derivatives by UV-Vis spectra titration.The binding constants decreased in the order of K(4-MePy)>K(Py)>K(3-MePy)>K(2,4,6-triMePy)>K(2-MePy) for pyridine derivatives.The results show that the capability of axial ligands decreased in the sequence of 4-MePy... |
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| Keywords: | Tailed zinc porphyrin Thermodynamic property Nonlinear optical property |
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