Rhenium(I)‐Catalyzed Generation of α,β‐Unsaturated Carbene Complex Intermediates from Propargyl Ethers for the Preparation of Cycloheptadiene Derivatives |
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| Authors: | Hideyuki Sogo Prof. Dr. Nobuharu Iwasawa |
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| Affiliation: | Department of Chemistry, Tokyo Institute of Technology, Tokyo, Japan |
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| Abstract: | The rhenium(I)‐catalyzed generation of α,β‐unsaturated carbene complex intermediates from easily available propargyl ethers was achieved for the concise construction of cycloheptadiene derivatives through the formal [4+3] cycloaddition reaction with siloxydienes. |
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| Keywords: | cycloaddition reactions propargyl ether rhenium unsaturated carbene complex vinylidene |
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