| Covalent Organic Framework Materials for Photo/ Electrocatalytic Carbon Dioxide Reduction北大核心CSCD |
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| 引用本文： | 商林杰,刘江,兰亚乾. Covalent Organic Framework Materials for Photo/ Electrocatalytic Carbon Dioxide Reduction北大核心CSCD[J]. 应用化学, 2022, 39(4): 559-584. DOI: 10.19894/j.issn.1000-0518.210439 |
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| 作者姓名： | 商林杰 刘江 兰亚乾 |
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| 作者单位： | 1.南京师范大学化学与材料科学学院，南京 210023;2.华南师范大学化学学院，广州 510006 |
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| 基金项目： | 国家自然科学基金(Nos.21871141,21871142,22071109,92061101)资助~~； |
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| 摘 要： | Covalent organic frameworks （COFs）are a class of emerging materials connected by covalent bonds，which have high thermal/chemical stability （except boric acid COFs），permanent porosity，large specific surface area and good crystallinity. In addition，the structure of the monomer unit in COFs is adjustable and can coordinate with many transition metal ions to provide catalytic active sites. These advantages make COFs helpful to catalyze various reactions. Among them，COFs have an excellent catalytic effect on the CO2 reduction reaction（CO2 RR）. This is mainly because the adjustable pore structure of COFs allows them to adsorb a large amount of CO2 and the π-π stacking structure in COFs can promote charge transfer， which can greatly improve the efficiency of CO2 reduction. COFs can be used as photo/ electrocatalysts to efficiently reduce CO2 to CO，CH4 ，HCOOH and other products. This review discusses the important achievements of CO2 RR catalyzed by COFs， including photo/electrocatalytic CO2 RR and photoelectric coupling CO2 RR. In addition，the future development of COFs as CO2 RR catalysts is also prospected. © 2022, Science Press (China). All rights reserved.
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| 关 键 词： | 共价有机框架 光催化 电催化 二氧化碳还原 |
| 收稿时间： | 2021-08-30 |
Covalent Organic Framework Materials for Photo/ Electrocatalytic Carbon Dioxide Reduction |
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| Lin-Jie SHANG,Jiang LIU,Ya-Qian LAN. Covalent Organic Framework Materials for Photo/ Electrocatalytic Carbon Dioxide Reduction[J]. Chinese Journal of Applied Chemistry, 2022, 39(4): 559-584. DOI: 10.19894/j.issn.1000-0518.210439 |
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| Authors: | Lin-Jie SHANG Jiang LIU Ya-Qian LAN |
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| Affiliation: | 1.School of Chemistry and Materials Science，Nanjing Normal University，Nanjing 210023，China;2.School of Chemistry，South China Normal University，Guangzhou 510006，China |
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| Abstract: | Covalent organic frameworks （COFs） are a class of emerging materials connected by covalent bonds， which have high thermal/chemical stability （except boric acid COFs）， permanent porosity， large specific surface area and good crystallinity. In addition， the structure of the monomer unit in COFs is adjustable and can coordinate with many transition metal ions to provide catalytic active sites. These advantages make COFs helpful to catalyze various reactions. Among them， COFs have an excellent catalytic effect on the CO2 reduction reaction （CO2RR）. This is mainly because the adjustable pore structure of COFs allows them to adsorb a large amount of CO2 and the π-π stacking structure in COFs can promote charge transfer， which can greatly improve the efficiency of CO2 reduction. COFs can be used as photo/electrocatalysts to efficiently reduce CO2 to CO， CH4， HCOOH and other products. This review discusses the important achievements of CO2RR catalyzed by COFs， including photo/electrocatalytic CO2RR and photoelectric coupling CO2RR. In addition， the future development of COFs as CO2RR catalysts is also prospected. |
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| Keywords: | Covalent organic frameworks Photocatalysis Electrocatalysis Carbon dioxide reduction |
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