Synthesis and Characterization of Novel Polyamines Containing Different Substitute Groups Via Chemical Oxidative Polymerization |
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| Authors: | Dilek Senol ismet Kaya |
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| Affiliation: | 1. ?anakkale Onsekiz Mart University, Faculty of Sciences and Arts, Department of Chemistry, Polymer Synthesis and Analysis Laboratory, 17020, ?anakkale, Turkey, Tel: +90?286?2180018;2. Fax: +90?286?218?05?33 |
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| Abstract: | In this study, polymers of substitute aromatic amine compounds were synthesized by chemical oxidative polycondensation in aqueous alkaline medium using NaOCl as oxidant. The structures of synthesized compounds were confirmed by FT‐IR, UV‐Vis and NMR analyses. The characterizations of synthesized compounds were made by fluorescence, TG‐DTA, DSC, scanning electron microscopy (SEM) and Brunauer‐Emmett‐Teller (BET) surface area measurements. In addition, electrochemical and electrical conductivity values of compounds were carried out with cyclic voltammetry (CV) and four points probe technique measurements, respectively. Synthesized polymers viewed structural change, optical, electrochemical and thermal differences. |
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| Keywords: | Oxidative polycondensation Substituted aromatic amines Thermal analysis Electrical conductivity Band gap |
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