| 基于金属复分解闭环反应合成新型杯[4]冠醚衍生物 |
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| 引用本文： | 卢林刚,吕海燕. 基于金属复分解闭环反应合成新型杯[4]冠醚衍生物[J]. 中国化学, 2008, 26(10): 1759-1763. DOI: 10.1002/cjoc.200890318 |
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| 作者姓名： | 卢林刚 吕海燕 |
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| 作者单位： | 1. 中国人民武装警察部队学院 科学技术研究所, 河北 廊坊, 065000; ;2. 中国科学院研究生院，北京100049 ; |
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| 摘 要： | 杯[4]芳烃的上端和下端通过金属复分解闭环反应以较高产率合成一系列新型杯[4]冠醚衍生物(8a-c)，目标产物结构经元素分析、IR、MS、1H NMR及13C NMR证实。
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| 关 键 词： | 杯[4]芳烃衍生物 金属复分解闭环反应 合成 结构 |
| 收稿时间： | 2008-05-04 |
| 修稿时间： | 2008-06-03 |
Synthesis of Novel Calix[4]arenocrowns via Ring‐closing Metathesis |
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| Lin‐Gang LU,Hai‐Yan LÜ. Synthesis of Novel Calix[4]arenocrowns via Ring‐closing Metathesis[J]. Chinese Journal of Chemistry, 2008, 26(10): 1759-1763. DOI: 10.1002/cjoc.200890318 |
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| Authors: | Lin‐Gang LU Hai‐Yan LÜ |
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| Affiliation: | Graduate School, Chinese Academy of Sciences, Beijing 100049, China |
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| Abstract: | A series of novel calix[4]arenocrown derivatives 8a – 8c in a cone conformation, in which the lower rim and the upper rim were connected via ring‐closing metathesis (RCM) reaction have been synthesized in good yields, and their structures were characterized by 1H NMR, 13C NMR, IR, MALDI‐TOF MS techniques and elemental analyses. |
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| Keywords: | calix[4]arene derivative RCM reaction synthesis structure |
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