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A EuIII‐MOF with Bis(2‐carboxyethyl)isocyanurate for Luminescence Sensing of Fe3+ and SCN– Ions
Authors:Yanan Zhang  Peng Zhang  Haiju Yin  Jing Cheng  Yifan Kang
Affiliation:College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an, Shaanxi, P. R. China
Abstract:The water‐stable 3D lanthanide‐organic framework (Ln‐MOF) {[Eu(bci)(H2O)] · 2H2O}n ( 1 ) [H2bci = bis(2‐carboxyethyl)isocyanurate] was synthesized under hydrothermal conditions. Compound 1 ‐ Eu exhibits a 3D open‐framework connected by Eu–(μ‐O)2–Eu chains and bci ligands. Meanwhile, 1 ‐ Eu exhibits highly efficient luminescent sensing for environmentally relevant Fe3+ and SCN ions through luminescence quenching. These results indicated that it could be utilized as a multi‐responsive luminescence sensor.
Keywords:Lanthanide‐MOF  Fluorescent probes  Bis(2‐carboxyethyl)isocyanurate  Europium
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