|
|||||
|
|
| 用Pitzer理论预测混合电解质溶液的偏摩尔体积 | |
| 引用本文： | 申屠雁明 李以圭. 用Pitzer理论预测混合电解质溶液的偏摩尔体积[J]. 高等学校化学学报, 1993, 14(5): 702-705 |
| 作者姓名： | 申屠雁明 李以圭 |
| 作者单位： | 清华大学化工系, 北京 100084 |
| 摘 要： | 用Pitzer理论研究了混合电解质溶液的偏摩尔体积,建立了偏摩尔体积的预测方法,并利用所得电解质溶液的表观摩尔体积的Pitzer参数预测了HNO3-UO2(NO3)2-H2O、KCl-Na2SO4-H2O、NaCl-Na2SO4-H2O、NaCl-CaCl2-H2O、KCl-CaCl2-H2O、KCl-MgCl2-H2O和KCl-NaBr-H2O共7个系统4种类型的混合溶液的偏摩尔体积。 |
| 关 键 词： | 电解质水溶液 Pitzer理论 偏摩尔体积 |
| 收稿时间： | 1992-03-27 |
Prediction for Partial Molar Volumes in Mixed Electrolyte Aqueous Solutions by Pitzer Theory |
|
| SHENTU Yan-Ming,LI Yi-Gui. Prediction for Partial Molar Volumes in Mixed Electrolyte Aqueous Solutions by Pitzer Theory[J]. Chemical Research In Chinese Universities, 1993, 14(5): 702-705 | |
| Authors: | SHENTU Yan-Ming LI Yi-Gui |
| Affiliation: | Department of Chemical Engineering, Tsinghua University, Beijing, 100084 |
| Abstract: | The partial molar volumes of mixed electrolyte aqueous solutions are calculated by using Pitzer theory, and the predicting equations were established. The partial molar volumes for HNOs-UO2(NO3)2-H2O, KCl-Na2SO4-H2O, NaCl-Na2SO4-H2O, NaCl-CaCl2-H2O, KCl-CaCl2-H2O, KC1-MgCl2-H2O, KCl-NaBr-H2O systems are estimated by using new Pitzer single and mixed parameters of apparent molar volumes, and compared with the partial molar volumes calculated from experimental densities. This paper establishes a new method for predicting the partial molar volumes of mixed electrolyte aqueous solutions. |
| Keywords: | Electrolyte aqueous solution Pitzer theory Partial molar volume |
| 本文献已被 CNKI 维普 等数据库收录！ | |
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 | |
| 点击此处可从《高等学校化学学报》下载全文 | |