| Sr2+对GdVO4晶体生长和拉曼性能的影响 |
| |
| 引用本文： | 钟富兰,朱进,陈建中,庄乃锋. Sr2+对GdVO4晶体生长和拉曼性能的影响[J]. 人工晶体学报, 2006, 35(4): 795-799 |
| |
| 作者姓名： | 钟富兰 朱进 陈建中 庄乃锋 |
| |
| 作者单位： | 福州大学化学化工学院,福州,350002;福州大学化学化工学院,福州,350002;福州大学化学化工学院,福州,350002;福州大学化学化工学院,福州,350002 |
| |
| 基金项目： | 国家自然科学基金(No.60478018)资助项目 |
| |
| 摘 要： | 本文报道了Sr2+离子掺杂对GdVO4晶体生长和拉曼性能的影响.SrxGd1-xVO4晶体粉末经X射线粉末衍射分析,其结果仍属四方晶系,具有锆英石结构.实验表明,高掺杂浓度时,Sr2+离子不易取代Gd3+离子进入GdVO4晶体的晶格,易导致SrxGd1-xVO4晶体开裂和产生包裹体.XPS实验证明,SrxGd1-xVO4晶体中钒元素为+5价.同时测试了常温下SrxGd1-xVO4晶体的拉曼光谱,发现随着Sr2+离子浓度增加,在884cm-1处的VO4反对称伸缩振动逐渐增强,表明Sr2+离子的掺入影响了GdVO4晶体的拉曼性能.
|
| 关 键 词： | SrxGd1-xVO4晶体 晶体生长 拉曼光谱 |
| 文章编号： | 1000-985X（2006）04-0795-05 |
| 收稿时间： | 2005-12-28 |
| 修稿时间： | 2005-12-28 |
Influence of Sr2+ on Crystal Growth and Raman Properties of GdVO4 Single Crystal |
| |
| ZHONG Fu-lan,ZHU Jin,CHEN Jian-zhong,ZHUANG Nai-feng. Influence of Sr2+ on Crystal Growth and Raman Properties of GdVO4 Single Crystal[J]. Journal of Synthetic Crystals, 2006, 35(4): 795-799 |
| |
| Authors: | ZHONG Fu-lan ZHU Jin CHEN Jian-zhong ZHUANG Nai-feng |
| |
| Affiliation: | Institute of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002, China |
| |
| Abstract: | The paper reported the influence of Sr~(2 )-doped ion on crystal growth and Raman properties of GdVO_4 single crystal.The powder of Sr_xGd_(1-x)VO_4 crystals was measured by X-ray diffraction,which showed as-grown crystals have a zircon-type structure belonging to tetragonal system.Sr~(2 ) ion substituted difficultly for Gd~(3 )when concentration is higher,which resulted in the formation of crack and inclusion in Sr_xGd_(1-x)VO_4 crystals.The XPS experiments proved that the V element of Sr_xGd_(1x)VO_4 crystals remained in the pentavalent.The Raman spectra of Sr_xGd_(1-x)VO_4 crystals were measured at room temperature.The results indicated that Sr~(2 )-doped ion strengthened the peak of VO_4 at 884cm~(-1),and influenced the Raman properties of GdVO_4 single crystal. |
| |
| Keywords: | Sr_xGd_(1-x)VO_4 crystals crystal growth Raman spectrum |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《人工晶体学报》浏览原始摘要信息 |
|
点击此处可从《人工晶体学报》下载全文 |
|
