Enhancements of Trifluoroacetic Acylated Five‐membered Heterocyclic Compounds Using as Additives in Dye Sensitized Solar Cells |
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| Authors: | Chung‐Chun Wang Yeh‐Fang Duann |
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| Affiliation: | 1. Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, Taipei, Taiwan, Republic of China;2. Tel: +886‐2‐2771‐2171#2562;3. Fax: +886‐2‐2731‐7117 |
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| Abstract: | In this study, five‐membered heterocyclic compounds are trifluoroacetic acylated for the purpose of providing more long pairs to enhance electrolyte in dye sensitized solar cells (DSSCs). Four five‐membered heterocyclic compounds will be trifluoroacetic acylated with trifluoroacetic anhydride by Friedel‐Crafts acylation: furan, thiophene, pyrrole and N‐methylpyrrole. The properties will be measured by cyclic voltage (CV), Fourier transform infrared spectroscopy (FTIR), solar simulator, and electrochemical impedance spectroscopy (EIS). We find out that furan and thiophene which we add in electrolyte as additives can increase short circuit current and photovoltaic efficiency, and furthermore, all the trifluoroacetic acylated heterocyclic compounds perform better photoelectric abilities than non‐trifluoroacetic acylated one. The photovoltaic efficiency will be increased from 4.439% to 5.197% when 1wt% trifluoroacetic acylated thiophene is added in electrolyte as additives. |
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| Keywords: | Friedel‐Crafts acylation Heterocyclic Trifluoroacetic anhydride DSSCs |
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