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A New Irregular Trihydroxy Sesquiterpene from Teucrium mascatense
Authors:Liaqat Ali  Imtiaz Hussain  Tania Shamim Rizvi  Abdul Latif Khan  Shaukat Shujah  Jawahar Mohammed Salim Al‐Sahi  Ahmed Al‐Harrasi  Javid Hussain
Affiliation:1. UoN Chair of Oman's Medicinal Plants and Marine Natural Products, University of Nizwa, Birkat Al‐Mouz, Nizwa‐616, Oman;2. Department of Chemistry, Kohat University of Science and Technology, Kohat, Pakistan;3. Department of Biological Sciences and Chemistry, College of Arts and Sciences, University of Nizwa, Birkat Al‐Mouz, Nizwa‐616, Oman, (phone: +968‐254‐46705;4. fax: +968‐254‐46612)
Abstract:A new trihydroxy sesquiterpene, rel‐(1R,4aR,5S,6S,7S,8aR)‐decahydro‐6,8a‐dimethyl‐5‐(propan‐2‐yl)naphthalene‐1,6,7‐triol ( 1 ), has been isolated as a result of the phytochemical investigation on the CH2Cl2 extract of Teucrium mascatense. The structure elucidation of the new constituent was carried out by the combined use of 1D‐ (1H‐ and 13C‐NMR) and 2D‐NMR (HMBC and HSQC) spectroscopic analysis, along with mass spectrometric techniques. In addition to the new constituent 1 , the known metabolite 2 , previously isolated from Crataegus pinnatifida, was also identified.
Keywords:Teucrium mascatense  Sesquiterpenoids
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