New Calix[4]arene‐Cored Peripherally Functionalized Dendrimers: Synthesis and Conformational Characteristics |
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Authors: | Georgios Paraskevopoulos Dimitrios Alivertis Vassiliki Theodorou Konstantinos Skobridis |
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Affiliation: | 1. Department of Chemistry, University of Ioannina, GR‐45110 Ioannina, (phone: +30‐265‐1008598;2. fax: +30‐265‐1008682);3. Department of Biological Applications and Technology, University of Ioannina, GR‐45110 Ioannina |
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Abstract: | New calixarene‐based dendrimers, containing calix[4]arene as the core and different generations of Fréchet‐type poly(benzyl ether) dendrons as building blocks, which possess either Br‐atoms or COOtBu groups at their surface were synthesized and presented herein for the first time. The new calix[4]arene‐cored dendritic macromolecules were fully characterized and found to prefer strictly the cone conformation. |
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Keywords: | Calixarenes Cone conformation Dendrimers Host guest compounds Supramolecular chemistry |
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