Ultrafast Magic‐Angle Spinning: Benefits for the Acquisition of Ultrawide‐Line NMR Spectra of Heavy Spin‐
Nuclei |
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| Authors: | Dr. Jean‐Philippe Demers Dr. Michal Malon Dr. Amit Pratap Singh Prof. Dr. Herbert W. Roesky Dr. Yusuke Nishiyama Prof. Dr. Adam Lange |
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| Affiliation: | 1. Department for NMR-based Structural Biology, Max Planck Institute for Biophysical Chemistry, G?ttingen, Germany;2. Department of Molecular Biophysics, Leibniz-Institut für Molekulare Pharmakologie (FMP), Berlin, Germany;3. Institut für Biologie, Humboldt-Universit?t zu Berlin, Berlin, GermanyThese authors contributed equally to this work;4. JEOL RESONANCE Inc., Akishima, Tokyo, Japan;5. RIKEN CLST-JEOL Collaboration Center, Suehiro-cho, Tsurumi, Yokohama, Kanagawa, Japan;6. Institut für Anorganische Chemie, Universit?t G?ttingen, G?ttingen, Germany;7. Institut für Biologie, Humboldt-Universit?t zu Berlin, Berlin, Germany |
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| Abstract: | The benefits of the ultrafast magic‐angle spinning (MAS) approach for the acquisition of ultrawide‐line NMR spectra—spectral simplification, increased mass sensitivity allowing the fast study of small amounts of material, efficient excitation, and application to multiple heavy nuclei—are demonstrated for tin(II) oxide (SnO) and the tin complex [(LB)SnIICl]+[SnIICl3]? [LB=2,6‐diacetylpyridinebis(2,6‐diisopropylanil)] containing two distinct tin environments. The ultrafast MAS experiments provide optimal conditions for the extraction of the chemical‐shift anisotropy tensor parameters, anisotropy, and asymmetry for heavy spin‐ nuclei. |
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| Keywords: | chemical shift anisotropy heavy spin-
nuclei magic angle spinning NMR spectroscopy tin |
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