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p‐Type Dye‐Sensitized Solar Cells with a CdSeS Quantum‐Dot‐Sensitized NiO Photocathode for Outstanding Short‐Circuit Current
Authors:Wenping Kong  Shengjun Li  Zeng Chen  Chaochao Wei  Wei Li  Tao Li  Ying Yan  Xiyang Jia  Binghua Xu  Weifeng Zhang
Affiliation:Department Key Laboratory of Photovoltaic Materials of Henan Province, School of Physics & Electronic, Henan University, Kaifeng, People's Republic of China
Abstract:CdSeS quantum dots (QDs) are firstly introduced into a NiO photocathode for photocathodic dye‐sensitized solar cells (p‐DSCs). The optimized sample exhibits a short‐circuit density (14.68 mA cm?2) and power conversion efficiency (1.02%) that are almost one order of magnitude higher than the reported value of p‐QDSCs. Steady‐state photoluminescence and time‐resolved photoluminescence measurements indicate that the photoexcited holes can be almost completely injected from CdSeS QDs into the valence band of NiO. At the same time, it can be observed from electrochemical impedance spectra measurements.
Keywords:CdSeS quantum dots  dye‐sensitized solar cells  nickel oxide  p‐type, photocathodes
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