| 含三苯胺的1,8-萘酰亚胺衍生物的合成及光谱和电化学性能研究 |
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| 引用本文： | 李林波,纪顺俊,刘宇. 含三苯胺的1,8-萘酰亚胺衍生物的合成及光谱和电化学性能研究[J]. 中国化学, 2008, 26(4): 595-598. DOI: 10.1002/cjoc.200890111 |
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| 作者姓名： | 李林波 纪顺俊 刘宇 |
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| 作者单位： | 江苏省有机合成重点实验室，苏州大学化学化工学院，苏州，江苏 215123，中国 |
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| 摘 要： | 通过Suzuki偶联反应合成了一系列含三苯胺的1,8-萘酰亚胺衍生物，并进行了表征及光谱和电化学性能研究。研究表明该类化合物的荧光波长在584~610nm，位于橙色区。三苯胺的引入降低了化合物的HOMO值，有利于空穴的注入。
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| 关 键 词： | 萘酰亚胺 三苯胺 荧光 电化学 空穴传输 |
| 收稿时间： | 2007-07-11 |
| 修稿时间： | 2007-09-13 |
Synthesis,Optical and Electrochemical Properties of Novel 1,8‐Naphthalimide Derivatives Containing Triphenylamine Moiety as Hole‐Transporting Groups |
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| Lin‐Bo LI,Shun‐Jun JI,Yu LIU. Synthesis,Optical and Electrochemical Properties of Novel 1,8‐Naphthalimide Derivatives Containing Triphenylamine Moiety as Hole‐Transporting Groups[J]. Chinese Journal of Chemistry, 2008, 26(4): 595-598. DOI: 10.1002/cjoc.200890111 |
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| Authors: | Lin‐Bo LI Shun‐Jun JI Yu LIU |
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| Affiliation: | 1. Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Jiangsu 215123, China;2. Tel.: 0086‐0512‐65880307;3. Fax: 0086‐0512‐65880307 |
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| Abstract: | A series of novel 1,8‐naphthalimide derivatives have been synthesized via Suzuki cross‐coupling and characterized by 1H NMR, IR and elemental analysis, with their luminescent properties, quantum yields and electronic properties also presented. These compounds exhibited orange fluorescence with the maximum wavelengths ranging from 584 to 610 nm and lower HOMO energy level. |
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| Keywords: | naphthalimide triphenylamine fluorescence electrochemical property hole‐transporting |
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