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软嵌式薄层粉末电极 II: 软嵌式粉末微电极
引用本文:李长明,查全性. 软嵌式薄层粉末电极 II: 软嵌式粉末微电极[J]. 化学学报, 1988, 46(5): 452-455
作者姓名:李长明  查全性
作者单位:武汉大学化学系
摘    要:
发展了软嵌式粉末微电极方法研究粉末材料的电催化行为, 制备电极时将超薄层催化剂粉末软嵌入用聚四氟乙烯乳剂和乙炔黑制成的防水导电膜上, 采用这种电极研究了各种粉末催化剂在可逆及不可逆反应中的电催化行为. 实验结果表明, 采用软嵌式粉末微电极可以利用微盘电极技术的种种优点而成为研究粉末催化剂电化学行为的有力工具.

关 键 词:电极  乙炔  聚四氟乙烯  电催化  粉末  

Electrodes with surface-intercalated powder of catalysts II: Microelectrodes with surface-intercalated powder of catalysts
LI CHANGMING,CHA QUANXING. Electrodes with surface-intercalated powder of catalysts II: Microelectrodes with surface-intercalated powder of catalysts[J]. Acta Chimica Sinica, 1988, 46(5): 452-455
Authors:LI CHANGMING  CHA QUANXING
Abstract:
Microelectrode techniques were used for the study of electrocatalytic behaviors of powdered catalysts. Ultrathin layer of fine catalyst powder was intercalated into the surface layer of soft conductive plastic sheet made from acetylene black and PTFE binder. Microelectrodes of such construction were successfully employed in the study of reversible and irreversible electrode reactions. Experimental results indicated that microelectrode with ultrathin layer of surface intercalated power could be a powerful tool for the study of electrocatalytic behaviors of powder catalysts.
Keywords:ELECTRODE  ACETYLENE  POLYTETRAFLUOROETHYLENE  ELECTRO-CATALYSIS  POWDER
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