Hydrogen‐Bonded Organic Aromatic Frameworks for Ultralong Phosphorescence by Intralayer π–π Interactions |
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| Authors: | Zaiyong Zhang Xuan Wang Dr. Huili Ma Nan Gan Qi Wu Zhichao Cheng Kun Ling Mingxing Gu Chaoqun Ma Long Gu Prof. Zhongfu An Prof. Wei Huang |
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| Affiliation: | 1. Pharmaceutical, Analytical, and Solid-State Chemistry Research Center, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai, China;2. Key Laboratory of Flexible Electronics (KLOFE) and Institute of Advanced Materials (IAM), Nanjing Tech University (NanjingTech), Nanjing, China;3. Shaanxi Institute of Flexible Electronics (SIFE), Northwestern Polytechnical University (NPU), Xi'an, China |
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| Abstract: | Ultralong organic phosphorescence (UOP) based on metal‐free porous materials is rarely reported owing to rapid nonradiative transition under ambient conditions. In this study, hydrogen‐bonded organic aromatic frameworks (HOAFs) with different pore sizes were constructed through strong intralayer π–π interactions to enable ultralong phosphorescence in metal‐free porous materials under ambient conditions for the first time. Impressively, yellow UOP with a lifetime of 79.8 ms observed for PhTCz‐1 lasted for several seconds upon ceasing the excitation. For PhTCz‐2 and PhTCz‐3, on account of oxygen‐dependent phosphorescence quenching, UOP could only be visualized in N2, thus demonstrating the potential of phosphorescent porous materials for oxygen sensing. This result not only outlines a principle for the design of new HOFs with high thermal stability, but also expands the scope of metal‐free luminescent materials with the property of UOP. |
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| Keywords: | hydrogen bonds hydrogen-bonded organic frameworks π interactions self-assembly ultralong organic phosphorescence |
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