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Photocatalyzed ortho‐Alkylation of Pyridine N‐Oxides through Alkene Cleavage |
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| Authors: | Dr. Wang Zhou Dr. Tomoya Miura Prof. Dr. Masahiro Murakami |
| Affiliation: | Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Kyoto, Japan |
| Abstract: | A photocatalyzed reaction of pyridine N‐oxides with alkenes gives ortho‐alkylated pyridines with cleavage of the carbon–carbon double bond. Benzyl and secondary alkyl groups are incorporated at the ortho position of pyridines in one pot. |
| Keywords: | alkenes C− C bond cleavage ortho-alkylation photocatalysis pyridine N-oxides |