Olefin‐Directed Palladium‐Catalyzed Regio‐ and Stereoselective Oxidative Arylation of Allenes |
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| Authors: | Dr. Can Zhu Bin Yang Dr. Tuo Jiang Prof. Dr. Jan‐E. Bäckvall |
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| Affiliation: | Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691 Stockholm (Sweden) |
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| Abstract: | An olefin‐directed palladium‐catalyzed oxidative regio‐ and stereoselective arylation of allenes to afford 1,3,6‐trienes has been established. A number of functionalized allenes, including 2,3‐ and 3,4‐dienoates and 3,4‐dienol derivatives, have been investigated and found to undergo the olefin‐directed allene arylation. The olefin moiety has been proven to be a crucial element for the arylating transformation. |
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| Keywords: | allenes arylation directing groups oxidation palladium |
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